scholarly journals A High-Resolution Solid-State23Na NMR Study of Sodium Complexes with Solvents, Small Ligand Molecules, and Ionophores.23Na Chemical Shifts as Means for Identification and Characterization of Ion–Ion, Ion–Solvent, and Ion–Ligand Interactions

1986 ◽  
Vol 59 (6) ◽  
pp. 1957-1966 ◽  
Author(s):  
Ryoko Tabeta ◽  
Misako Aida ◽  
Hazime Saitô
Keyword(s):  
High Resolution ◽  
Chemical Shifts ◽  
Nmr Study ◽  
Sodium Complexes ◽  
Ligand Interactions ◽  
Identification And Characterization

Synthesis and characterization of several series of 4-acyl-1-[2-aryl-1-diazenyl]piperazines

2014 ◽  
Vol 92 (9) ◽  
pp. 838-848 ◽  
Author(s):  
Vanessa Renee Little ◽  
Keith Vaughan
Keyword(s):  
High Resolution ◽  
Ir Spectroscopy ◽  
Chemical Shifts ◽  
Synthesis And Characterization ◽  
Model Compounds ◽  
Primary Aromatic Amine ◽  
Piperazine Ring ◽  
H Nmr ◽  
C Nmr

Five series of a novel class of 4-acyl-1-[2-aryl-1-diazenyl]piperazines have been synthesized and characterized: the 4-acetyl-1-[2-aryl-1-diazenyl]piperazines [series 1]; the 4-cyclohexylcarbonyl-1-[2-aryl-1-diazenyl]piperazines [series 2]; the 4-benzoyl-1-[2-aryl-1-diazenyl]piperazines [series 3]; the benzyl 4-[2-aryl-1-diazenyl]-1-piperazinecarboxylates [series 4]; and the t-butyl 4-[2-aryl-1-diazenyl]-1-piperazinecarboxylates [series 5]. The compounds were synthesized by diazotization of a primary aromatic amine and subsequent coupling to an appropriate secondary amine: 1-acetylpiperazine [series 1]; 1-(cyclohexylcarbonyl)-piperaizine [series 2]; 1-benzoylpiperazine [series 3]; benzyl 1-piperazinecarboxylate [series 4]; and t-butyl piperazine-1-carboxylate (1-BOC-piperazine) [series 5]. The compounds of series 1–5 were characterized by 1H NMR, 13C NMR, high-resolution MS and IR spectroscopy. The model compounds 1,4-di[2-aryl-1-diazenyl]piperazines, and ethyl 4-[2-aryl-1-diazenyl]-1-piperazinecarboxylates were used to facilitate the assignment of the chemical shifts specific to the piperazine ring carbons. HSQC spectra of select compounds established the correlation between proton and carbon resonance signals.

Characterization of the 2,2′-bipyridine chelates of lanthanum(III) in acetonitrile. A 1H, 13C, 17O, and 139La NMR study

1993 ◽  
Vol 71 (3) ◽  
pp. 377-383 ◽  
Author(s):  
Monique Fréchette
Keyword(s):  
Coordination Sphere ◽  
Chemical Shifts ◽  
Complexation Reaction ◽  
Complex Species ◽  
H Nmr ◽  
Nmr Data ◽  
Nmr Study ◽  
Close Proximity ◽  
Coordinated Water

We have investigated the reaction between La(NO3)3•6H2O and 2,2′-bipyridine (bipy) in acetonitrile by means of 139La, 17O, 13C, and 1H NMR spectroscopy. The 139La spectra show up to three different sites with variable intensities attributed to solvated La(III) ions and to two complex species with one or two bipy moieties in the La(III) coordination sphere. 17O NMR indicates that during the complexation reaction, the coordinated water is totally displaced from the coordination sphere whereas the nitrate groups remain coordinated. Proton NMR data confirm the water expulsion. In addition, the proton chemical shifts of bipy, in comparison with the 13C NMR data, clearly show an anisotropic shielding when two bipy are coordinated to La(III). Therefore, the two bipy molecules are in close proximity in the coordination sphere. From the NMR results it has been shown that, during the complexation process, five different La(III) species are formed: [La(NO3)3(CH3CN)4], [La(NO3)3(CH3CN)3(H2O)], [La(NO3)3(bipy)(CH3CN)2], [La(NO3)3(bipy)(CH3CN)-(H2O)], and [La(NO3)3(bipy)2]. Each La(III) complex has a coordination member of 10, with NO3− and bipy acting as chelating ligands. Furthermore, the structure of the La(NO3)3(bipy)2 complex in solution shows similarities with the solid state compound. Finally, comparisons are made with the La(III) complexes previously obtained with 1,10-phenanthroline.

scholarly journals On the Identification and Characterization of Drought and Aridity in Postglacial Paleoenvironmental Records from the Northern Great Plains

2004 ◽  
Vol 56 (2-3) ◽  
pp. 229-246 ◽  
Author(s):  
Alwynne B. Beaudoin
Keyword(s):  
Global Warming ◽  
High Resolution ◽  
Great Plains ◽  
Northern Great Plains ◽  
Short Term ◽  
Instrumental Data ◽  
Proxy Records ◽  
Identification And Characterization

Abstract The Northern Great Plains region is especially sensitive to drought and is likely to be even more drought-prone under projected global warming. Drought has been invoked as an explanatory factor for changes seen in postglacial paleoenvironmental records. These proxy records may extend drought history derived from instrumental data. Moreover, in the last decade, some paleoenvironmental studies have been expressly undertaken for the examination of long-term drought history. Nevertheless, few such studies explicitly define drought. This makes it difficult to compare results or to understand what the results mean in terms of the operational drought definitions that are used in resource management. Operational drought is defined as usually short-term; longer sustained dry intervals reflect a shift to aridity. Therefore, high resolution paleoenvironmental proxies (annual or subdecadal) are best for the investigation of drought history. Such proxies include tree rings and some lake records. However, most lake-based records are sampled at lower resolution (decadal or subcentury) and are therefore providing aridity signals.

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