scholarly journals Studies of the Sodium Salts of Homologues of Alkyl Sulfates in Aqueous Solutions in Relation to the Water Structure

1972 ◽  
Vol 45 (11) ◽  
pp. 3270-3276 ◽  
Author(s):  
Harumi Endo

Cold neutron inelastic scattering experiments have been performed on dilute aqueous solutions of (CD 3 ) 3 COH and of solutions of (CH 3 ) 3 COH in D 2 O at 21 °C. From the broadening of the quasi-elastic peak and independently determined self-diffusion coefficients ( D ), diffusive lifetimes ( c ) of H 2 O molecules have been calculated as functions of solute concentration. The product Dc is insensitive to concentration, giving a mean diffusion step length of 0.14 nm. The inelastic portion of the spectrum, reflecting lattice-like hydrogen bonding modes indicates that the solute enhances the water ‘structure’ but that such structure bears no resemblance to ice.


2006 ◽  
Vol 124 (3) ◽  
pp. 180-191 ◽  
Author(s):  
Alan K. Soper ◽  
Kristian Weckström

2015 ◽  
Vol 11 (8) ◽  
pp. 3866-3872
Author(s):  
E.A. Masimov ◽  
Etibar Hummat Ismailov ◽  
S.Y. Odzhaqverdiyeva

Dynamic light scattering (DLS) method in combination with the UV/VIS spectrophotometry is used to study the interaction of polyethylene- glycols with a molecular weight  6000 ( PEG6000 ) with sodium salts of citric and succinic acids in aqueous solutions. The values of density, viscosity, refractive and diffusion indexes, the values of the hydrodynamic diameter, wavelength electronic absorption bands for PEG6000 aqueous solutions, their mixtures with succinic and citric acids are determined. It was shown that depending on the composition of the solutions the values of hydrodynamic diameter for aqueous solutions containing 1-5 wt.% PEG6000 and their mixtures with succinic and citric acids (~ 1 wt%) ranges from 3.6 to 5.2 nm. It is assumed that the formation of complexes with the sizes  that are within the above range is due to the features of interaction  and the structure of the complexes formed in solution.


2003 ◽  
Vol 4 (5) ◽  
pp. 1348-1356 ◽  
Author(s):  
Kazuto Yoshiba ◽  
Akio Teramoto ◽  
Naotake Nakamura ◽  
Kyo Kikuchi ◽  
Yuji Miyazaki ◽  
...  

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