scholarly journals Dielectric Relaxation and Molecular Structure. XII. Dipole Moments and Dielectric Relaxation Times of Rigid Molecules in Solutions

1974 ◽  
Vol 47 (4) ◽  
pp. 1022-1023 ◽  
Author(s):  
Tohru Nagai ◽  
Yoshinori Koga ◽  
Hiroaki Takahashi ◽  
Keniti Higasi
1975 ◽  
Vol 28 (5) ◽  
pp. 1137 ◽  
Author(s):  
MJ Aroney ◽  
RL Angel

Dipole moments and dielectric relaxation times determined by dielectric loss measurements are reported for bis(pentane-2,4- dionato)oxovanadium(IV) as a solute in benzene and in dioxan. Evidence is presented for VO(acac)2,dioxan complex formation.


1975 ◽  
Vol 6 (8) ◽  
pp. no-no
Author(s):  
TOHRU NAGAI ◽  
HIROAKI TAKAHASHI ◽  
KENITI HIGASI ◽  
LESLIE E. SUTTON ◽  
DAVID WADDINGTON

2006 ◽  
Vol 61 (3-4) ◽  
pp. 197-204
Author(s):  
Raman Kumar ◽  
V. S. Rangra ◽  
D. R. Sharma ◽  
N. Thakur ◽  
N. S. Negi

The dielectric relaxation times τ and dipole moments μ of N-methylacetamide (NMA) mixed with N,N-dimethylformamide (DMF) in benzene solutions have been obtained using standard standing wave microwave techniques and Gopala Krishna’s single frequency (9.90 GHz) concentration variational method at 25, 30, 35, and 40 ◦C. The energy parameters (ΔHε , ΔFε , ΔSε ) for the dielectric relaxation process of mixtures with equal amounts of NMA and DMF have been calculated and compared with the corresponding energy parameters (ΔHη , ΔFη , ΔSη ) for the viscous flow. On the basis of the observations it is found that the dielectric relaxation process can be treated as a rate process like the viscous flow. Solute-solute and solute-solvent types of the molecular associations have been predicted


1972 ◽  
Vol 50 (13) ◽  
pp. 2031-2034 ◽  
Author(s):  
Sing Pin Tay ◽  
John Crossley

Mean relaxation times, Cole–Cole distribution parameters and apparent dipole moments, obtained from dielectric constant and loss measurements at 2 MHz and 1.5, 2.0, 2.5, 9.3, 16, 24, 35, 70, and 145 GHz, are reported for 1-, 2-, and 4-bromooctane, 1-bromodecane, 1-bromododecane, 1-bromohexadecane, 1-bromooctadecane, and 1,10-dibromodecane in cyclohexane solution at 25 °C.


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