scholarly journals An X-Ray Diffraction Study of the Structures of the Hexachloro-and Hexabromoplatinate(IV) Ions in Aqueous Solution

1975 ◽  
Vol 48 (11) ◽  
pp. 3193-3196 ◽  
Author(s):  
Masunobu Maeda ◽  
Takeshi Akaishi ◽  
Hitoshi Ohtaki
1977 ◽  
Vol 47 (2) ◽  
pp. 275-278 ◽  
Author(s):  
R. Caminiti ◽  
G. Licheri ◽  
G. Piccaluga ◽  
G. Pinna

1982 ◽  
Vol 15 (6) ◽  
pp. 621-625 ◽  
Author(s):  
A. Musinu ◽  
G. Paschina ◽  
G. Piccaluga ◽  
M. Magini

1981 ◽  
Vol 35a ◽  
pp. 591-597 ◽  
Author(s):  
Erland Andersson ◽  
Oliver Lindqvist ◽  
Toshio Yamaguchi ◽  
Elina Näsäkkälä ◽  
Olof Wahlberg

1981 ◽  
Vol 36 (10) ◽  
pp. 1062-1066
Author(s):  
Ruggero Caminiti

The X-Ray scattering of a 2 M aqueous solution CdSO4 has been measured at 9 and 62 °C in a “Θ-Θ” transmission arrangement with a plane-parallel liquid sample. The experimental distribution curves show main peaks at about 1.5, 2.3, 2.8, 3.5, and 4.35 Å. The 3.5 A peak reveals the formation of inner sphere cadmium-sulphate complexes Cd(H2O)6-z(OSO3)z+2-2z, in which oxygens from sulphate groups substitute z water molecules of the hydrated Cd(H2O)62+ ions. Least squares refinements of the i(s) curves are consistent with a structural unit in which the sulphate tetrahedron shares a corner with one cadmium octahedron with Cd-O-S angle of 133 deg. The average number (z) of coordinated sulphate ions increases with increasing temperature.


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