scholarly journals Radical Addition Reactions to the Carbonyl Group. I. The Reaction of Aliphatic Aldehydes with Di-t-butyl Peroxide

1974 ◽  
Vol 47 (3) ◽  
pp. 712-714 ◽  
Author(s):  
Kazuhiro Maruyama ◽  
Mamoru Taniuchi ◽  
Shinzaburo Oka
Keyword(s):  
Carbonyl Group ◽  
Radical Addition ◽  
Addition Reactions ◽  
Aliphatic Aldehydes ◽  
Group I ◽  
Butyl Peroxide

Free radical addition reactions—IV

Tetrahedron ◽  
1965 ◽  
Vol 21 (10) ◽  
pp. 2743-2747 ◽  
Author(s):  
H. Goldwhite ◽  
M.S. Gibson ◽  
C. Harris
Keyword(s):  
Free Radical ◽  
Radical Addition ◽  
Addition Reactions ◽  
Free Radical Addition

THE REACTION OF METHYL RADICALS WITH FORMALDEHYDE

1959 ◽  
Vol 37 (9) ◽  
pp. 1462-1468 ◽  
Author(s):  
A. R. Blake ◽  
K. O. Kutschke
Keyword(s):  
Activation Energy ◽  
Kinetic Analysis ◽  
Addition Reactions ◽  
Methyl Radicals ◽  
Kcal Mole ◽  
A Value ◽  
Abstraction Reaction ◽  
Butyl Peroxide

The pyrolysis of di-t-butyl peroxide has been reinvestigated and used as a source of methyl radicals to study the abstraction reaction between methyl radicals and formaldehyde. At low [HCHO]/[peroxide] ratios the system was simple enough for kinetic analysis, and a value of 6.6 kcal/mole was obtained for the activation energy. At higher [HCHO]/[peroxide] ratios the system became very complicated, possibly due to the increased importance of addition reactions.

An ESR study of thiyl radical addition at the carbonyl group

1977 ◽  
Vol 26 (11) ◽  
pp. 2284-2287 ◽  
Author(s):  
R. G. Gasanov ◽  
R. G. Petrova ◽  
I. O. Bragina ◽  
R. Kh. Freidlina
Keyword(s):  
Carbonyl Group ◽  
Radical Addition ◽  
Thiyl Radical

ChemInform Abstract: CAPTODATIVE SUBSTITUENT EFFECTS. 18. KINETIC EFFECTS IN RADICAL ADDITION REACTIONS TO RADICOPHILES

1985 ◽  
Vol 16 (2) ◽  
Author(s):  
F. LAHOUSSE ◽  
R. MERENYI ◽  
J. R. DESMURS ◽  
H. ALLAIME ◽  
A. BORGHESE ◽  
...  
Keyword(s):  
Substituent Effects ◽  
Radical Addition ◽  
Addition Reactions ◽  
Kinetic Effects

Expanding the Scope of the Acyl-Type Radical Addition Reactions Promoted by SmI2

2006 ◽  
Vol 71 (21) ◽  
pp. 8219-8226 ◽  
Author(s):  
Jakob Karaffa ◽  
Karl B. Lindsay ◽  
Troels Skrydstrup
Keyword(s):  
Radical Addition ◽  
Addition Reactions ◽  
Type Radical

N-Chloroamines as substrates for metal-free photochemical atom-transfer radical addition reactions in continuous flow

2021 ◽  
Author(s):  
Alexander Steiner ◽  
Oscar de Frutos ◽  
Juan A. Rincón ◽  
Carlos Mateos ◽  
Jason Williams ◽  
...  
Keyword(s):  
Continuous Flow ◽  
Radical Addition ◽  
Addition Reactions ◽  
Atom Transfer ◽  
Metal Free ◽  
Atom Transfer Radical Addition

N-Chloroamines have recently seen interest as substrates for atom-transfer radical addition (ATRA) reactions with olefins, to form β-chloroamine products, with complete atom incorporation. We report the development of a fully...

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