Donor and Acceptor Functionalized Silsesquioxane Nanostructures for Organic-Based Photovoltaic Devices

2017 ◽  
pp. 40-63
2003 ◽  
Vol 82 (21) ◽  
pp. 3788-3790 ◽  
Author(s):  
Fanshun Meng ◽  
Kongchang Chen ◽  
He Tian ◽  
Libero Zuppiroli ◽  
Frank Nuesch

2017 ◽  
Vol 31 (02) ◽  
pp. 1650253 ◽  
Author(s):  
Shahryar Tamandani ◽  
Ghafar Darvish

We investigate electron transport between circular graphene quantum dots (CGQDs) and ZnO nanowires (ZnO NWs). This structure can be used as donor and acceptor in hybrid solar cells. We consider circular quantum dots (QDs) and use analytical calculation in order to estimate wavefunctions of GQD and ZnO NWs. After calculating the wavefunctions overlap, we use Marcus relation in order to calculate electron transfer rate. Also, we calculate this transfer rate for CdSe QDs–ZnO NWs system. Results from analytical calculation show that the transfer rate is limited to 10[Formula: see text] s[Formula: see text]. This result is in agreement with experimental results which are reported earlier. Such systems could be suitable for solar cells.


Langmuir ◽  
2012 ◽  
Vol 28 (28) ◽  
pp. 10305-10309 ◽  
Author(s):  
Satoshi Watanabe ◽  
Yasumasa Fukuchi ◽  
Masako Fukasawa ◽  
Takafumi Sassa ◽  
Masanobu Uchiyama ◽  
...  

2019 ◽  
Vol 233 (11) ◽  
pp. 1625-1644 ◽  
Author(s):  
Ahmad Irfan ◽  
Mehboobali Pannipara ◽  
Abdullah G. Al-Sehemi ◽  
Muhammad Waseem Mumtaz ◽  
Mohammed A. Assiri ◽  
...  

Abstract Multifunctional pyrazole derivative, i.e. 3-amino-1-(5-hydroxy-3-methyl-1H-pyrazol-4-yl)-1H-benzo[f]chromene-2-carbonitrile (PBCC) has been synthesized and characterized. To shed light on various properties of interests, the ground state geometry was optimized by adopting Density Functional Theory (PBE/TZ2P). The effect of different functionals on the absorption wavelengths was studied by using Time-Domain DFT (TDDFT), e.g. GGA functional PBE, hybrid functionals B3LYP and PBE0, rang separated functionals CAM-B3LYP, LCY-PBE and CAMY-B3LYP, Dispersion Corrections PBE-D3 and B3LYP-D3. Among all these functionals PBE and PBE-D3 were found to be good choices which reproduced the absorption spectra of the PBCC. With the aim to enhance the electro-optical, charge transfer and photovoltaic properties, five new derivatives were designed by di-substituting the –F, –Cl, –Br, –COOH and –CN at benzochromene moiety. The electron injection barrier, band gap alignment and related calculated photovoltaic parameters revealed that PBCC and its newly designed derivatives would be proficient to be used in photovoltaic devices. These compounds can be used as donor materials in dye-sensitized solar cells (DSSCs) with favorable type-II band alignment. Moreover, PBCC and most of its derivatives might also be good choice as efficient acceptors with poly(dithieno[3,2-b:2,3-d]pyrrole thiophene) (PDTPr-T) and donor materials with Phenyl-C61-butyric acid methyl ester (PC61BM) in organic solar cells.


1981 ◽  
Vol 42 (C4) ◽  
pp. C4-463-C4-466
Author(s):  
A. Madan ◽  
W. Czubatyj ◽  
J. Yang ◽  
J. McGill ◽  
S. R. Ovshinsky

1983 ◽  
Vol 27 ◽  
Author(s):  
L. Salamanca-Riba ◽  
B.S. Elman ◽  
M.S. Dresselhaus ◽  
T. Venkatesan

ABSTRACTRutherford backscattering spectrometry (RBS) is used to characterize the stoichiometry of graphite intercalation compounds (GIC). Specific application is made to several stages of different donor and acceptor compounds and to commensurate and incommensurate intercalants. A deviation from the theoretical stoichiometry is measured for most of the compounds using this non-destructive method. Within experimental error, the RBS results agree with those obtained from analysis of the (00ℓ) x-ray diffractograms and weight uptake measurements on the same samples.


2002 ◽  
Vol 715 ◽  
Author(s):  
Wei Xu ◽  
P. C. Taylor

AbstractWe have made a series of a-SiSx:H based solar cells, with a pin structure, in a multichamber plasma enhanced chemical vapor deposition (PECVD) system. The sulfur concentration ranges from zero to 5 x 1018 cm-3 as measured by secondary ion mass spectroscopy. The initial conversion efficiencies of cells in this series with sulfur concentrations ≤ 1018 cm-3 are approximately 7%. The time constants for degradation increase with increasing sulfur concentration, but not fast enough to be of practical importance in photovoltaic devices.


2011 ◽  
Vol E94-C (12) ◽  
pp. 1838-1844 ◽  
Author(s):  
Naoki OYAMA ◽  
Sho KANEKO ◽  
Katsuaki MOMIYAMA ◽  
Fumihiko HIROSE

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