scholarly journals Kinetic Studies on the Reactions of Electrogenerated 9,10-Diphenylanthracene Cation Radical with Water and Alcohols by Means of Column-Electrolytic Stopped-Flow Method

1990 ◽  
Vol 63 (1) ◽  
pp. 33-41 ◽  
Author(s):  
Munetaka Oyama ◽  
Koichi Nozaki ◽  
Tsutomu Nagaoka ◽  
Satoshi Okazaki
1978 ◽  
Vol 10 (2) ◽  
pp. 153-159 ◽  
Author(s):  
Hidetoshi Ushio ◽  
Hiroshi Uchimura ◽  
Yoshikuni Tsuji ◽  
Takayuki Sano ◽  
Tatsuya Yasunaga

1970 ◽  
Vol 68 (2) ◽  
pp. 205-214 ◽  
Author(s):  
Keitaro HIROMI ◽  
Toshio SHIBAOKA ◽  
Sôzaburo ONO

1970 ◽  
Vol 67 (5) ◽  
pp. 749-752 ◽  
Author(s):  
NAOKI HIGASHI ◽  
HIROHUMI SHOUN ◽  
KEITARO HIROMI ◽  
KEIJI YANO ◽  
KEI ARIMA

1984 ◽  
Vol 62 (9) ◽  
pp. 1681-1686 ◽  
Author(s):  
Robert Ménard ◽  
Miklos Zador

The complex formed between acridine orange (AO) and polycytidylic acid (poly(C)) was studied by spectrophotometry and spectrofluorometry. The complex was characterized by its stoichiometry, structure, and the thermodynamic parameters of its formation. The results are in agreement with an external aggregation of the protonated dye along the negatively charged poly(C) chain and indicate that approximately two AO molecules are bound per nucleotide unit of poly(C). The kinetics of the reaction between this complex and a Pd(II) complex was studied by the stopped-flow method. The addition of (dien)Pd(II) to the AO–poly(C) complex leads to the dissociation of the latter, due to fixation of the Pd(II) complex to the N3 site of the cytosine base of poly(C). The rate constant for the AO liberation, extrapolated at zero AO concentration, corresponds to the rate constant of Pd(II) fixation on poly(C). This indicates that AO can be used as an indicator for this reaction and allows kinetic studies at very low concentrations (≤ 5 × 10−6 M).


Sign in / Sign up

Export Citation Format

Share Document