Stereoselective Epoxidation of Allylic Alcohols and Dehydrogenative Oxidation of Secondary Alcohols by Means oft-Butyl Hydroperoxide and Aluminium Reagents

Kazuhiko Takai; Koichiro Oshima; Hitosi Nozaki

doi:10.1246/bcsj.56.3791

Stereoselective Epoxidation of Allylic Alcohols and Dehydrogenative Oxidation of Secondary Alcohols by Means oft-Butyl Hydroperoxide and Aluminium Reagents

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.56.3791 ◽

1983 ◽

Vol 56 (12) ◽

pp. 3791-3795 ◽

Cited By ~ 21

Author(s):

Kazuhiko Takai ◽

Koichiro Oshima ◽

Hitosi Nozaki

Keyword(s):

Allylic Alcohols ◽

Secondary Alcohols ◽

Butyl Hydroperoxide ◽

Stereoselective Epoxidation

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ChemInform Abstract: STEREOSELECTIVE EPOXIDATION OF ALLYLIC ALCOHOLS AND DEHYDROGENATIVE OXIDATION OF SECONDARY ALCOHOLS BY MEANS OF TERT-BUTYL HYDROPEROXIDE AND ALUMINUM REAGENTS

Chemischer Informationsdienst ◽

10.1002/chin.198414115 ◽

1984 ◽

Vol 15 (14) ◽

Author(s):

K. TAKAI ◽

K. OSHIMA ◽

H. NOZAKI

Keyword(s):

Allylic Alcohols ◽

Secondary Alcohols ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Tert Butyl Hydroperoxide ◽

Stereoselective Epoxidation

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Chiral hydroxamic acids as ligands in the vanadium catalyzed asymmetric epoxidation of allylic alcohols by tert-butyl hydroperoxide

Journal of the American Chemical Society ◽

10.1021/ja00448a059 ◽

1977 ◽

Vol 99 (6) ◽

pp. 1990-1992 ◽

Cited By ~ 147

Author(s):

R. C. Michaelson ◽

R. E. Palermo ◽

K. B. Sharpless

Keyword(s):

Hydroxamic Acids ◽

Asymmetric Epoxidation ◽

Allylic Alcohols ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Tert Butyl Hydroperoxide

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An analysis of the diastereomeric transition state interactions for stereoselective epoxidation of acyclic allylic alcohols with peroxy-acids

Tetrahedron Letters ◽

10.1016/s0040-4039(01)92893-x ◽

1981 ◽

Vol 22 (21) ◽

pp. 2017-2020 ◽

Cited By ~ 45

Author(s):

Acharan S. Narula

Keyword(s):

Transition State ◽

Allylic Alcohols ◽

Stereoselective Epoxidation ◽

Peroxy Acids

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ChemInform Abstract: Cobalt-Catalyzed Selective Oxidation of Benzylic and Allylic Alcohols by tert-Butyl Hydroperoxide.

ChemInform ◽

10.1002/chin.199543085 ◽

2010 ◽

Vol 26 (43) ◽

pp. no-no

Author(s):

S. IYER ◽

J. P. VARGHESE

Keyword(s):

Selective Oxidation ◽

Allylic Alcohols ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Tert Butyl Hydroperoxide

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Chiral Hydroperoxides as Oxygen Source in the Catalytic Stereoselective Epoxidation of Allylic Alcohols by Sandwich-Type Polyoxometalates: Control of Enantioselectivity through a Metal-Coordinated Template

The Journal of Organic Chemistry ◽

10.1021/jo034923z ◽

2003 ◽

Vol 68 (21) ◽

pp. 8222-8231 ◽

Cited By ~ 64

Author(s):

Waldemar Adam ◽

Paul L. Alsters ◽

Ronny Neumann ◽

Chantu R. Saha-Möller ◽

Dieter Seebach ◽

...

Keyword(s):

Allylic Alcohols ◽

Sandwich Type ◽

Stereoselective Epoxidation ◽

Sandwich Type Polyoxometalates

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Cu(II) 2-quinoxalinol salen catalyzed oxidation of propargylic, benzylic, and allylic alcohols using tert-butyl hydroperoxide in aqueous solutions

Tetrahedron ◽

10.1016/j.tet.2014.08.050 ◽

2014 ◽

Vol 70 (43) ◽

pp. 7962-7968 ◽

Cited By ~ 12

Author(s):

Kushan C. Weerasiri ◽

Anne E.V. Gorden

Keyword(s):

Aqueous Solutions ◽

Allylic Alcohols ◽

Butyl Hydroperoxide ◽

Tert Butyl ◽

Tert Butyl Hydroperoxide ◽

Catalyzed Oxidation

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Reaction of Allylic Alcohols with -Butyl Hydroperoxide Catalyzed by a Polyoxometalate

Category 5, Compounds with One Saturated Carbon Heteroatom Bond ◽

10.1055/sos-sd-038-00254 ◽

2009 ◽

pp. 1

Author(s):

I. N. Lykakis ◽

M. Stratakis

Keyword(s):

Allylic Alcohols ◽

Butyl Hydroperoxide

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1,2-Addition of Alkyl- and Alkenylzirconocene Chlorides to Aldehydes Accelerated by Catalytic Amounts of ZnBr2 as a Method of Synthesizing Secondary Alcohols, Secondary Allylic Alcohols, and in-Situ Oppenauer-Type Oxidation of the Alcohols to Ketones

The Journal of Organic Chemistry ◽

10.1021/jo00116a007 ◽

1995 ◽

Vol 60 (11) ◽

pp. 3278-3279 ◽

Cited By ~ 26

Author(s):

Bin Zheng ◽

Morris Srebnik

Keyword(s):

Allylic Alcohols ◽

Secondary Alcohols

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ChemInform Abstract: An Efficient, Practical Method for Preparation of Optically Active erythro-Epoxy Secondary Alcohols Using Sharpless Kinetic Resolution of β-Trimethylsilyl Secondary Allylic Alcohols.

ChemInform ◽

10.1002/chin.198717180 ◽

1987 ◽

Vol 18 (17) ◽

Author(s):

Y. KITANO ◽

T. MATSUMOTO ◽

Y. TAKEDA ◽

F. SATO

Keyword(s):

Kinetic Resolution ◽

Practical Method ◽

Optically Active ◽

Allylic Alcohols ◽

Secondary Alcohols

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Synthesis of Z allylic alcohols with 1,4-related chiral centres by stereoselective epoxidation and the horner-wittig reaction

Tetrahedron Letters ◽

10.1016/0040-4039(91)85057-c ◽

1991 ◽

Vol 32 (48) ◽

pp. 7123-7126 ◽

Cited By ~ 15

Author(s):

David Hall ◽

Anne-Françoise Sévin ◽

Stuart Warren

Keyword(s):

Wittig Reaction ◽

Allylic Alcohols ◽

Stereoselective Epoxidation

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