scholarly journals An Important Metal Complex in the Asymmetric Synthesis of α-Amino Acids. The Crystal and Molecular Structure of (−)546-((R)-Alaninato)((6R,8R)-6,8-dimethyl-2,5,9,12-tetraazatridecane)cobalt(III) Bromide Trihydrate, (−)546-[Co(R-ala)(1,5R,7R,11-Me4-2,3,2-tet)]Br2·3H2O

1986 ◽  
Vol 59 (7) ◽  
pp. 2255-2261 ◽  
Author(s):  
Morio Yashiro ◽  
Masanobu Ajioka ◽  
Shigenobu Yano ◽  
Koshiro Toriumi ◽  
Tasuku Ito ◽  
...  
1987 ◽  
Vol 17 (3) ◽  
pp. 313-321 ◽  
Author(s):  
L. Menabue ◽  
M. Saladini ◽  
L. P. Battaglia ◽  
A. Bonamartini Corradi ◽  
G. Marcotrigiano ◽  
...  

1985 ◽  
Vol 63 (3) ◽  
pp. 688-691 ◽  
Author(s):  
Brenda M. Louie ◽  
Steven J. Rettig ◽  
Alan Storr ◽  
James Trotter

Details of the synthesis and physical properties of (μ-Cl)(μ-pz)[Rh(CO)2]2 are given. Crystals of (μ-chloro) (μ-pyrazolyl)-bis(dicarbonylrhodiumd(I)) are monoclinic, a = 7.0970(8), b = 20.5184(10), c = 15.808(2) Å, β = 94.695(6)°, Z = 8, space group P21/c. The structure was solved by conventional heavy-atom methods and was refined by full-matrix least-squares procedures to R = 0.035 and Rw = 0.038 for 2949 reflections with I ≥ 3σ(I). The complex provides a rare example of molecular stacking in a binuclear transition metal complex with [Formula: see text] distances of 3.5107(8) and 3.6201(8) Å.


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