scholarly journals Dehydrogenation of Secondary Alcohols with Reduced Copper. III. Catalytic Dehydrogenation of Isopropyl Alcohol (Part 1)

1961 ◽  
Vol 34 (2) ◽  
pp. 161-166 ◽  
Author(s):  
Kazuaki Kawamoto
Keyword(s):  
Isopropyl Alcohol ◽  
Catalytic Dehydrogenation ◽  
Secondary Alcohols

Secondary Alcohols as Rechargeable Electrofuels: Electrooxidation of Isopropyl Alcohol at Pt Electrodes

ACS Catalysis ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 6831-6842
Author(s):  
Fabian Waidhas ◽  
Sandra Haschke ◽  
Peyman Khanipour ◽  
Lukas Fromm ◽  
Andreas Görling ◽  
...  
Keyword(s):  
Isopropyl Alcohol ◽  
Secondary Alcohols ◽  
Pt Electrodes

Hydrogen transfer reactions. I. Reduction of carbonyl compounds by alcohols catalyzed by alumina

1969 ◽  
Vol 47 (19) ◽  
pp. 3705-3707 ◽  
Author(s):  
D. V. Ramana ◽  
C. N. Pillai
Keyword(s):  
Vapor Phase ◽  
Carbonyl Compounds ◽  
Hydrogen Transfer ◽  
Isopropyl Alcohol ◽  
Aromatic Aldehydes ◽  
Transfer Reactions ◽  
Secondary Alcohols ◽  
Effective Catalyst ◽  
Phase Reduction ◽  
Aldehydes And Ketones

Alumina containing about 2.2% by weight of Na+ has been found to be an effective catalyst for the vapor phase reduction of carbonyl compounds by alcohols and for the reverse reaction, the oxidation of the alcohols by carbonyl compounds. The reduction of a number of aliphatic and aromatic aldehydes and ketones by isopropyl alcohol and the oxidation of a number of primary and secondary alcohols by ketones like acetone and cyclohexanone are reported.

scholarly journals Reversible catalytic dehydrogenation of alcohols for energy storage

2015 ◽  
Vol 112 (6) ◽  
pp. 1687-1692 ◽  
Author(s):  
Peter J. Bonitatibus ◽  
Sumit Chakraborty ◽  
Mark D. Doherty ◽  
Oltea Siclovan ◽  
William D. Jones ◽  
...  
Keyword(s):  
Energy Storage ◽  
Fuel Cell ◽  
Homogeneous Catalysis ◽  
Partial Oxidation ◽  
Catalytic Reaction ◽  
Pincer Complexes ◽  
Catalytic Dehydrogenation ◽  
Secondary Alcohols ◽  
Iridium Complexes ◽  
Primary Alcohols

Reversibility of a dehydrogenation/hydrogenation catalytic reaction has been an elusive target for homogeneous catalysis. In this report, reversible acceptorless dehydrogenation of secondary alcohols and diols on iron pincer complexes and reversible oxidative dehydrogenation of primary alcohols/reduction of aldehydes with separate transfer of protons and electrons on iridium complexes are shown. This reactivity suggests a strategy for the development of reversible fuel cell electrocatalysts for partial oxidation (dehydrogenation) of hydroxyl-containing fuels.

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