scholarly journals Kinetic Study of Liquid-Phase Esterification with Sulfonic Acid Cation-Exchange Resin of the Macroreticular Type. I. Heterogeneous–Pseudohomogeneous Resin Catalysis

1986 ◽  
Vol 59 (1) ◽  
pp. 7-11 ◽  
Author(s):  
Shoichi Shimizu ◽  
Choichiro Hirai
1993 ◽  
Vol 24 (5) ◽  
pp. 341-344
Author(s):  
T. V. Nemilova ◽  
O. V. Prisekina ◽  
O. V. Astashkina ◽  
L. V. Emets

1962 ◽  
Vol 1 (2) ◽  
pp. 140-144 ◽  
Author(s):  
Robert Kunin ◽  
E. A. Meitzner ◽  
J. A. Oline ◽  
S. A. Fisher ◽  
Norman Frisch

2012 ◽  
Vol 4 (1) ◽  
pp. 79-82 ◽  
Author(s):  
V. N. Fomin ◽  
S. V. Kotov ◽  
I. M. Zerzeva ◽  
G. V. Timofeeva ◽  
A. V. Tarasov ◽  
...  

2014 ◽  
Vol 900 ◽  
pp. 361-364
Author(s):  
Xiao Hui Wang ◽  
Xi Hua Du ◽  
Li Min Dong

Esters of Citric acid and palmityl alcohol were synthesized by esterification reaction under catalysis of cation exchange resin and P-toluene sulfonic acid respectively. The effects of amount of catalyst, ratio of raw materials, reaction time and temperature on the synthesis reaction were investigated . The experimental results showed that optimum of process conditions were 1:1~1:1.5 molar ratio of citric acid and palmityl alcohol, reaction temperature of 130~140°C, reaction time of 2 h. Conversion of palmityl alcohol were all more than 90% under 0.3% dosage using p-toluene sulfonic acid as the catalyst, or 0.5% dosage using 721 cation exchange resin with sulfonic acid type as catalyst. The synthesized product had good surface activity.


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