scholarly journals Alteration of Reaction Course in Thermolysis ofcis-Diethylbis(tertiary phosphine)palladium(II) from Reductive Elimination to β-Elimination Process Induced by Addition of Tertiary Phosphine Ligand

1985 ◽  
Vol 58 (1) ◽  
pp. 399-400 ◽  
Author(s):  
Fumiyuki Ozawa ◽  
Kunihiko Kurihara ◽  
Takakazu Yamamoto ◽  
Akio Yamamoto
Keyword(s):  
Reductive Elimination ◽  
Phosphine Ligand ◽  
Tertiary Phosphine ◽  
Elimination Process

A trigonal and hindered tertiary phosphine ligand rendered anionic by a niobate anchor: Formation of zwitterionic M(i) (M = Cu, Ag, Au, Rh) complexes

2011 ◽  
Vol 2 (11) ◽  
pp. 2166 ◽  
Author(s):  
Sidney E. Creutz ◽  
Ivo Krummenacher ◽  
Christopher R. Clough ◽  
Christopher C. Cummins
Keyword(s):  
Phosphine Ligand ◽  
Tertiary Phosphine

Iodobenzene-Catalyzed Oxidative Cyclization for the Synthesis of Highly Functionalized Cyclopropanes

Synthesis ◽  
2020 ◽  
Vol 52 (06) ◽  
pp. 928-932
Author(s):  
Yang Li ◽  
Hao Guo ◽  
Renhua Fan
Keyword(s):  
Ligand Exchange ◽  
Reductive Elimination ◽  
Oxidative Cyclization ◽  
Elimination Process ◽  
Michael Adducts

An iodobenzene-catalyzed oxidative cyclization of Michael adducts of activated methylene compounds with nitroolefins or chalcones is developed. mCPBA is used as oxidant together with Bu4NI for the generation of a highly reactive iodine(III) species to mediate the cyclopropanation via a ligand exchange and reductive elimination process. A range of highly functionalized cyclopropanes are synthesized with high diastereoselectivities.

Sign in / Sign up

Export Citation Format

Share Document