scholarly journals Fischer Tropsch Reaction over Reduced Molybdenum Catalysts Derived from Various Heteropoly Compounds

1985 ◽  
Vol 58 (1) ◽  
pp. 236-241 ◽  
Author(s):  
Hiroshi Miura ◽  
Hitoshi Ishiguro ◽  
Masashi Osawa ◽  
Kazunori Sasagawa ◽  
Kazuo Sugiyama ◽  
...  
Keyword(s):  
Heteropoly Compounds ◽  
Fischer Tropsch ◽  
Molybdenum Catalysts

Fischer-Tropsch waxes VII. The thermal conductivity of hard wax

1974 ◽  
Vol 24 (1-2) ◽  
pp. 81-91 ◽  
Author(s):  
Johannes H. Le Roux ◽  
Roy D. F. Smith ◽  
Richard Turner ◽  
Onno Weidema
Keyword(s):  
Thermal Conductivity ◽  
Fischer Tropsch

HEAT EXPLOSION IN FISCHER-TROPSCH CATALYTIC GRANULE WITH LOCALIZED COBALT MICROPARTICLES

2018 ◽  
Author(s):  
Igor V. Derevich ◽  
V. Ermolaev ◽  
V. Mordkovich ◽  
I. Solomonik ◽  
A. Fokina
Keyword(s):  
Fischer Tropsch

Carbon Chain Growth by Sequential Reactions of CO and CO2 with a Transition Metal Carbonyl Complex

2018 ◽  
Author(s):  
Richard Kong ◽  
Mark Crimmin
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbon Chain ◽  
Chain Growth ◽  
Carbonyl Complex ◽  
Fischer Tropsch ◽  
Carbon Chains ◽  
Sequential Coupling ◽  
Energy Economy ◽  
Sequential Reactions

<i>The formation of carbon chains by the coupling of COx (X = 1 or 2) units on transition metals is a fundamental step relevant to Fischer-Tropsch catalysis. Fischer-Tropsch catalysis produces energy dense liquid hydrocarbons from synthesis gas (CO and H2) and has been a mainstay of the energy economy since its discovery nearly a century ago. Despite detailed studies aimed at elucidating the steps of catalysis, experimental evidence for chain growth (Cn to Cn+1 ; n > 2) from the reaction of CO with metal complexes is unprecedented. In this paper, we show that carbon chains can be grown from sequential reactions of CO or CO2 with a transition metal carbonyl complex. By exploiting the cooperative effect of transition and main group metals, we document the first example of chain propagation from sequential coupling of CO units (C1 to C3 to C4), along with the first example of incorporation of CO2 into the growing carbon chain.</i><br>

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