scholarly journals The Anodic Oxidation of a Propionate-Propionic Acid Solution in the Presence of Several Organic Compounds

1970 ◽  
Vol 43 (5) ◽  
pp. 1298-1302 ◽  
Author(s):  
Akira Kunugi ◽  
Toshiyuki Shimizu ◽  
Shigeo Nagaura
1962 ◽  
Vol 40 (5) ◽  
pp. 966-975 ◽  
Author(s):  
J. T. Edward ◽  
I. C. Wang

Protonation constants (pKBH+) of −6.8 and −0.9 have been determined for propionic acid and propionamide, respectively, from measurements of their ultraviolet absorption in various concentrations of sulphuric acid. The ionization ratio of propionamide and of other amides increases more slowly than the Hammett acidity function, h0, with increase in acid concentration. This may be explained by assuming that in a given concentration of sulphuric acid the protonated amide is more heavily hydrated than the protonated Hammett indicator used to establish the h0 scale for this region of acid concentrations.


2014 ◽  
Vol 59 (1) ◽  
pp. 137-143 ◽  
Author(s):  
W. Gumowska ◽  
I. Dobosz ◽  
B. Wrzoszczyk

Abstract The optimal parameters of the anodic oxidation of aluminium in orthophosphoric acid solution was determined. In the pores of the obtained Al2O3 membranes with the ordered nanometric structure Co-Fe alloys were electrodeposited. The Al2O3 membranes were obtained in the two-stage anodic oxidation of aluminium in the 0.17 M H3PO4 solution in the temperature 1°C and at the electrolysis voltage 180 V. The influence of the anodizing process parameters on the thickness of oxide films and the diameter of pores and the distance between them in the alumina membranes were determined. The electrodeposition of Co-Fe alloys was carried out from sulphate baths containing sulphates (VI) of copper (II) and cobalt (II) of different composition, in potentiostatic conditions. The optimal electrolysis conditions were determined, where the cathodic deposits of the best quality were obtained. The conditions are: the electrolyte composition: 0.3 M Fe; 0.5 M Co; pH = 3, the potential: -0.760 V (vs. SHE1)).


2017 ◽  
Vol 118 ◽  
pp. 1-11 ◽  
Author(s):  
Clément Trellu ◽  
Nihal Oturan ◽  
Yoan Pechaud ◽  
Eric D. van Hullebusch ◽  
Giovanni Esposito ◽  
...  

1970 ◽  
Vol 48 (10) ◽  
pp. 1533-1535 ◽  
Author(s):  
N. L. Weinberg

A ring expanded lactone is obtained on electrochemical oxidation of t-BuOOH in presence of tetracyclone. The same product is formed on chemical oxidation of a mixture of t-BuOOH and tetracyclone with cerie ammonium sulfate or on heating the mixture to dryness.


2006 ◽  
Vol 114 (1325) ◽  
pp. 46-50 ◽  
Author(s):  
Atsushi NAKAHIRA ◽  
Koichi KONISHI ◽  
Koji YOKOTA ◽  
Tetsuo HONMA ◽  
Hirofumi ARITANI ◽  
...  

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