scholarly journals The Catalytic Dehydrogenation, Dehydroxylation and Dehydroxymethylation of Benzyl Alcohol. I. The Scope and the Kinetic Study

1970 ◽  
Vol 43 (7) ◽  
pp. 2186-2191 ◽  
Author(s):  
Masayoshi Ishige ◽  
Koji Sakai ◽  
Masatoshi Kawai ◽  
Kazuo Hata
Keyword(s):  
Kinetic Study ◽  
Benzyl Alcohol ◽  
Catalytic Dehydrogenation

A detailed kinetic study on oxidation of benzyl alcohol

2019 ◽  
Vol 207 ◽  
pp. 10-19 ◽  
Author(s):  
Lei Zhou ◽  
Dan Yu ◽  
Zhen Wang ◽  
Li-Juan Cheng ◽  
Zhi-Hao Jin ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Benzyl Alcohol ◽  
Oxidation Of Benzyl Alcohol

Role of the Feed Gas on the Selective Catalytic Dehydrogenation of Benzyl Alcohol over Cu/Hydrotalcite Catalyst

2018 ◽  
Vol 3 (28) ◽  
pp. 8277-8284 ◽  
Author(s):  
Venkata Ramesh Babu Gurram ◽  
Siva Sankar Enumula ◽  
Murali Kondeboina ◽  
Kumara Swamy Koppadi ◽  
David Raju Burri ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Catalytic Dehydrogenation

Kinetics and Mechanism of the Oxidation of Benzyl Alcohol and Benzaldehyde by Aqueous Sodium Dichromate

1975 ◽  
Vol 53 (24) ◽  
pp. 3709-3713 ◽  
Author(s):  
Donald G. Lee ◽  
Udo A. Spitzer
Keyword(s):  
Reaction Mechanism ◽  
Kinetic Study ◽  
Benzyl Alcohol ◽  
Oxidation Rate ◽  
Activation Parameters ◽  
Sodium Dichromate ◽  
Benzyl Alcohols ◽  
Aqueous Sodium ◽  
Entropy Of Activation ◽  
The Difference

A kinetic study of the oxidation of a series of substituted benzyl alcohols and benzaldehydes by neutral aqueous sodium dichromate has been completed. The aldehydes are more resistant to oxidation because the reaction mechanism presumably involves hydration prior to oxidation, and under the conditions employed the extent of this hydration is suppressed. These conclusions are consistent with the activation parameters which indicate that the difference in oxidation rate is due to a more negative entropy of activation for the aldehydes.

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