EFFECT OF AMINO NAPHTHALENE SULFONIC ACID NATURE ON THE STRUCTURE AND PHYSICAL PROPERTIES OF THEIR COPOLYMERS WITH ANILINE

2014 ◽  
pp. 235-248
Materials ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1476 ◽  
Author(s):  
Dongliang Kuang ◽  
Zhou Ye ◽  
Lifeng Yang ◽  
Ning Liu ◽  
Zaihong Lu ◽  
...  

DBSA was used as a solubilizer together with conventional rejuvenator (CR) to produce a solubilized rejuvenator (SR), two kinds of aged bitumen involving TFOT aged bitumen and PAV aged bitumen were obtained by thin film oven test (TFOT) and pressurized aging vessel (PAV), respectively. Effects of CR and SR on the physical properties, chemical components, colloidal structure and micro-morphology of TFOT aged bitumen and PAV aged bitumen were investigated. Testing results of physical properties and chemical components indicated that CR and SR can replenish aged bitumen with necessary aromatics, TFOT aged bitumen that chemical component variation deteriorates its physical properties. With regard to PAV aged bitumen, of which the performance attenuation lies in chemical components variation and colloidal structure transformation, even if the content of CR reached up to 10 wt %, the regenerated bitumen cannot meet the regeneration requirement yet due to its definite influence on colloidal structure transformation, comparatively, sulfonic group in SR can react with the superficial atoms of asphaltenes to reform a solvation layer to facilitate the colloidal structure transformation of PAV aged bitumen, performance and beelike structure of regenerated PAV aged with bitumen with 10 wt % SR were approximated to that of virgin bitumen.


2013 ◽  
Vol 35 (1) ◽  
pp. 60-67 ◽  
Author(s):  
C. Basavaraja ◽  
Kwang Il Kim ◽  
Gyu Ho Jung ◽  
Do Sung Huh

Author(s):  
Jyoti Nayak ◽  
Suresha K Mahadeva ◽  
Jaehwan Kim

This article investigates the possibility of soluble polypyrrole coating on cellulose as an alternative low-cost electrode material for paper speaker application. Soluble polypyrrole was prepared using β-naphthalene sulfonic acid as dopant and ammonium persulfate as oxidizing agent. For coating soluble polypyrrole on regenerated cellulose, prepared polypyrrole powder was dissolved in N-Methylpyrrolidone. N-Methylpyrrolidone was chosen to dissolve β-naphthalene sulfonic acid-doped polypyrrole due to large dielectric constant (32.2) compared with other organic solvents. It is observed that the optical transmittance of cellulose tends to decrease while electrical conductivity increases with increase of the β-naphthalene sulfonic acid doped polypyrrole– N-Methylpyrrolidone coatings, due to increased thickness of the polypyrrole layer on cellulose films.


2012 ◽  
Vol 65 (5) ◽  
pp. 802-807 ◽  
Author(s):  
Wenjian Shi ◽  
Shuwei Chen ◽  
Fei Chang ◽  
Yue Han ◽  
Yuanzhang Zhang

Chitosan-β-cyclodextrin (CTS-CD) prepared through a crosslinking reaction between chitosan and β-cyclodextrin was employed to adsorb the three following sulfo-group-containing aromatics: disodium 2-naphthol-3,6-disulfonate (R salt), 2-naphthalene sulfonic acid (NSA), and sodium dodecylbenzene sulfonate (SDBS). At 318 K, the saturated adsorption capacity of CTS-CD for R salt, NSA, and SDBS was 431, 416, and 376 mg/g, respectively. The experimental data fitted the second-order model well and the rate constant of the adsorption increased with the temperature increment. The values of apparent activation energy for R salt, NSA, and SDBS were calculated as 33.2, 34.2, and 16.8 kJ/mol respectively. The isothermal adsorption was found following the Langmuir adsorption equation. The negative values of ΔG and the positive values of ΔH indicated that the adsorption process was spontaneous and exothermic.


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