scholarly journals Group Interactions in Polyelectrolytes. IX. The Amination Kinetics of Chloromethylated Polystyrene in Binary Mixed Solvents

1975 ◽  
Vol 48 (1) ◽  
pp. 163-166 ◽  
Author(s):  
Hiroshi Kawabe
Keyword(s):  
Mixed Solvents ◽  
Group Interactions ◽  
Kinetics Of

Kinetic medium effects. IV. Transition state activity coefficients in mixed solvents

1972 ◽  
Vol 25 (4) ◽  
pp. 777 ◽  
Author(s):  
PT McTigue ◽  
AR Watkins
Keyword(s):  
Transition State ◽  
Activity Coefficients ◽  
Mixed Solvents ◽  
State Theory ◽  
Medium Effects ◽  
State Activity ◽  
Medium Activity ◽  
Solvent Systems ◽  
Kinetics Of ◽  
Hydrolysis Of

The kinetics of acid hydrolysis of a number of aliphatic acetals have been studied in dimethyl sulphoxide-water and dioxan-water mixtures. Where possible, experimentally measured medium activity coefficients for the acetals in the solvent systems have been used in order to calculate the transition state activity coefficients as a function of solvent composition. These activity coefficients are compared with those calculated for the transition states of other hydrolytic reactions, and with the known activity coefficients of some stable ions. The results show no features inconsistent with the assumptions of transition state theory.

Kinetics of the complexation of nickel(II) with 1,10-phenanthroline and its derivatives in acetonitrile–water mixed solvents

2005 ◽  
Vol 358 (6) ◽  
pp. 1823-1829 ◽  
Author(s):  
Masaaki Tabata ◽  
Toshihiro Murase ◽  
Kousuke Kurisaki ◽  
Ying Guang Wu
Keyword(s):  
Mixed Solvents ◽  
Kinetics Of
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