Study on the corrosion of rebars in fly ash concrete during moderate to high corrosion rate

Author(s):  
I Zafar ◽  
T Sugiyama
Materials ◽  
2020 ◽  
Vol 13 (22) ◽  
pp. 5135
Author(s):  
Manuel Valcuende ◽  
Rafael Calabuig ◽  
Ana Martínez-Ibernón ◽  
Juan Soto

The main objective of this study was to analyze the influence that the addition of finely ground hydrated lime has on chloride-induced reinforcement corrosion in eco-efficient concrete made with 50% cement replacement by fly ash. Six tests were carried out: mercury intrusion porosimetry, chloride migration, accelerated chloride penetration, electrical resistivity, and corrosion rate. The results show that the addition of 10–20% of lime to fly ash concrete did not affect its resistance to chloride penetration. However, the cementitious matrix density is increased by the pozzolanic reaction between the fly ash and added lime. As a result, the porosity and the electrical resistivity improved (of the order of 10% and 40%, respectively), giving rise to a lower corrosion rate (iCORR) of the rebars and, therefore, an increase in durability. In fact, after subjecting specimens to wetting–drying cycles in a 0.5 M sodium chloride solution for 630 days, corrosion is considered negligible in fly ash concrete with 10% or 20% lime (iCORR less than 0.2 µA/cm2), while in fly ash concrete without lime, corrosion was low (iCORR of the order of 0.3 µA/cm2) and in the reference concrete made with Portland cement, only the corrosion was high (iCORR between 2 and 3 µA/cm2).


2015 ◽  
Vol 1110 ◽  
pp. 107-112 ◽  
Author(s):  
Keiji Miyata ◽  
Takao Ueda ◽  
Masayuki Tsukagoshi

In order to consider the durability of fly ash concrete against the chloride attack, quantitative evaluation of rebar corrosion rate in concrete is necessary. In this study, reinforced concrete specimens containing premixed chlorides were prepared, using concrete with cement or fine aggregate partly substituted by fly-ash. The corrosion rate of rebar embedded in the specimen was evaluated by measuring the polarization resistance which is an electrochemical corrosion index and one of the non-destructive techniques. As a result, the corrosion rate of rebar was greatly suppressed by admixing fly-ash at the environmental temperature of 20 degrees Celsius, while such suppression effect decreased with the rise of temperature to 40 degrees Celsius. The suppression effect was remarkable in the case of fly ash addition as the substitution of fine aggregate. Moreover, in the experimental conditions of this study, the influence of a variation of the chloride content in concrete on the corrosion rate of steel in concrete was not so significant. The influence of environmental temperature on the corrosion rate could be evaluated by an existing formula in the case of non-fly ash concrete, but the error became relatively high in the cases of fly ash concrete.


2019 ◽  
Vol 37 (2) ◽  
pp. 157-178
Author(s):  
Wei Zhang ◽  
Sanae Haskouri ◽  
Georges Houlachi ◽  
Edward Ghali

AbstractIn recent years, a renewed interest in studying the electrochemical corrosion behavior of lead anodes during zinc electrowinning is probably due to the particularly high sulfuric acid concentrations in zinc electrolyte where lead alloy anodes have high cell voltage and high corrosion rate of lead. The high corrosion rate of lead alloy resulted in Pb contamination on zinc deposit. In zinc electrometallurgy, the electrolyte from a zinc-rich ore contains a significant amount of Mn2+. Mn2+ in the zinc electrolyte results in forming an oxide film on lead anodes during electrolysis. Pb-0.7% Ag anode is generally used in the zinc industry. To improve the technical performance and decrease product cost, other anodes, such as Pb-Ca or Pb-Ag-Ca or Pb-Ag-Ti or Pb-Ag-Se alloys were tested. Till now, none of them has succeeded in the substitution of Pb-Ag anodes in the zinc electrowinning. As an alloying element, silver in small quantities is considered because of the benefits that generates on the anode during electrolysis. During zinc electrolysis, lead dissolution into the zinc electrolyte can be harmful to the quality of zinc deposit. However, the lead silver alloy anode can decrease the lead content in the zinc deposit by pre-treated methods such as blasting and preconditioning.


2016 ◽  
Vol 42 (3) ◽  
pp. 1039-1048 ◽  
Author(s):  
Santosh Ashok Kadapure ◽  
Girish S. Kulkarni ◽  
K. B. Prakash

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