scholarly journals Protonated Bis-1,2,3-triazole as an Anion-Binding Chiral Brønsted Acid for Catalytic Asymmetric Friedel–Crafts Reaction of Indoles with Imines

2018 ◽  
Vol 91 (8) ◽  
pp. 1252-1257 ◽  
Author(s):  
Yukino Furukawa ◽  
Ryuhei Suzuki ◽  
Tsubasa Nakashima ◽  
Rafael Gramage-Doria ◽  
Kohsuke Ohmatsu ◽  
...  
Synthesis ◽  
2018 ◽  
Vol 50 (10) ◽  
pp. 1935-1957 ◽  
Author(s):  
Daniel Sedgwick ◽  
Matthew Grayson ◽  
Santos Fustero ◽  
Pablo Barrio

The 50-year-old allylboration reaction has seen dramatic developments since the dawn of the new century after the first catalytic asymmetric versions came into play. In the past decade alone, several methodologies capable of achieving the desired homoallylic alcohols in over 90% ee have been developed. This review focuses on the chiral Brønsted acid catalyzed allylboration reaction, covering everything from the very first examples and precedents to modern day variations and applications.1 Introduction2 Early Developments3 Synthetic Applications4 Variants5 Computational Contribution6 Conclusions


Author(s):  
Yongbiao Guo ◽  
Zhenhua Gao ◽  
Junchen Li ◽  
Xiaojing Bi ◽  
Enxue Shi ◽  
...  

An efficient, practical and scalable protocol to prepare chiral 2,3-dihydroquinazolinones was developed under catalysis of spirocyclic SPINOL-phosphoric acid.


2014 ◽  
Vol 356 (16) ◽  
pp. 3451-3455 ◽  
Author(s):  
Shaolin Zhou ◽  
Steffen Fleischer ◽  
Haijun Jiao ◽  
Kathrin Junge ◽  
Matthias Beller

2018 ◽  
Vol 360 (24) ◽  
pp. 4744-4753 ◽  
Author(s):  
Jianwen Jin ◽  
Yichao Zhao ◽  
Ella Min Ling Sze ◽  
Prasath Kothandaraman ◽  
Philip Wai Hong Chan

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