scholarly journals Studies of the Organic Reactions of Metal Carbonyl. II. The Reaction of Olefin Oxide with Cobalt Hydrocarbonyl

1964 ◽  
Vol 37 (5) ◽  
pp. 672-676 ◽  
Author(s):  
Yoshinobu Takegami ◽  
Chikao Yokokawa ◽  
Yoshihisa Watanabe ◽  
Hiromitsu Masada
Keyword(s):  
Metal Carbonyl ◽  
Organic Reactions ◽  
Olefin Oxide

scholarly journals Studies of the Organic Reactions of Metal Carbonyl. III. The Hydroformylation of Olefin Oxides

1964 ◽  
Vol 37 (5) ◽  
pp. 677-679 ◽  
Author(s):  
Chikao Yokokawa ◽  
Yoshihisa Watanabe ◽  
Yoshinobu Takegami
Keyword(s):  
Metal Carbonyl ◽  
Organic Reactions ◽  
Olefin Oxides

MULTIPLE SCATTERING EFFECTS IN THE COBALT K-EDGE EXAFS OF METAL CARBONYL COMPLEXES

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-589-C8-592
Author(s):  
N. BINSTED ◽  
S. L. COOK ◽  
J. EVANS ◽  
R. J. PRICE ◽  
G. N. GREAVES
Keyword(s):  
Multiple Scattering ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Scattering Effects ◽  
Multiple Scattering Effects

Decarboxylation Reactions in a Photocatalytic Microchip

2018 ◽  
Author(s):  
Kenji Katayama ◽  
Momona Seki ◽  
Kayoko Tokumitsu ◽  
Woon Yong Sohn
Keyword(s):  
Reaction Time ◽  
Organic Reactions ◽  
Light Conditions ◽  
High Yields

The photocatalytic microchip was demonstrated as an efficient platform of the photocatalytic organic reactions, which features an easy control of the reaction time and light conditions. We demonstrated the photocatalytic decarboxylation and the following adduct reaction inside the microchip and successfully achieved high yields of the products.

Carbon Chain Growth by Sequential Reactions of CO and CO2 with a Transition Metal Carbonyl Complex

2018 ◽  
Author(s):  
Richard Kong ◽  
Mark Crimmin
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbon Chain ◽  
Chain Growth ◽  
Carbonyl Complex ◽  
Fischer Tropsch ◽  
Carbon Chains ◽  
Sequential Coupling ◽  
Energy Economy ◽  
Sequential Reactions

<i>The formation of carbon chains by the coupling of COx (X = 1 or 2) units on transition metals is a fundamental step relevant to Fischer-Tropsch catalysis. Fischer-Tropsch catalysis produces energy dense liquid hydrocarbons from synthesis gas (CO and H2) and has been a mainstay of the energy economy since its discovery nearly a century ago. Despite detailed studies aimed at elucidating the steps of catalysis, experimental evidence for chain growth (Cn to Cn+1 ; n > 2) from the reaction of CO with metal complexes is unprecedented. In this paper, we show that carbon chains can be grown from sequential reactions of CO or CO2 with a transition metal carbonyl complex. By exploiting the cooperative effect of transition and main group metals, we document the first example of chain propagation from sequential coupling of CO units (C1 to C3 to C4), along with the first example of incorporation of CO2 into the growing carbon chain.</i><br>

Periodic Mesoporous Organosilicas as Catalysts for Organic Reactions

2014 ◽  
Vol 18 (10) ◽  
pp. 1280-1295 ◽  
Author(s):  
Dolores Esquivel ◽  
Els Canck ◽  
Cesar Jimenez-Sanchidrian ◽  
Pascal Voort ◽  
Francisco Romero-Salguero
Keyword(s):  
Organic Reactions ◽  
Periodic Mesoporous Organosilicas ◽  
Mesoporous Organosilicas
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