Formation of silver nanowires in ethylene glycol for transparent conducting electrodes

2018 ◽  
Vol 775 ◽  
pp. 254-259
Author(s):  
Nathaniel de Guzman ◽  
Mary Donnabelle L. Balela

High aspect ratio silver nanowires (AgNWs) with an average length of 40 μm and average diameter of 88 nm were successfully synthesized using waste ethylene glycol as solvent and reducing agent. Silver nanowires with an average length and diameter of 32 μm and 122 nm, were produced after the third cycle of being reused. A transparent conducting film with a sheet resistance of 69 Ω/sq and optical transmittance of 91% was fabricated by Meyer rod coating an ink formulation of AgNWs dispersed in hydroxyethyl celullose (HEC)/methanol/deionized water. The low resistance of the AgNW networks was maintained even after 1000 bending cycles due to HEC acting as binder for the nanowires. The AgNWHEC transparent conductive electrode performed better than bare AgNWs and indium tin oxide (ITO) on polyethylene terephthalate (PET) substrate after several bending cycles. The AgNW-HEC electrode also showed excellent stability against corrosion.


Nanoscale ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 5760-5769 ◽  
Author(s):  
D. Kumar ◽  
V. Stoichkov ◽  
E. Brousseau ◽  
G. C. Smith ◽  
J. Kettle

A report of transparent and conducting silver nanowires (AgNWs) that produce remarkable electrical performance, surface planarity and environmental stability is given.


2013 ◽  
Author(s):  
Jieran Fang ◽  
Suprem R. Das ◽  
Ludmila J. Prokopeva ◽  
Vladimir M. Shalaev ◽  
David B. Janes ◽  
...  

Coatings ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 30
Author(s):  
Jinseon You ◽  
Sung Min Lee ◽  
Hong-Sik Eom ◽  
Suk Tai Chang

Transparent conducting electrodes (TCEs) formed with silver nanowires (AgNWs) have attracted attention as substitutes for indium tin oxide (ITO). However, the randomly deposited AgNW film performs poorly in terms of the transmittance and sheet resistance to serve as a substitute of ITO. To improve the performance of the AgNW film, we fabricated a grid-patterned AgNW by modifying the surface energy of the substrate. The hydrophobized surface was selectively etched by UV light through a quartz chrome mask, and a suspension of AgNWs in isopropyl alcohol/ethylene glycol mixture was coated on the substrate by a meniscus dragging deposition process. The grid-patterned AgNW film has a lower percolation threshold and a 13% higher figure-of-merit value compared to the randomly deposited AgNW film. The transparent thin films with a grid structure of AgNWs exhibit the high electrical conductivity with a sheet resistance of 33 Ohm/sq at a transmittance of 92.7% (λ = 550 nm).


Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 693
Author(s):  
Amit Kumar ◽  
Muhammad Omar Shaikh ◽  
Cheng-Hsin Chuang

One-dimensional metal nanowires, with novel functionalities like electrical conductivity, optical transparency and high mechanical stiffness, have attracted widespread interest for use in applications such as transparent electrodes in optoelectronic devices and active components in nanoelectronics and nanophotonics. In particular, silver nanowires (AgNWs) have been widely researched owing to the superlative thermal and electrical conductivity of bulk silver. Herein, we present a detailed review of the synthesis of AgNWs and their utilization in fabricating improved transparent conducting electrodes (TCE). We discuss a range of AgNW synthesis protocols, including template assisted and wet chemical techniques, and their ability to control the morphology of the synthesized nanowires. Furthermore, the use of scalable and cost-effective solution deposition methods to fabricate AgNW based TCE, along with the numerous treatments used for enhancing their optoelectronic properties, are also discussed.


2017 ◽  
Vol 2017 ◽  
pp. 1-14 ◽  
Author(s):  
Nathaniel de Guzman ◽  
Mary Donnabelle L. Balela

High aspect ratio silver (Ag) nanowires with an average length of 25.4 μm and diameter of 102.8 nm were successfully prepared by electroless deposition in hot ethylene glycol (160°C) for 1 h in the presence of PVP. It was found that both PVP concentration and molecular weight significantly influence the morphology and yield of Ag nanowires in solution. Using PVP MW = 55,000, addition of lower amounts of PVP led to formation of large irregularly shaped Ag particles together with a few rod-like structures. Increasing PVP concentration generally resulted in longer and thinner Ag nanowires. On the other hand, low molecular weight PVP produced spherical Ag particles even at high PVP concentration. Ag nanowire flexible transparent conducting electrodes attained a sheet resistance of about 92.5 Ω/sq at an optical transmittance of about 79.6% without any heat treatment. In addition, no significant change in optical and electrical properties was observed after several cycles of bending and adhesion test.


2020 ◽  
Vol 56 (42) ◽  
pp. 5593-5596 ◽  
Author(s):  
Sian-Hong Tseng ◽  
Lian-Ming Lyu ◽  
Kai-Yuan Hsiao ◽  
Wan-Hua Ho ◽  
Ming-Yen Lu

The present study employed the surfactant-free growth of ultralong (∼50 μm) silver nanowires (AgNWs) with a high aspect ratio (more than 1000) by galvanic replacement.


Polymers ◽  
2021 ◽  
Vol 13 (21) ◽  
pp. 3856
Author(s):  
Sujin Cha ◽  
Byeolyi Choi ◽  
Eugene Lee ◽  
Gilsoo Cho

There is an increased need for research on flexible transparent electrodes (FTEs) because they are critical to next-generation electronic devices, such as wearable computers. In this study, highly conductive transparent conducting electrodes, based on polyvinylidene fluoride (PVDF) nanofiber webs treated with poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) and silver nanowires (AgNWs), were successfully fabricated. Transparent conducting electrodes (TCEs) were obtained by a brush-painting process using different weight ratios of a AgNWs to PEDOT:PSS solution, and the surface, electrical, optical, and chemical properties, as well as the tensile strength of the samples, were determined. It was found that the electrical conductivity of the samples improved as the AgNW content increased, but the light transmittance decreased. In this work, there was a slight decrease in the optical properties and a considerable increase in the electrical properties due to the hybridization of AgNWs and PEDOT:PSS, compared to using only PEDOT:PSS. When considering both transparency and electrical conductivity, which are essential parameters of TCEs, sample PA2, which was treated by mixing AgNWs and PEDOT:PSS/dimethyl sulfoxide (DMSO) in a ratio of 1:5 (16.67 wt% of AgNWs), was found to be the best sample, with a sheet resistance of 905 Ω/cm2 and light transmittance of 79%.


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