Aromatic Nucleophilic Substitution. X. Confirmation of the Anionic σ Complex in the Base-catalyzed Smiles Rearrangement of 2-(Acetylamino)ethyl 2,4-Dinitrophenyl Ether in Dimethyl Sulfoxide

Keiji Okada; Kohji Matsui; Shizen Sekiguchi

doi:10.1246/bcsj.51.2601

Aromatic Nucleophilic Substitution. X. Confirmation of the Anionic σ Complex in the Base-catalyzed Smiles Rearrangement of 2-(Acetylamino)ethyl 2,4-Dinitrophenyl Ether in Dimethyl Sulfoxide

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.51.2601 ◽

1978 ◽

Vol 51 (9) ◽

pp. 2601-2604 ◽

Cited By ~ 5

Author(s):

Keiji Okada ◽

Kohji Matsui ◽

Shizen Sekiguchi

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Aromatic Nucleophilic Substitution ◽

Smiles Rearrangement

Download Full-text

ChemInform Abstract: AROMATIC NUCLEOPHILIC SUBSTITUTION. X. CONFIRMATION OF THE ANIONIC Σ COMPLEX IN THE BASE-CATALYZED SMILES REARRANGEMENT OF 2-(ACETYLAMINO)ETHYL 2,4-DINITROPHENYL ETHER IN DIMETHYL SULFOXIDE

Chemischer Informationsdienst ◽

10.1002/chin.197850099 ◽

1978 ◽

Vol 9 (50) ◽

Author(s):

K. OKADA ◽

K. MATSUI ◽

S. SEKIGUCHI

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Aromatic Nucleophilic Substitution ◽

Smiles Rearrangement

Download Full-text

Aromatic nucleophilic substitution. 27. Aromatic nucleophilic substitution reactions of 1-(alkylamino)-2,4-dinitronaphthalenes with various primary amines in dimethyl sulfoxide

The Journal of Organic Chemistry ◽

10.1021/jo00293a029 ◽

1990 ◽

Vol 55 (6) ◽

pp. 1829-1834 ◽

Cited By ~ 8

Author(s):

Shizen Sekiguchi ◽

Tohru Suzuki ◽

Yukitoshi Hirosawa ◽

Hiromi Ishikura

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Primary Amines ◽

Substitution Reactions ◽

Aromatic Nucleophilic Substitution ◽

Nucleophilic Substitution Reactions

Download Full-text

ChemInform Abstract: Aromatic Nucleophilic Substitution Reactions of 1-Dialkylamino-2,4-dinitronaphthalenes with Various Amines in Dimethyl Sulfoxide. Part 26.

ChemInform ◽

10.1002/chin.199010070 ◽

1990 ◽

Vol 21 (10) ◽

Author(s):

S. SEKIGUCHI ◽

T. SUZUKI ◽

M. HOSOKAWA

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Substitution Reactions ◽

Aromatic Nucleophilic Substitution ◽

Nucleophilic Substitution Reactions

Download Full-text

Aromatic nucleophilic substitution reactions of 1-dialkylamino-substituted activated benzenes with various amines in dimethyl sulfoxide

Tetrahedron ◽

10.1016/s0040-4020(01)87755-3 ◽

1990 ◽

Vol 46 (16) ◽

pp. 5567-5578 ◽

Cited By ~ 9

Author(s):

Shizen Sekiguchi ◽

Hiromi Ishikura ◽

Yukitoshi Hirosawa ◽

Nobuyuki Ono

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Substitution Reactions ◽

Aromatic Nucleophilic Substitution ◽

Nucleophilic Substitution Reactions

Download Full-text

ChemInform Abstract: Aromatic Nucleophilic Substitution. Part 27. Aromatic Nucleophilic Substitution Reactions of 1-(Alkylamino)-2,4-dinitronaphthalenes with Various Primary Amines in Dimethyl Sulfoxide.

ChemInform ◽

10.1002/chin.199034109 ◽

1990 ◽

Vol 21 (34) ◽

Author(s):

S. SEKIGUCHI ◽

T. SUZUKI ◽

Y. HIROSAWA ◽

H. ISHIKURA

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Primary Amines ◽

Substitution Reactions ◽

Aromatic Nucleophilic Substitution ◽

Nucleophilic Substitution Reactions

Download Full-text

Aromatic Nucleophilic Substitution. XV. Stopped-flow Kinetics of the Formation and Decomposition of 1,3- and 1,1-Disubstituted Meisenheimer Complexes in the Reactions of 1-Dialkylamino-2,4-dinitronaphthalenes with Potassium Methoxide in Dimethyl Sulfoxide-Methanol

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.54.3009 ◽

1981 ◽

Vol 54 (10) ◽

pp. 3009-3014 ◽

Cited By ~ 2

Author(s):

Shizen Sekiguchi ◽

Toshio Takei ◽

Kohji Matsui ◽

Noboru Tone ◽

Noboru Tomoto

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Stopped Flow ◽

Aromatic Nucleophilic Substitution ◽

Potassium Methoxide ◽

Meisenheimer Complexes ◽

Stopped Flow Kinetics ◽

Kinetics Of

Download Full-text

Dibenzo[b,f]pyrazolo[1,5-d][1,4]oxazepines: Facile Construction of a Rare Heterocyclic System via Tandem Aromatic Nucleophilic Substitution-Smiles Rearrangement-Denitrocyclization

Synthesis ◽

10.1055/s-0031-1289789 ◽

2012 ◽

Vol 44 (15) ◽

pp. 2401-2407 ◽

Cited By ~ 12

Author(s):

Mikhail Krasavin ◽

Alexander Sapegin ◽

Stanislav Kalinin ◽

Alexey Smirnov ◽

Mikhail Dorogov

Keyword(s):

Nucleophilic Substitution ◽

Heterocyclic System ◽

Aromatic Nucleophilic Substitution ◽

Smiles Rearrangement

Download Full-text

ChemInform Abstract: Aromatic Nucleophilic Substitution. Part 29. Aromatic Nucleophilic Substitution Reactions of 1-Dialkylamino-Substituted Activated Benzenes with Various Amines in Dimethyl Sulfoxide.

ChemInform ◽

10.1002/chin.199052072 ◽

1990 ◽

Vol 21 (52) ◽

Author(s):

S. SEKIGUCHI ◽

H. ISHIKURA ◽

Y. HIROSAWA ◽

N. ONO

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Substitution Reactions ◽

Aromatic Nucleophilic Substitution ◽

Nucleophilic Substitution Reactions

Download Full-text

Kinetics of the Formation of the Intermediate Complex in the Aromatic Nucleophilic Substitution of Methyl 4-Methoxy-3,5-dinitrobenzoate with Piperidine in Dimethyl Sulfoxide

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.56.1314 ◽

1983 ◽

Vol 56 (5) ◽

pp. 1314-1318 ◽

Cited By ~ 2

Author(s):

Yoshinori Hasegawa

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Intermediate Complex ◽

Aromatic Nucleophilic Substitution ◽

Kinetics Of

Download Full-text

Aromatic nucleophilic substitution. 11. Effects of ortho substituents on the rates of the smiles rearrangements of (.beta.-acetylamino)ethyl 2-X-4-Y-6-Z-1-phenyl ethers with potassium hydroxide in aqueous dimethyl sulfoxide

The Journal of Organic Chemistry ◽

10.1021/jo01328a047 ◽

1979 ◽

Vol 44 (14) ◽

pp. 2556-2560 ◽

Cited By ~ 4

Author(s):

Shizen Sekiguchi ◽

Isao Ohtsuka ◽

Keiji Okada

Keyword(s):

Dimethyl Sulfoxide ◽

Nucleophilic Substitution ◽

Potassium Hydroxide ◽

Aromatic Nucleophilic Substitution ◽

Phenyl Ethers

Download Full-text