scholarly journals Radical Formation through Curing Reaction of Epoxy Resins with 2,4,6-Trinitrophenol or 2,4,6-Trinitroresorcinol

1983 ◽  
Vol 56 (3) ◽  
pp. 676-679 ◽  
Author(s):  
Kazuro Kawamura
2011 ◽  
Vol 216 ◽  
pp. 34-38
Author(s):  
Jun Gang Gao ◽  
Xiao Na Zhang ◽  
Yong Gang Du

Three class of novel liquid crystalline epoxy resins containing azomething groups: N,N’-Bis[4-(2,3-epoxypropoxy)benzylidene]-4,4-diamino-diphenyl ether (p-BEPBDDE), N,N’-Bis[4-(2,3-epoxypropoxy)benzylidene]-4,4-diamino-diphenyl methane (p-BEPBDDM) and N,N’-Bis[(4-(2,3-epoxypropoxy)-benzyliden)-1,4- phenylene diamine] (p-BEPBPD) were synthesized and characterized. The results show that p-BEBDDE and p-BEBDDM belong to smectic texture and melting point is 239.5 and 178 oC, respectively. The p-BEPBD is nematic texture between its melting temperature (Tm) of 192 oC and clearing temperature (Ti) of 238 oC. The curing reaction can be described by Ozawa equation, and the alcohol-hydroxyl group can accelerate the curing reaction and decrease Ea in DSC experiment.


2018 ◽  
Vol 2018 (1) ◽  
pp. 000344-000348
Author(s):  
Eric Ouyang ◽  
Billy Ahn ◽  
SeonMo Gu ◽  
Jim Hsu ◽  
Yonghyuk Jeong ◽  
...  

Abstract In this paper, the impact of two different types of warpage, strip warpage and system-in-packages (SiP) module warpage, are considered and studied, both experimentally and numerically. An advanced material characterization method is also conducted to study the curing reaction and Pressure-Volume-Temperature-Cure (PVTC) kinetics of the packages. The curing reaction of epoxy resins, as a function of temperature and activation energies, is experimentally determined. During the curing process, the viscosity of epoxy resins change with temperature and conversion rate. The Castro-Macosko model is adopted to describe the rheological properties of epoxy resins. Experimentally, we have prepared substrate strip samples with different component density and molding compound materials. Each substrate strip contains eighteen system-in-packages. The warpages of all substrate strips and all the system-in-package modules were measured, compared, and correlated.


2012 ◽  
Vol 28 (2) ◽  
pp. 131-139 ◽  
Author(s):  
Yong-Seok Choi ◽  
You-Jin Park ◽  
Yong-Soo Kang ◽  
Jong-Ok Won ◽  
Jeong-Jin Kim ◽  
...  

2013 ◽  
Vol 702 ◽  
pp. 119-122
Author(s):  
Teng Fei Shen ◽  
Fa Chao Wu ◽  
Ying Juan Sun

A series of novel azo-containing twin liquid crystalline (LC) epoxy monomers were cured with anhydrides without extra catalyst and the curing kinetics was investigated by non-isothermal differential scanning calorimetry (DSC) technique. The effect of Azo group on the Curing Kinetics of Epoxy/anhydride System was investigated and the result showed that Azo group served as a catalyst to accelerate the curing reaction. The curing mechanism was confirmed by the UV-Vis spectrum.


1997 ◽  
Vol 36 (8) ◽  
pp. 2976-2983 ◽  
Author(s):  
Giovanni Micco ◽  
Marta Giamberini ◽  
Eugenio Amendola ◽  
Cosimo Carfagna ◽  
Gianni Astarita

1979 ◽  
Vol 19 (4) ◽  
pp. 313-318 ◽  
Author(s):  
G. A. Senich ◽  
W. J. MacKnight ◽  
N. S. Schneider

Sign in / Sign up

Export Citation Format

Share Document