scholarly journals Infrared Dichroism and Molecular Orientation of Ethyl 2-Hydroxyimino-3-oxo-3-phenylpropionate in Thin Films on Pd Metal Surfaces

1976 ◽  
Vol 49 (6) ◽  
pp. 1512-1516 ◽  
Author(s):  
Masatoshi Osawa ◽  
Aritada Hatta ◽  
Kaoru Harada ◽  
Wataru Suëtaka
2002 ◽  
Vol 405 (1-2) ◽  
pp. 77-80 ◽  
Author(s):  
Hitoshi Muguruma ◽  
Kazutoshi Matsumura ◽  
Shu Hotta

1993 ◽  
Vol 316 ◽  
Author(s):  
Hiroaki Usui ◽  
Kiyoshi Kashihara ◽  
Kuniaki Tanaka ◽  
Seizo Miyata

ABSTRACTThin films of 3,4,9,10-perylenetetracarboxylic-dianhydride (PTCDA) were deposited by an ionized beam method. The molecular orientation and chemical structure of the films were studied in connection with ionization and ion acceleration conditions. At a low ionization condition, the molecules are oriented in parallel with the substrate, and the crystallinity was improved by an appropriate ion acceleration. At higher ionization conditions, on the other hand, ion acceleration resulted in a loss of crystallinity. Deposited molecules undergo chemical change in such a condition, leading to dissociation of dianhydride groups.


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