One-Pot Facile Synthesis of Water-Soluble Cationic Aluminum(III) Porphyrins in a Unique Heterogeneous System at Ambient Temperature

2016 ◽  
Vol 89 (3) ◽  
pp. 334-336 ◽  
Author(s):  
Siby Mathew ◽  
Fazalurahman Kuttassery ◽  
Daisuke Yamamoto ◽  
Satomi Onuki ◽  
Yu Nabetani ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Heterogeneous System ◽  
Water Soluble ◽  
Facile Synthesis ◽  
One Pot

ChemInform Abstract: One-Pot Facile Synthesis of Water-Soluble Cationic Aluminum(III) Porphyrins in a Unique Heterogeneous System at Ambient Temperature.

ChemInform ◽  
2016 ◽  
Vol 47 (21) ◽  
Author(s):  
Siby Mathew ◽  
Fazalurahman Kuttassery ◽  
Daisuke Yamamoto ◽  
Satomi Onuki ◽  
Yu Nabetani ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Heterogeneous System ◽  
Water Soluble ◽  
Facile Synthesis ◽  
One Pot

Facile synthesis of superparamagnetic magnetite nanoflowers and their applications in cellular imaging

RSC Advances ◽  
2016 ◽  
Vol 6 (48) ◽  
pp. 42649-42655 ◽  
Author(s):  
Chichong Lu ◽  
Hao Wang ◽  
Jianmei Ma ◽  
Huanxiang Yuan ◽  
Haiyan Liang ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Cellular Imaging ◽  
Water Soluble ◽  
Facile Synthesis ◽  
One Pot

Thermal decomposition of an iron-oleate complex in the presence of a surfactant gives water-soluble biocompatible superparamagnetic magnetite nanoflowers via a one-pot reaction.

Facile synthesis of silver sulfide quantum dots by one pot reverse microemulsion under ambient temperature

2019 ◽  
Vol 242 ◽  
pp. 143-146 ◽  
Author(s):  
Jing Xue ◽  
Hailong Li ◽  
Jixian Liu ◽  
Yao Wang ◽  
Yuanmeng Liu ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Ambient Temperature ◽  
Silver Sulfide ◽  
Reverse Microemulsion ◽  
Facile Synthesis ◽  
One Pot

Facile synthesis of noncytotoxic PEGylated dendrimer encapsulated silver sulfide quantum dots for NIR-II biological imaging

Nanoscale ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 5678-5684 ◽  
Author(s):  
Pragati Awasthi ◽  
Xinyi An ◽  
Jiajia Xiang ◽  
Nagendra Kalva ◽  
Youqing Shen ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Silver Sulfide ◽  
Biological Imaging ◽  
Water Soluble ◽  
Fluorescence Property ◽  
Facile Synthesis ◽  
One Pot

The water-soluble PEG-PATU Ag2S QDs have been successfully prepared by one-pot method, which display the favorable NIR-II fluorescence property for in vivo bioimaging.

Facile Synthesis of Water-Soluble Cationic Tin(IV) Porphyrins and Water-Insoluble Tin(IV) Porphyrins in Water at Ambient Temperature

2016 ◽  
Vol 89 (8) ◽  
pp. 902-904 ◽  
Author(s):  
Arun Thomas ◽  
Fazalurahman Kuttassery ◽  
Seabatian Nybin Remello ◽  
Siby Mathew ◽  
Daisuke Yamamoto ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Water Soluble ◽  
Facile Synthesis

Synthesis and Kinetics of Highly Substituted Piperidines in the Presence of Tartaric Acid as a Catalyst

2018 ◽  
Vol 21 (4) ◽  
pp. 302-311
Author(s):  
Younes Ghalandarzehi ◽  
Mehdi Shahraki ◽  
Sayyed M. Habibi-Khorassani
Keyword(s):  
Ambient Temperature ◽  
Tartaric Acid ◽  
Aromatic Aldehydes ◽  
One Pot ◽  
Rate Determining Step ◽  
State Approximation ◽  
Solvent Free Conditions ◽  
Steady State Approximation ◽  
Absorbance Changes ◽  
The One

Aim & Scope: The synthesis of highly substituted piperidine from the one-pot reaction between aromatic aldehydes, anilines and β-ketoesters in the presence of tartaric acid as a catalyst has been investigated in both methanol and ethanol media at ambient temperature. Different conditions of temperature and solvent were employed for calculating the thermodynamic parameters and obtaining an experimental approach to the kinetics and mechanism. Experiments were carried out under different temperature and solvent conditions. Material and Methods: Products were characterized by comparison of physical data with authentic samples and spectroscopic data (IR and NMR). Rate constants are presented as an average of several kinetic runs (at least 6-10) and are reproducible within ± 3%. The overall rate of reaction is followed by monitoring the absorbance changes of the products versus time on a Varian (Model Cary Bio- 300) UV-vis spectrophotometer with a 10 mm light-path cell. Results: The best result was achieved in the presence of 0.075 g (0.1 M) of catalyst and 5 mL methanol at ambient temperature. When the reaction was carried out under solvent-free conditions, the product was obtained in a moderate yield (25%). Methanol was optimized as a desirable solvent in the synthesis of piperidine, nevertheless, ethanol in a kinetic investigation had none effect on the enhancement of the reaction rate than methanol. Based on the spectral data, the overall order of the reaction followed the second order kinetics. The results showed that the first step of the reaction mechanism is a rate determining step. Conclusion: The use of tartaric acid has many advantages such as mild reaction conditions, simple and readily available precursors and inexpensive catalyst. The proposed mechanism was confirmed by experimental results and a steady state approximation.

Synthesis of Pyrrolo[1,2-a][1,6]- and [1,8]naphthyridines by Alkyne-Carbonyl Metathesis

Synthesis ◽  
2020 ◽  
Author(s):  
Peter Ehlers ◽  
Peter Langer ◽  
Marian Blanco Ponce ◽  
Silvio Parpart ◽  
Alexander Villinger ◽  
...  
Keyword(s):  
Heterocyclic Compounds ◽  
Metathesis Reaction ◽  
Synthetic Methodology ◽  
Facile Synthesis ◽  
Reaction Conditions ◽  
One Pot ◽  
Metal Free ◽  
Modular Synthesis

AbstractA concise and modular synthesis of pyrrolo[1,2-a][1,6]- and [1,8]naphthyridines by a one-pot two-step reaction consisting of electrophilic acylation followed by an alkyne-carbonyl-metathesis reaction as the final cyclization step is reported. This developed synthetic methodology allows the facile synthesis of these heterocyclic core structures in mainly high overall yields under metal-free conditions. Reaction conditions are carefully optimized and display a novel supplement to access these tricyclic heterocyclic compounds.

scholarly journals One-Pot Microwave-Assisted Synthesis of Water-Soluble Pyran-2,4,5-triol Glucose Amine Schiff Base Derivative: XRD/HSA Interactions, Crystal Structure, Spectral, Thermal and a DFT/TD-DFT

Crystals ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 117
Author(s):  
Yousef Hijji ◽  
Rajeesha Rajan ◽  
Hamdi Ben Yahia ◽  
Said Mansour ◽  
Abdelkader Zarrouk ◽  
...  
Keyword(s):  
Schiff Base ◽  
Molecular Orbital ◽  
Density Functional ◽  
Condensation Reaction ◽  
3D Structure ◽  
Water Soluble ◽  
Microwave Assisted Synthesis ◽  
One Pot ◽  
Microwave Assisted ◽  
Td Dft

The(3R,4R,6R)-3-(((E)-2-hydroxybenzylidene)amino)-6-(hydroxymethyl)tetrahydro-2H-pyran-2,4,5-triol water-soluble Glucose amine Schiff base (GASB-1) product was made available by condensation of 2-hydroxybenzaldehyde with (3R,6R)-3-amino-6-(hydroxymethyl)-tetra-hydro-2H-pyran-2,4,5-triol under mono-mode microwave heating. A one-pot 5-minute microwave-assisted reaction was required to complete the condensation reaction with 90% yield and without having byproducts. The 3D structure of GASB-1 was solved from single crystal X-ray diffraction data and computed by DFT/6-311G(d,p). The Hirshfeld surface analysis (HSA), molecular electronic potential (MEP), Mulliken atomic charge (MAC), and natural population analysis (NPA) were performed. The IR and UV-Vis spectra were matched to their density functional theory (DFT) relatives and the thermal behavior was resolved in an open-room condition via thermogravimetry/Derivative thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC). The highest occupied molecular orbital/lowest unoccupied molecular orbital (HOMO/LUMO), density of state (DOS), and time-dependence TD-DFT computations were correlated to the experimental electron transfer in water and acrylonitrile solvents.

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