Aggregation Behavior of Unsubstituted Metal Phthalocyanines in Supramolecular Systems

2014 ◽  
pp. 211-224
Keyword(s):  
Aggregation Behavior ◽  
Supramolecular Systems ◽  
Metal Phthalocyanines

Aggregation Behavior and Thermodynamic Studies of Hydrotropes: A Review

2020 ◽  
Vol 57 (3) ◽  
pp. 192-202 ◽  
Author(s):  
Akash D. Patel ◽  
Meghal A. Desai
Keyword(s):  
Aggregation Behavior ◽  
Thermodynamic Studies

MONOLAYERS LENGMYUR AZAKRAUN-ESSENTIAL DERIVATIVES OF CALIXES[4]ARENA

2018 ◽  
Vol 1 (11(56)) ◽  
pp. 62-64
Author(s):  
A.A. Muravev ◽  
E.A. Ivanova ◽  
A.T. Yakupov
Keyword(s):  
Aggregation Behavior ◽  
Langmuir Films ◽  
Azacrown Ether ◽  
Derivatives Of

In this work, aggregation behavior of azacrown-ether derivatives on a macrocyclic calix[4]arene scaffold within ultrathin Langmuir films on water subphase is considered.

Abiotic Supramolecular Systems

2011 ◽  
Author(s):  
Chad A. Mirkin ◽  
Joseph T. Hupp
Keyword(s):  
Supramolecular Systems

Synthesis and Characterization of New Zinc Phthalocyanine - Dodecenyl Succinic Anhydride Benzoic Groups

2020 ◽  
Vol 17 (6) ◽  
pp. 488-495
Author(s):  
Hussein Ali Al-Bahrani ◽  
Mohanad Mousa Kareem ◽  
Abdul Amir Kadhum ◽  
Nour A. Alrazzak
Keyword(s):  
Salicylic Acid ◽  
Succinic Anhydride ◽  
Zinc Phthalocyanine ◽  
Central Metal ◽  
Target Compound ◽  
Compound I ◽  
Metal Phthalocyanines ◽  
Metal Atoms ◽  
Amino Salicylic Acid

Background: The phthalocyanines a series of compounds involves four iso-indole units linked by aza nitrogen atoms bonded with metal atoms that are normally located in the center a phthalocyanines ring. Some of the central metal-phthalocyanines can be excited by ultraviolet light and emit a fluorescence in far-red region. Objective: To synthesize a derivative of phthalocyanines namely 4,4',4' '-tri-(dodecenyl succinic anhydride)- 4' ' '-(5-amino salicylic acid) zinc phthalocyanine with a zinc central metal. Materials and Methods: The reaction of 4- nitro Phthalonitrile and 4- amino Phthalonitrile with ZnCl2 in the presence of dimethyl amino ethanol afforded 4,4',4' '-triamino-4' ' '-nitro zinc phthalocyanine. This product reacted with 5-amino salicylic acid to yield tetra-(5-amino salicylic acid) zinc phthalocyanine. A dodecenyl succinic anhydride was added on the amine group of benzoic rings to afford 4,4',4' '-tri-(dodecenyl succinic anhydride)-4' ' '-(5-amino salicylic acid) zinc phthalocyanine(I), the target compound. Results and Discussion: Compound I is successfully synthesized with a yield of 72% from tetra-(5-amino salicylic acid) zinc phthalocyanine with dodecenyl succinic anhydride. Conclusion: The newly synthesized molecule of 4,4',4' '-tri-(dodecenyl succinic anhydride)-4' ' '-(5-amino salicylic acid) zinc phthalocyanine (I), tetra-(5-amino salicylic acid) zinc phthalocyanine(E) and 4,4',4' '- triamino-4' ' '-nitro zinc phthalocyanine (S). The reaction of 4- nitro Phthalonitrile and 4- amino and the structure of compound I is confirmed and its formation was proven.

Catalytic Generation of Radicals in Supramolecular Systems with Acetylcholine

2020 ◽  
Vol 61 (5) ◽  
pp. 786-793
Author(s):  
N. V. Potapova ◽  
O. T. Kasaikina ◽  
M. P. Berezin ◽  
I. G. Plashchina
Keyword(s):  
Supramolecular Systems

Aggregation behavior and foam properties of the mixture of hydrocarbon and fluorocarbon surfactants with addition of nanoparticles

2021 ◽  
Vol 323 ◽  
pp. 115070
Author(s):  
Youjie Sheng ◽  
Menghua Xue ◽  
Yubo Wang ◽  
Xudong Zhai ◽  
Shanwen Zhang ◽  
...  
Keyword(s):  
Aggregation Behavior ◽  
Foam Properties

scholarly journals Structure and Location of Protein Sites Binding Self-Associated Congo Red Molecules with Intercalated Drugs as Compact Ligands—Theoretical Studies

Biomolecules ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 501
Author(s):  
Ptak-Kaczor Magdalena ◽  
Kwiecińska Klaudia ◽  
Korchowiec Jacek ◽  
Chłopaś Katarzyna ◽  
Banach Mateusz ◽  
...  
Keyword(s):  
Organic Compounds ◽  
Light Chain ◽  
Congo Red ◽  
Theoretical Studies ◽  
Mathematical Tool ◽  
Supramolecular Systems ◽  
Micellar Structure ◽  
Protein Molecules ◽  
Toxic Drugs ◽  
Independent Property

In the search for new carriers capable of transporting toxic drugs to a target, particular attention has been devoted to supramolecular systems with a ribbon-like micellar structure of which Congo red is an example. A special promise of the possible use of such systems for directing drugs to a target emerges from their particular affinity to immune complexes and as an independent property, binding many organic compounds including drugs by intercalation. Serum albumin also appeared able to bind micellar particles of such systems. It may protect them against dilution in transport. The mathematical tool, which relies on analysis of the distribution of polarity and hydrophobicity in protein molecules (fuzzy oil drop model), has been used to find the location of binding area in albumin as well as anchorage site for Congo red in heated IgG light chain used as a model presenting immunoglobulin-like structures. Results confirm the suggested formerly binding site of Congo red in V domain of IgG light chain and indicated the cleft between pseudo-symmetric domains of albumin as the area of attachment for the dye.

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