Models for the Pore-Size Distribution of Microporous Materials from a Single Adsorption Isotherm

Adsorption ◽  
2002 ◽  
pp. 183-218
Keyword(s):  
Adsorption Isotherm ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Microporous Materials

scholarly journals NLDFT Pore Size Distribution in Amorphous Microporous Materials

Langmuir ◽  
2017 ◽  
Vol 33 (42) ◽  
pp. 11138-11145 ◽  
Author(s):  
Grit Kupgan ◽  
Thilanga P. Liyana-Arachchi ◽  
Coray M. Colina
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Microporous Materials

What kind of pore size distribution is assumed in the Dubinin–Astakhov adsorption isotherm equation?

Carbon ◽  
2002 ◽  
Vol 40 (15) ◽  
pp. 2879-2886 ◽  
Author(s):  
Artur P. Terzyk ◽  
Piotr A. Gauden ◽  
Piotr Kowalczyk
Keyword(s):  
Adsorption Isotherm ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Isotherm Equation

pyGAPS: A Python-Based Framework for Adsorption Isotherm Processing and Material Characterisation

2019 ◽  
Author(s):  
Paul Iacomi ◽  
Philip L. Llewellyn
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Surface Area ◽  
Isosteric Heat ◽  
Material Characterisation ◽  
Mixture Adsorption ◽  
Surface Energetics ◽  
Adsorption Processing ◽  
User Friendly

Material characterisation through adsorption is a widely-used laboratory technique. The isotherms obtained through volumetric or gravimetric experiments impart insight through their features but can also be analysed to determine material characteristics such as specific surface area, pore size distribution, surface energetics, or used for predicting mixture adsorption. The pyGAPS (python General Adsorption Processing Suite) framework was developed to address the need for high-throughput processing of such adsorption data, independent of the origin, while also being capable of presenting individual results in a user-friendly manner. It contains many common characterisation methods such as: BET and Langmuir surface area, t and α plots, pore size distribution calculations (BJH, Dollimore-Heal, Horvath-Kawazoe, DFT/NLDFT kernel fitting), isosteric heat calculations, IAST calculations, isotherm modelling and more, as well as the ability to import and store data from Excel, CSV, JSON and sqlite databases. In this work, a description of the capabilities of pyGAPS is presented. The code is then be used in two case studies: a routine characterisation of a UiO-66(Zr) sample and in the processing of an adsorption dataset of a commercial carbon (Takeda 5A) for applications in gas separation.

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