scholarly journals The Kinetics of the Acid-Catalyzed Formation of Peracetic Acid from Acetic Acid and Hydrogen Peroxide

1965 ◽  
Vol 38 (12) ◽  
pp. 2103-2106 ◽  
Author(s):  
Yasuhiko Sawaki ◽  
Yoshiro Ogata
Keyword(s):  
Hydrogen Peroxide ◽  
Acetic Acid ◽  
Peracetic Acid ◽  
Acid Catalyzed ◽  
Kinetics Of

Kinetics of the acid-catalyzed isomerization of phenylbutenes in glacial acetic acid

1972 ◽  
Vol 94 (4) ◽  
pp. 1247-1249 ◽  
Author(s):  
R. S. Schwartz ◽  
H. Yokokawa ◽  
E. W. Graham
Keyword(s):  
Acetic Acid ◽  
Glacial Acetic Acid ◽  
Acid Catalyzed ◽  
Kinetics Of

Synthesized WO3/ZrO2 Nanocomposite as the Catalyst for Preparation of Peracetic Acid

2011 ◽  
Vol 287-290 ◽  
pp. 1727-1730 ◽  
Author(s):  
Mei Li ◽  
Zhi Ming Chen
Keyword(s):  
Hydrogen Peroxide ◽  
Acetic Acid ◽  
Lewis Acid ◽  
Peracetic Acid ◽  
Pyridine Adsorption ◽  
Nanosized Material ◽  
Adsorption Desorption ◽  
Structural Characterizations ◽  
Surfactant Assisted

Nanosized material tungstate zirconia (WO3/ZrO2) was prepared by surfactant -assisted precipitation. Structural characterizations of the catalyst were performed by N2adsorption– desorption and FTIR pyridine adsorption spectroscopy. Preparation of peracetic acid (PAA) from acetic acid (AA) and hydrogen peroxide (HP) under the catalysis of Lewis acid WO3/ZrO2was investigated.

scholarly journals Respiratory Symptoms in Hospital Cleaning Staff Exposed to a Product Containing Hydrogen Peroxide, Peracetic Acid, and Acetic Acid

2018 ◽  
Vol 64 (8) ◽  
pp. 911-911
Author(s):  
Brie Hawley ◽  
Megan Casey ◽  
Mohammed Abbas Virji ◽  
Kristin J Cummings ◽  
Alyson Johnson ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Acetic Acid ◽  
Peracetic Acid ◽  
Respiratory Symptoms ◽  
Cleaning Staff ◽  
Hospital Cleaning

Simultaneous determination of peracetic acid and acetic acid by titration with NaOH

2014 ◽  
Vol 6 (7) ◽  
pp. 2406-2409 ◽  
Author(s):  
Frank Sode
Keyword(s):  
Hydrogen Peroxide ◽  
Acetic Acid ◽  
Simultaneous Determination ◽  
Peracetic Acid ◽  
Easy Method

This paper describes a fast and easy method to analyze peracetic acid in mixtures with both acetic acid and hydrogen peroxide.

Palladium(II) Catalyzed Exchange Reactions. XI. Vinyl Propionate Exchange with Acetic Acid Catalyzed by Palladium(II) Acetate

1975 ◽  
Vol 53 (15) ◽  
pp. 2223-2231 ◽  
Author(s):  
Raj N. Pandey ◽  
Patrick M. Henry
Keyword(s):  
Acetic Acid ◽  
Sodium Acetate ◽  
Exchange Reactions ◽  
Free System ◽  
Acetate Concentration ◽  
Rate Expression ◽  
Π Complex ◽  
Acid Catalyzed ◽  
Kinetics Of ◽  
Vinyl Propionate

The kinetics of the palladium(II) acetate catalyzed exchange of vinyl propionate with acetic acid solvent to give vinyl acetate has been studied in the sodium acetate concentration range from 0 to 1 M. The exchange rate first sharply increases as [NaOAc] increases, reaches a maximum at about 0.2 M and then gradually decreases as the sodium acetate concentration is in-creased to 1.0 M. Using previous results on the equilibrium between palladium(II) acetate and sodium acetate in acetic acid it can be shown that the rate expression for exchange is: rate = (ko + kt[Pd3(OAc)6] + kd[Na2Pd2(OAc)6]) [CH2=CHO2CC2H5] where ko = 2 × 10−4 s−1, kt = 0.045 M−1 s−1, and kd = 0.089 M−1 s−1. A monomeric palladium(II) species, Na2Pd(OAc)4, formed at high [NaOAc] is unreactive. Since the rate expression does not contain a term in [NaOAc], the sodium acetate serves only to convert one palladium(II) species to another. The lack of a [NaOAc] term in the rate expression for the Na2Pd2(OAc)6 catalyzed reaction is believed to result from cancellation of an inhibitory term for π-complex formation by a catalytic term in [NaOAc] in the rate determining conversion of π -complex to σ-complex (acetoxypalladation). Stereochemical studies indicate that acetoxypalladation is nonstereospecific. This result is expected since in the chloride free system acetate is both a ligand and a reactant. Thus it can attack from both inside and outside the coordination sphere of Pd(II).

Formation of Peracetic Acid upon Aging of Perborate in Acetic Acid. Kinetics of the Oxidation of S-Phenylmercaptoacetic Acids

2000 ◽  
Vol 131 (10) ◽  
pp. 1025-1029 ◽  
Author(s):  
Chockalingam Karunakaran ◽  
Kaliyaperumal Anandhy ◽  
Velusamy Ramachandran
Keyword(s):  
Acetic Acid ◽  
Peracetic Acid ◽  
Kinetics Of
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