All-Solid-State Rechargeable Batteries

2015 ◽  
pp. 286-299
Keyword(s):  
Solid State ◽  
Rechargeable Batteries

scholarly journals Suppressing Void Formation in All-Solid-State Batteries: The Role of Interfacial Adhesion on Alkali Metal Vacancy Transport

2021 ◽  
Author(s):  
Ieuan Seymour ◽  
Ainara Aguadero
Keyword(s):  
Solid State ◽  
Interfacial Adhesion ◽  
Void Formation ◽  
Rechargeable Batteries ◽  
Metal Anode ◽  
Solid State Batteries ◽  
Promising Solution ◽  
Metal Vacancy ◽  
All Solid State Batteries

All-solid-state batteries containing a solid electrolyte and a lithium (Li) or sodium (Na) metal anode are a promising solution to simultaneously increase the energy density and safety of rechargeable batteries....

PROPERTIES OF ALL-SOLID-STATE LITHIUM-ION RECHARGEABLE BATTERIES DEPOSITED BY RF MAGNETRON SPUTTERING

2013 ◽  
Vol 27 (22) ◽  
pp. 1350156 ◽  
Author(s):  
R. J. ZHU ◽  
Y. REN ◽  
L. Q. GENG ◽  
T. CHEN ◽  
L. X. LI ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Solid State ◽  
Magnetron Sputtering ◽  
Coulombic Efficiency ◽  
Electronic Conductivity ◽  
Lithium Ion ◽  
Rf Magnetron Sputtering ◽  
Rechargeable Batteries ◽  
Voltage Range

Amorphous V 2 O 5, LiPON and Li 2 Mn 2 O 4 thin films were fabricated by RF magnetron sputtering methods and the morphology of thin films were characterized by scanning electron microscopy. Then with these three materials deposited as the anode, solid electrolyte, cathode, and vanadium as current collector, a rocking-chair type of all-solid-state thin-film-type Lithium-ion rechargeable battery was prepared by using the same sputtering parameters on stainless steel substrates. Electrochemical studies show that the thin film battery has a good charge–discharge characteristic in the voltage range of 0.3–3.5 V, and after 30 cycles the cell performance turned to become stabilized with the charge capacity of 9 μAh/cm2, and capacity loss of single-cycle of about 0.2%. At the same time, due to electronic conductivity of the electrolyte film, self-discharge may exist, resulting in approximately 96.6% Coulombic efficiency.

Soft Chemical Routes to Heterostructured High-Tc Superconducting Materials

MRS Bulletin ◽  
2000 ◽  
Vol 25 (9) ◽  
pp. 32-39 ◽  
Author(s):  
Jin-Ho Choy ◽  
Soon-Jae Kwon ◽  
Seong-Ju Hwang ◽  
Eue-Soon Jang
Keyword(s):  
Solid State ◽  
High Performance ◽  
Inorganic Compounds ◽  
Rechargeable Batteries ◽  
Host Lattice ◽  
Inorganic Materials ◽  
Solid State Reactions ◽  
Metal Chalcogenides ◽  
Structural Anisotropy ◽  
Intercalation Reaction

Recently, inorganic/inorganic and organic/inorganic heterostructured materials have attracted considerable research interest, due to their unusual physicochemical properties, which cannot be achieved by conventional solid-state reactions. In order to develop new hybrid materials, various synthetic approaches, such as vacuum deposition, Langmuir–Blodgett films, selfassembly, and intercalation techniques, have been explored. Among them, the intercalation reaction technique—that is, the reversible insertion of guest species into the two-dimensional host lattice—is expected to be one of the most effective tools for preparing new layered heterostructures because this process can provide a soft chemical way of hybridizing inorganic/inorganic, organic/inorganic, or biological/inorganic compounds. In fact, the intercalation/deintercalation process allows us to design high-performance materials in a solution at ambient temperature and pressure, just as “soft solution processing” provides a simple and economical route for advanced inorganic materials by means of an environmentally benign, lowenergy method. These unique advantages of the intercalation technique have led to its wide application to diverse fields of the solid-state sciences, namely, secondary (rechargeable) batteries, electrochromic systems, oxidation–reduction catalysts, separating agents, sorbents, and so on. Through these extensive studies, many kinds of low-dimensional compounds have been developed as host materials for the intercalation reaction, including graphite, transition-metal chalcogenides, transitionmetal oxides, aluminosilicates, metal phosphates, metal chalcogenohalides, and so on. Recently, the area of intercalation chemistry has been extended to high-Tc superconducting copper oxides, resulting in remarkable structural anisotropy.

The effect of lithium excess toward synthesis of Li7La3Zr2O12 cubic garnet-type as solid electrolyte for all solid-state rechargeable batteries

2021 ◽  
Author(s):  
Siti Nur Adlina Norazman ◽  
Nazerah Yaacob ◽  
Rozana Aina Maulat Osman ◽  
Mohd Sobri Idris ◽  
Ku Noor Dhaniah Ku Muhsen
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Rechargeable Batteries

Sulfone Containing Clay Electrolytes and Their Potential for Li-Rechargeable Batteries

1998 ◽  
Vol 548 ◽  
Author(s):  
Gregory J. Moore ◽  
M. Stanley Whittingham
Keyword(s):  
Thermal Analysis ◽  
Solid State ◽  
Rechargeable Batteries ◽  
Molecular Formula ◽  
X Ray Diffraction ◽  
Impedance Measurements ◽  
X Ray ◽  
Lithium Secondary Batteries ◽  
Solid State Cell ◽  
Made In

ABSTRACTClays have been synthesized and several types of molecules have been intercalated into them to enhance their ionic conductivity. The clay has the molecular formula of Litaeniolite, Li(Mg2Li)Si4O10F2, and the inserted molecules include PEO and two varieties of sulfone, tetramethylene sulfone and ethylmethyl sulfone. These have been made in the interest of electrolytes in lithium secondary batteries in order to produce a truly solid state cell. The products have been thoroughly characterized by x-ray diffraction to verify the uptake of the molecules into the layers, thermal analysis to observe the stabilization of the intercalated molecules, along with impedance measurements to test their conductivity.

scholarly journals Mastering the interface for advanced all-solid-state lithium rechargeable batteries

2016 ◽  
Vol 113 (47) ◽  
pp. 13313-13317 ◽  
Author(s):  
Yutao Li ◽  
Weidong Zhou ◽  
Xi Chen ◽  
Xujie Lü ◽  
Zhiming Cui ◽  
...  
Keyword(s):  
Solid State ◽  
Solid Electrolyte ◽  
Solid Electrolyte Interphase ◽  
Rechargeable Batteries ◽  
Ion Conductivity ◽  
Rhombohedral Structure ◽  
Interfacial Resistance ◽  
Lithium Anode ◽  
Metal Anode ◽  
Li Ion

A solid electrolyte with a high Li-ion conductivity and a small interfacial resistance against a Li metal anode is a key component in all-solid-state Li metal batteries, but there is no ceramic oxide electrolyte available for this application except the thin-film Li-P oxynitride electrolyte; ceramic electrolytes are either easily reduced by Li metal or penetrated by Li dendrites in a short time. Here, we introduce a solid electrolyte LiZr2(PO4)3 with rhombohedral structure at room temperature that has a bulk Li-ion conductivity σLi = 2 × 10−4 S⋅cm−1 at 25 °C, a high electrochemical stability up to 5.5 V versus Li+/Li, and a small interfacial resistance for Li+ transfer. It reacts with a metallic lithium anode to form a Li+-conducting passivation layer (solid-electrolyte interphase) containing Li3P and Li8ZrO6 that is wet by the lithium anode and also wets the LiZr2(PO4)3 electrolyte. An all-solid-state Li/LiFePO4 cell with a polymer catholyte shows good cyclability and a long cycle life.

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