scholarly journals Chemical Reaction of Electron Donor–Acceptor System: A New Mechanism for the Tricyanovinylation Reaction of Some Aromatic Amines with Tetracyanoethylene

1975 ◽  
Vol 48 (11) ◽  
pp. 3048-3055 ◽  
Author(s):  
Takashi Nogami ◽  
Yoshiki Hasegawa ◽  
Yasuhiko Shirota ◽  
Hiroshi Mikawa
Keyword(s):  
Chemical Reaction ◽  
Electron Donor ◽  
Aromatic Amines ◽  
System A ◽  
Donor Acceptor

scholarly journals Chemical Reaction of Electron Donor-Acceptor System: Reaction Mechanism of the Tricyanovinylation Reaction ofN,N-Dimethylaniline with Tetracyanoethylene

1979 ◽  
Vol 52 (7) ◽  
pp. 2110-2113 ◽  
Author(s):  
Takashi Nogami ◽  
Yoshio Nakano ◽  
Yoshiki Hasegawa ◽  
Yasuhiko Shirota ◽  
Hiroshi Mikawa
Keyword(s):  
Reaction Mechanism ◽  
Chemical Reaction ◽  
Electron Donor ◽  
Donor Acceptor

scholarly journals CHEMICAL REACTIONS OF ELECTRON DONOR-ACCEPTOR SYSTEM: ON THE MECHANISM OF TRICYANOVINYLATION REACTION OF AROMATIC AMINES WITH TETRACYANOETHYLENE

1974 ◽  
Vol 3 (9) ◽  
pp. 1009-1012 ◽  
Author(s):  
Yasuhiko Shirota ◽  
Takashi Nogami ◽  
Yoshiki Hasegawa ◽  
Hiroshi Mikawa
Keyword(s):  
Chemical Reactions ◽  
Electron Donor ◽  
Aromatic Amines ◽  
Donor Acceptor

Metal-Free Photoinduced Hydroalkylation Cascade Enabled by an Electron-Donor-Acceptor Complex

2020 ◽  
Author(s):  
José Tiago Menezes Correia ◽  
Gustavo Piva da Silva ◽  
Camila Menezes Kisukuri ◽  
Elias André ◽  
Bruno Pires ◽  
...  
Keyword(s):  
Electron Donor ◽  
Functional Group ◽  
Photoexcited Electron ◽  
One Pot ◽  
Quaternary Centers ◽  
Metal Free ◽  
Acceptor Complex ◽  
Catalyst Free ◽  
Donor Acceptor ◽  
Radical Cascade

A metal- and catalyst-free photoinduced radical cascade hydroalkylation of 1,7-enynes has been disclosed. The process is triggered by a SET event involving a photoexcited electron-donor-aceptor complex between NHPI ester and Hantzsch ester, which decomposes to afford a tertiary radical that is readily trapped by the enyne. <a>The method provides an operationally simple, robust and step-economical approach to the construction of diversely functionalized dihydroquinolinones bearing quaternary-centers. A sequential one-pot hydroalkylation-isomerization approach is also allowed giving access to a family of quinolinones. A wide substrate scope and high functional group tolerance was observed in both approaches</a>.

Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes

2021 ◽  
Vol 31 (3) ◽  
pp. 326-329
Author(s):  
Olga E. Eremina ◽  
Mariia V. Samodelova ◽  
Mariia V. Ferree ◽  
Tatyana N. Shekhovtsova ◽  
Irina A. Veselova
Keyword(s):  
Electron Donor ◽  
Polycyclic Aromatic Sulfur Heterocycles ◽  
Polycyclic Aromatic ◽  
Donor Acceptor ◽  
Sulfur Heterocycles
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