Preparation of a Palladium Complex

2013 ◽  
pp. 177-184
Keyword(s):  
Palladium Complex

ChemInform Abstract: Diastereoselective Carbonyl Allylation with Simple Olefins Enabled by Palladium Complex-Catalyzed C-H Oxidative Borylation.

ChemInform ◽  
2015 ◽  
Vol 46 (35) ◽  
pp. no-no
Author(s):  
Zhong-Lin Tao ◽  
Xing-Han Li ◽  
Zhi-Yong Han ◽  
Liu-Zhu Gong
Keyword(s):  
Palladium Complex ◽  
Carbonyl Allylation

First use of a palladium complex with a thiosemicarbazone ligand as catalyst precursor for the Heck reaction

2004 ◽  
Vol 45 (14) ◽  
pp. 2923-2926 ◽  
Author(s):  
Dimitra Kovala-Demertzi ◽  
Paras N. Yadav ◽  
Mavroudis A. Demertzis ◽  
Jerry P. Jasiski ◽  
Fotini J. Andreadaki ◽  
...  
Keyword(s):  
Heck Reaction ◽  
Palladium Complex ◽  
Catalyst Precursor ◽  
Thiosemicarbazone Ligand

Palladium Complex Catalyzed Acylation of Allylic Esters with Acylsilanes

2001 ◽  
Vol 123 (43) ◽  
pp. 10489-10493 ◽  
Author(s):  
Yasushi Obora ◽  
Yasuhiro Ogawa ◽  
Yuji Imai ◽  
Takashi Kawamura ◽  
Yasushi Tsuji
Keyword(s):  
Palladium Complex ◽  
Allylic Esters

Unsymmetrical phthalocyanines with cyclopalladated azo functions

2012 ◽  
Vol 16 (02) ◽  
pp. 192-199 ◽  
Author(s):  
H. Yasemin Yenilmez Akkurt ◽  
Ali ihsan Okur ◽  
Ahmet Gül
Keyword(s):  
Organic Solvents ◽  
Column Chromatography ◽  
Spectroscopic Analysis ◽  
Palladium Complex ◽  
Palladium Complexes ◽  
High Solubility ◽  
Synthetic Procedure ◽  
Different Types ◽  
New Compounds ◽  
Very High

In this study, a synthetic procedure for unsymmetrical metallophthalocyanines of the form M[Pc(AB3)], where A and B refer to two different types of peripheral functionality, has been developed and the new compounds have been converted to monomeric and dimeric palladium complexes. Asymmetrically substituted phthalocyanines were synthesized with the well-known statistical condensation method, by using two differently substituted precursors, namely 4-(2-ethoxyethoxy)-1-2-dicyanobenzene (1) and 4-{4-[Z/E]-phenylazo]-1-naphthyl}oxy-1,2-dicyanobenzene (2). Consequently, electron-donating 2-ethoxyethoxy groups and electron-withdrawing palladium complex are present in the same structure. Cyclopalladation was performed with [Pd(PhCN)2Cl2] to yield the bis-μ-chloro-bridged dimers and subsequently, the corresponding monomers were obtained by refluxing with three equivalents of potassium acetylacetonate. The resulting products were purified by column chromatography and characterized by several chemical and spectroscopic analysis methods. All compounds have very high solubility in organic solvents due to the presence of 2-ethoxyethoxy moiety.

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