Activation of C–S Bond by Group 10 Metal Complexes: Reaction of Phosphine Ligand Tethered with Threetert-Butylthiophenyl Groups with Group 10 Metal Compounds

2016 ◽  
Vol 89 (8) ◽  
pp. 922-930 ◽  
Author(s):  
Nobuhiro Takeda ◽  
Yusuke Tanaka ◽  
Rin Oma ◽  
Fumiaki Sakakibara ◽  
Masafumi Unno
Keyword(s):  
Metal Complexes ◽  
Phosphine Ligand ◽  
Metal Compounds ◽  
Group 10

scholarly journals Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes

2017 ◽  
Vol 375 (2101) ◽  
pp. 20170002 ◽  
Author(s):  
R. Morris Bullock ◽  
Geoffrey M. Chambers
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Molecular Complexes ◽  
Main Group ◽  
Lewis Base ◽  
Metal Compounds ◽  
Metal Catalysis ◽  
Heterolytic Cleavage ◽  
Lewis Pairs

This perspective examines frustrated Lewis pairs (FLPs) in the context of heterolytic cleavage of H 2 by transition metal complexes, with an emphasis on molecular complexes bearing an intramolecular Lewis base. FLPs have traditionally been associated with main group compounds, yet many reactions of transition metal complexes support a broader classification of FLPs that includes certain types of transition metal complexes with reactivity resembling main group-based FLPs. This article surveys transition metal complexes that heterolytically cleave H 2 , which vary in the degree that the Lewis pairs within these systems interact. Many of the examples include complexes bearing a pendant amine functioning as the base with the metal functioning as the hydride acceptor. Consideration of transition metal compounds in the context of FLPs can inspire new innovations and improvements in transition metal catalysis. This article is part of the themed issue ‘Frustrated Lewis pair chemistry’.

Toward Butadiene-ATRP with Group 10 (Ni, Pd, Pt) Metal Complexes

2018 ◽  
pp. 205-225 ◽  
Author(s):  
Vignesh Vasu ◽  
Joon-Sung Kim ◽  
Hyun-Seok Yu ◽  
William I. Bannerman ◽  
Mark E. Johnson ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Group 10

scholarly journals Synthesis and Reactivity of Group 10 Transition Metal Complexes with Alkenylphosphoryl Compounds

2019 ◽  
Vol 39 (8) ◽  
pp. 2183
Author(s):  
Tieqiao Chen ◽  
Long Liu ◽  
Tianzeng Huang ◽  
Li-Biao Han
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Group 10

A Two-Step Catalytic Cycle for the Acceptorless Dehydrogenation of Ethane by Group 10 Metal Complexes: Role of the Metal in Reactivity and Selectivity

2020 ◽  
Vol 39 (22) ◽  
pp. 4027-4036
Author(s):  
Kevin Parker ◽  
Geethika K. Weragoda ◽  
Allan J. Canty ◽  
Anastasios Polyzos ◽  
Victor Ryzhov ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Catalytic Cycle ◽  
Group 10

Transmetallation reactions of [Sn(R)2(Ph2PC6H4-2-S)2] with metal complexes of the Group 10

2003 ◽  
Vol 679 (1) ◽  
pp. 101-109 ◽  
Author(s):  
Daniel Canseco-González ◽  
Valente Gómez-Benı́tez ◽  
Simón Hernández-Ortega ◽  
Rubén A Toscano ◽  
David Morales-Morales
Keyword(s):  
Metal Complexes ◽  
Group 10
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