Synergistic Solvent Extraction of Alkali Metal Picrates by Crown Ethers

Yasuyuki Takeda

doi:10.1246/bcsj.54.526

Synergistic Solvent Extraction of Alkali Metal Picrates by Crown Ethers

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.54.526 ◽

1981 ◽

Vol 54 (2) ◽

pp. 526-529 ◽

Cited By ~ 20

Author(s):

Yasuyuki Takeda

Keyword(s):

Solvent Extraction ◽

Alkali Metal ◽

Crown Ethers ◽

Synergistic Solvent Extraction

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Synergistic Solvent Extraction of Trivalent Lanthanoids with Mixtures of 1‐Phenyl‐3‐methyl‐4‐pivaloyl‐5‐pyrazolone and Crown Ethers

Solvent Extraction and Ion Exchange ◽

10.1081/sei-120025924 ◽

2003 ◽

Vol 21 (6) ◽

pp. 797-813 ◽

Cited By ~ 14

Author(s):

Rani Pavithran ◽

R. Luxmi Varma ◽

M. L. P. Reddy

Keyword(s):

Solvent Extraction ◽

Crown Ethers ◽

Synergistic Solvent Extraction

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RING-SIZE AND SUBSTTTUENT EFFECTS IN THE SOLVENT EXTRACTION OF ALKALI METAL NITRATES BY CROWN ETHERS IN 1,2-DICHLOROETHANE AND 1 -OCTANOL

Solvent Extraction and Ion Exchange ◽

10.1080/07366299608918379 ◽

1996 ◽

Vol 14 (6) ◽

pp. 995-1015 ◽

Cited By ~ 18

Author(s):

Richard A. Sachleben* ◽

Yanpei Deng ◽

Darla R. Bailey ◽

Bruce A. Moyer

Keyword(s):

Solvent Extraction ◽

Alkali Metal ◽

Crown Ethers ◽

Ring Size ◽

Metal Nitrates

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ChemInform Abstract: New Applications of Crown Ethers. Part 6. Structural Effects of Bis(benzocrown ether)s and Substituted Benzocrown Ethers on Solvent Extraction and Complexation of Alkali Metal Cations.

ChemInform ◽

10.1002/chin.198724062 ◽

1987 ◽

Vol 18 (24) ◽

Author(s):

K. KIKUKAWA ◽

G.-X. HE ◽

A. ABE ◽

T. GOTO ◽

R. ARATA ◽

...

Keyword(s):

Solvent Extraction ◽

Alkali Metal ◽

Crown Ethers ◽

Metal Cations ◽

Alkali Metal Cations ◽

Structural Effects ◽

Benzocrown Ethers ◽

New Applications

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New applications of crown ethers. Part 6. Structural effects of bis(benzocrown ether)s and substituted benzocrown ethers on solvent extraction and complexation of alkali-metal cations

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29870000135 ◽

1987 ◽

pp. 135 ◽

Cited By ~ 42

Author(s):

Kiyoshi Kikukawa ◽

Gong-Xin He ◽

Akito Abe ◽

Tokio Goto ◽

Ryozo Arata ◽

...

Keyword(s):

Solvent Extraction ◽

Alkali Metal ◽

Crown Ethers ◽

Metal Cations ◽

Alkali Metal Cations ◽

Structural Effects ◽

Benzocrown Ethers ◽

New Applications

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SYNERGISTIC SOLVENT EXTRACTION OF TRIVALENT LANTHANIDES WITH MIXTURES OF 3-PHENYL-4-BENZOYL-5-ISOXAZOLONE AND CROWN ETHERS

Solvent Extraction and Ion Exchange ◽

10.1080/07366299708934465 ◽

1997 ◽

Vol 15 (1) ◽

pp. 49-64 ◽

Cited By ~ 18

Author(s):

M.L.P. Reddy ◽

R. Luxmi Varma ◽

T.R. Ramamohan ◽

A.D. Damodaran ◽

Punam Thakur ◽

...

Keyword(s):

Solvent Extraction ◽

Crown Ethers ◽

Trivalent Lanthanides ◽

Synergistic Solvent Extraction

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ANION EFFECT ON SELECTIVITY IN SOLVENT EXTRACTION OF ALKALI METAL SALTS BY CROWN ETHERS

Solvent Extraction and Ion Exchange ◽

10.1080/07366299508918313 ◽

1995 ◽

Vol 13 (6) ◽

pp. 983-995 ◽

Cited By ~ 10

Author(s):

Matthew G. Hankins ◽

Richard A. Bartsch∗ ◽

Uriel Olsher

Keyword(s):

Solvent Extraction ◽

Alkali Metal ◽

Crown Ethers ◽

Metal Salts ◽

Alkali Metal Salts ◽

Anion Effect

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EFFECTS OF STRUCTURAL VARIATION WITHIN PROTON-IONIZABLE CROWN ETHERS UPON THE SELECTIVITY AND EFFICIENCY OF SOLVENT EXTRACTION OF ALKALI METAL AND ALKALINE EARTH CATIONS

Solvent Extraction and Ion Exchange ◽

10.1080/07360298908962340 ◽

1989 ◽

Vol 7 (5) ◽

pp. 829-854 ◽

Cited By ~ 40

Author(s):

Richard A. Bartsch

Keyword(s):

Solvent Extraction ◽

Alkali Metal ◽

Crown Ethers ◽

Alkaline Earth ◽

Structural Variation ◽

Alkaline Earth Cations

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Synergistic Solvent Extraction of Crown Ether Complexes with Alkali Metal Picrates by Neutral Donor Solvents

Heterocycles ◽

10.3987/s-1984-02-0376 ◽

1984 ◽

Vol 21 (2) ◽

pp. 376

Author(s):

Yasuyuki Takeda

Keyword(s):

Solvent Extraction ◽

Crown Ether ◽

Alkali Metal ◽

Neutral Donor ◽

Crown Ether Complexes ◽

Synergistic Solvent Extraction

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Synergistic Solvent Extraction of Crown Ether Complexes with Alkali Metal Picrates by Neutral Donor Solvents

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.56.2589 ◽

1983 ◽

Vol 56 (9) ◽

pp. 2589-2590 ◽

Cited By ~ 11

Author(s):

Yasuyuki Takeda

Keyword(s):

Solvent Extraction ◽

Crown Ether ◽

Alkali Metal ◽

Neutral Donor ◽

Crown Ether Complexes ◽

Synergistic Solvent Extraction

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Effect of crown ethers on the solvent extraction and separation of lanthanide(III) ions with 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one

Chemical Papers ◽

10.2478/s11696-008-0012-4 ◽

2008 ◽

Vol 62 (2) ◽

Cited By ~ 6

Author(s):

Maria Petrova ◽

Ivan Dukov

Keyword(s):

Experimental Data ◽

Solvent Extraction ◽

Crown Ethers ◽

Synergistic Effects ◽

Equilibrium Constants ◽

Chloride Medium ◽

Extraction And Separation ◽

Separation Factors ◽

Aqueous Chloride ◽

Synergistic Solvent Extraction

AbstractSynergistic solvent extraction of 14 lanthanides with mixtures of 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one (HP) and the crown ethers (S), 18-crown-6, benzo-18-crown-6 or dibenzo-18-crown-6 from an aqueous chloride medium with the constant ionic strength of 0.1 mol dm−3 was investigated using benzene as a diluent. The composition of the species extracted was determined as LnP3 · S. The addition of a crown ether to the chelating extractant produced rather significant synergistic effects. On basis of experimental data, values of equilibrium constants, synergistic coefficients, and separation factors were calculated.

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