Chapter 17Progress in Cathode Catalysts for PEFC

2015 ◽  
pp. 542-583
Keyword(s):  
Author(s):  
Aling Chen ◽  
Qingfeng Yi ◽  
Kuang Sheng ◽  
Yuebing Wang ◽  
Jiangchuan Chen ◽  
...  

Exploring efficient metal-free electrocatalyst for oxygen reduction reaction (ORR) plays a significant role in a variety of storage technologies and renewable energy conversion. In this work, we firstly compounded a...


2021 ◽  
pp. 2101423
Author(s):  
Junxiang Zhang ◽  
Fuhui Wang ◽  
Guicai Qi ◽  
Jianli Cheng ◽  
Lin Chen ◽  
...  
Keyword(s):  

2014 ◽  
Vol 70 (10) ◽  
pp. 1610-1616 ◽  
Author(s):  
Huanan Wu ◽  
Min Lu ◽  
Lin Guo ◽  
Leonard Guan Hong Bay ◽  
Zheng Zhang ◽  
...  

Polyelectrolyte–single wall carbon nanotube (SCNT) composites are prepared by a solution-based method and used as metal-free cathode catalysts for oxygen reduction reaction (ORR) in air-cathode microbial fuel cells (MFCs). In this study, two types of polyelectrolytes, polydiallyldimethylammonium chloride (PDDA) and poly[bis(2-chloroethyl)ether-alt-1,3-bis[3-(dimethylamino)propyl]urea] (PEPU) are applied to decorate the SCNTs and the resulting catalysts exhibit remarkable catalytic ability toward ORR in MFC applications. The enhanced catalytic ability could be attributed to the positively charged quaternary ammonium sites of polyelectrolytes, which increase the oxygen affinity of SCNTs and reduce activation energy in the oxygen reduction process. It is also found that PEPU–SCNT composite-based MFCs show efficient performance with maximum power density of 270.1 mW m−2, comparable to MFCs with the benchmark Pt/C catalyst (375.3 mW m−2), while PDDA–SCNT composite-based MFCs produce 188.9 mW m−2. These results indicate that PEPU–SCNT and PDDA–SCNT catalysts are promising candidates as metal-free cathode catalysts for ORR in MFCs and could facilitate MFC scaling up and commercialization.


2015 ◽  
Vol 40 (41) ◽  
pp. 14095-14103 ◽  
Author(s):  
Abudukeremu Kadier ◽  
Yibadatihan Simayi ◽  
K. Chandrasekhar ◽  
Manal Ismail ◽  
Mohd Sahaid Kalil

Sign in / Sign up

Export Citation Format

Share Document