scholarly journals Reaction of Allyl Phenyl Ether over Various Liquid Metal Catalysts

1987 ◽  
Vol 60 (12) ◽  
pp. 4279-4284 ◽  
Author(s):  
Sentaro Ozawa ◽  
Yoshiki Sasaki ◽  
Yoshisada Ogino
Keyword(s):  
Liquid Metal ◽  
Metal Catalysts ◽  
Phenyl Ether ◽  
Allyl Phenyl Ether

Gallium-rich Pd–Ga phases as supported liquid metal catalysts

2017 ◽  
Vol 9 (9) ◽  
pp. 862-867 ◽  
Author(s):  
N. Taccardi ◽  
M. Grabau ◽  
J. Debuschewitz ◽  
M. Distaso ◽  
M. Brandl ◽  
...  
Keyword(s):  
Liquid Metal ◽  
Metal Catalysts

Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcohol

1994 ◽  
Vol 72 (9) ◽  
pp. 1961-1965 ◽  
Author(s):  
Michael T. H. Liu ◽  
Yuri N. Romashin ◽  
T. K. Venkatachalam
Keyword(s):  
Rate Constants ◽  
Allyl Alcohol ◽  
Flash Photolysis ◽  
Laser Flash Photolysis ◽  
Laser Flash ◽  
Phenyl Ether ◽  
High Yield ◽  
Allyl Ethers ◽  
Oxonium Ylide ◽  
Allyl Phenyl Ether

When photolysis of arylchlorodiazirines is performed in the presence of either alkyl- or allyl-substituted amines, either N-alkyl- or N-allyl-substituted amines result as the sole high-yield (64-93%) products. Photolysis in the presence of phenylallylamine produces a rearranged product in poor yield (11–15%) whereas the reaction of allyl alcohol with arylchlorocarbene gives exclusively diallyl acetals in high yield (70%). The rate constants for these reactions were obtained by laser flash photolysis. Allyl phenyl ether forms a cyclopropanated product when treated with arylchlorocarbene. The different behaviour of these compounds may be attributed to the nucleophilicity at the nitrogen and oxygen centres of these compounds, when the latter are subjected to the substitutions described above. The formation of a cyclopropanated product when allyl phenyl ether is used differs from the reaction of bis (methoxycarbonyl) carbene with allyl ethers, as reported in the literature. The formation of this cyclopropanated product demonstrates the absence of an oxonium ylide intermediate during the reaction.

METHODS FOR THE SYNTHESIS OF 2-ATTYTPHENOT AND ALLYL PHENYL ETHER

2018 ◽  
pp. 4-17
Author(s):  
M.M. Antonova ◽  
O.O. Shibkov ◽  
N.A. Kostikova ◽  
A.G. Golikov
Keyword(s):  
Phenyl Ether ◽  
Allyl Phenyl Ether

Polymerization of allyl phenyl ether

1976 ◽  
Vol 14 (11) ◽  
pp. 2689-2694 ◽  
Author(s):  
K. M. Hui ◽  
L. C. Yip
Keyword(s):  
Phenyl Ether ◽  
Allyl Phenyl Ether
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