Nitration of Hexamethylbenzene and Hexamethylbenzene-d18in Acetic Acid. Deuterium Isotope Effect on the Product Distribution. Mechanism of Side-chain Substitution of Arenes

Hitomi Suzuki; Tadashi Mishina; Terukiyo Hanafusa

doi:10.1246/bcsj.52.191

Nitration of Hexamethylbenzene and Hexamethylbenzene-d18in Acetic Acid. Deuterium Isotope Effect on the Product Distribution. Mechanism of Side-chain Substitution of Arenes

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.52.191 ◽

1979 ◽

Vol 52 (1) ◽

pp. 191-197 ◽

Cited By ~ 8

Author(s):

Hitomi Suzuki ◽

Tadashi Mishina ◽

Terukiyo Hanafusa

Keyword(s):

Acetic Acid ◽

Isotope Effect ◽

Product Distribution ◽

Side Chain ◽

Deuterium Isotope Effect

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Mechanistic duality of the side-chain substitution in electrophilic aromatic nitration. Unexpected large difference in deuterium isotope effect kH/kD between the side-chain nitration and nitrooxylation of deuterated p-xylenes

Tetrahedron Letters ◽

10.1016/s0040-4039(99)02053-5 ◽

2000 ◽

Vol 41 (2) ◽

pp. 229-233

Author(s):

Nobuaki Nonoyama ◽

Masao Iwaya ◽

Hitomi Suzuki

Keyword(s):

Isotope Effect ◽

Side Chain ◽

Deuterium Isotope Effect ◽

Aromatic Nitration

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ChemInform Abstract: Intra- and Inter-molecular Hydron Abstraction from Allylic Carbocation Intermediates in Aqueous Solvent. Observation of a Substantial Deuterium Isotope Effect for 1,4-Elimination of Acetic Acid from One of the Ion-pair Intermediates

Chemischer Informationsdienst ◽

10.1002/chin.198623089 ◽

1986 ◽

Vol 17 (23) ◽

Author(s):

A. THIBBLIN

Keyword(s):

Acetic Acid ◽

Isotope Effect ◽

Ion Pair ◽

Deuterium Isotope Effect ◽

Aqueous Solvent

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The Deuterium Isotope Effect in the Side Chain Halogenation of Toluene1

Journal of the American Chemical Society ◽

10.1021/ja01545a034 ◽

1958 ◽

Vol 80 (12) ◽

pp. 3033-3039 ◽

Cited By ~ 45

Author(s):

Kenneth B. Wiberg ◽

Lynn H. Slaugh

Keyword(s):

Isotope Effect ◽

Side Chain ◽

Deuterium Isotope Effect

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The kinetics and mechanisms of aromatic halogen substitution. Part XXVI. Confirmation of the existence of a solvent deuterium isotope effect in the bromination of phenol in acetic acid

Journal of the Chemical Society B Physical Organic ◽

10.1039/j29670000251 ◽

1967 ◽

pp. 251 ◽

Cited By ~ 3

Author(s):

P. B. D. de la Mare ◽

O. M. H. El Dusouqui

Keyword(s):

Acetic Acid ◽

Isotope Effect ◽

Deuterium Isotope Effect

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Intra- and inter-molecular hydron abstraction from allylic carbocation intermediates in aqueous solvent. Observation of a substantial deuterium isotope effect for 1,4-elimination of acetic acid from one of the ion-pair intermediates

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29860000321 ◽

1986 ◽

pp. 321 ◽

Cited By ~ 2

Author(s):

Alf Thibblin

Keyword(s):

Acetic Acid ◽

Isotope Effect ◽

Ion Pair ◽

Deuterium Isotope Effect ◽

Aqueous Solvent

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3D0924 New NMR method for studying the side-chain OH/SH groups in proteins using the deuterium isotope effect on adjacent carbon chemical shifts(3D Protein: Structure & Function 2,The 49th Annual Meeting of the Biophysical Society of Japan)

Seibutsu Butsuri ◽

10.2142/biophys.51.s117_2 ◽

2011 ◽

Vol 51 (supplement) ◽

pp. S117

Author(s):

Mitsuhiro Takeda ◽

Chun-Jing Yang ◽

Jee JunGoo ◽

Akira Ono ◽

Tsutomu Terauchi ◽

...

Keyword(s):

Protein Structure ◽

Structure Function ◽

Annual Meeting ◽

Isotope Effect ◽

Chemical Shifts ◽

Side Chain ◽

Deuterium Isotope Effect ◽

3D Protein Structure ◽

Nmr Method ◽

Biophysical Society

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Deuterium isotope effect on vibrational dynamics in molecular crystals: picosecond experiments on variously deuterated naphthalenes

Journal de Chimie Physique ◽

10.1051/jcp/1985820159 ◽

1985 ◽

Vol 82 ◽

pp. 159-168 ◽

Cited By ~ 14

Author(s):

E.L. Chronister ◽

J.R. Hill ◽

D.D. Dlott

Keyword(s):

Isotope Effect ◽

Molecular Crystals ◽

Deuterium Isotope Effect ◽

Vibrational Dynamics

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alpha-Hydroxylation of fatty acids in brain. Substrate specificity and deuterium isotope effect.

Journal of Biological Chemistry ◽

10.1016/s0021-9258(19)63332-6 ◽

1977 ◽

Vol 252 (15) ◽

pp. 5206-5210

Author(s):

S Murad ◽

R H Chen ◽

Y Kishimoto

Keyword(s):

Fatty Acids ◽

Substrate Specificity ◽

Isotope Effect ◽

Deuterium Isotope Effect

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ChemInform Abstract: SOLVENT DEUTERIUM ISOTOPE EFFECT ON HYDROLYSIS OF BORIC ACID

Chemischer Informationsdienst ◽

10.1002/chin.197826021 ◽

1978 ◽

Vol 9 (26) ◽

Author(s):

M. MAEDA ◽

Y. SUNAOKA ◽

H. KAKIHANA

Keyword(s):

Boric Acid ◽

Isotope Effect ◽

Deuterium Isotope Effect ◽

Hydrolysis Of

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The Secondary β-Deuterium Isotope Effect and the Cage Effect in the Thermal Decomposition of Azobis-α-phenylethane1

Journal of the American Chemical Society ◽

10.1021/ja00968a018 ◽

1966 ◽

Vol 88 (16) ◽

pp. 3775-3781 ◽

Cited By ~ 16

Author(s):

Stanley Seltzer ◽

Edwin J. Hamilton

Keyword(s):

Thermal Decomposition ◽

Isotope Effect ◽

Cage Effect ◽

Deuterium Isotope Effect

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