Properties of oxide coatings deposited on a plastic substrate by a successive pulsed plasma anodisation process

2014 ◽  
pp. 215-224
Keyword(s):  
Plastic Substrate ◽  
Pulsed Plasma ◽  
Oxide Coatings ◽  
Anodisation Process

Study on Effects of Technological Parameters of Micro-Arc Oxidation on Properties of Oxide Coatings

2019 ◽  
Vol 24 (4) ◽  
pp. 363-369
Author(s):  
Ekaterina A. Pecherskaya ◽  
◽  
Pavel E. Golubkov ◽  
Oleg V. Karpanin ◽  
Dmitriy V. Artamonov ◽  
...  
Keyword(s):  
Oxide Coatings ◽  
Technological Parameters ◽  
Micro Arc Oxidation

APPLICATION OF TITANIUM OXIDE COATINGS FOR NEUTRALIZATION OF HAZARDOUS CHEMICAL SUBSTANCES

2019 ◽  
Vol 2 (12) ◽  
pp. 131-136
Author(s):  
О. Halak ◽  
N. Poltorak ◽  
О. Kravchuk ◽  
V. Synko ◽  
Y. Korol
Keyword(s):  
Ultraviolet Rays ◽  
Gaseous Emissions ◽  
Oxide Coatings ◽  
Mobile Objects ◽  
Hazardous Chemical ◽  
Catalytic Material ◽  
Air Purifier ◽  
Domestic Use ◽  
Purification Methods ◽  
Plasma Electrolytic

Contamination of hazardous chemicals is currently considered one of the major environmental problems. The methods of purification of gaseous emissions depending on the physicochemical properties of pollutants, in particular dangerous chemical, their aggregate state, concentration in the gas environment are studied in this article. The effect of aerosol content such as dust and soot is analyzed as well as the efficiency of purification methods at different temperature intervals, methods of purification of multicomponent mixtures. The comparative characteristics of thermochemical, reagent, sorption and catalytic methods are given and the prospects of their application in filtering systems of stationary and mobile objects are evaluated. It has been proved that almost any organic compounds can be oxidized (mineralized) on the TiO2surface. In practice, any photocatalytic air purifier includes a porous TiO2 deposited carrier, which is irradiated with ultraviolet rays and through which air is purged. Photocatalysis is suitable for domestic use as it can occur at room temperature. For example, a thermocatalytic method of destroying harmful substances requires preheating the air to a temperature above 200 ° C. Photocatalysis destroys substances that penetrate even through activated carbon filters. Features of formation of oxide coatings by plasma-electrolytic oxidation of titanium alloys are considered. It is proposed to refine the design of collective defense systems on armored vehicles and stationary facilities with additional installation in the filter-absorber of the grid with the deposited layer of catalytic material, which will neutralize various types of dangerous chemicals due to photocatalytic air purification.

Facile and Fast Detection of Genistein in Derris scandens by Square Wave Voltammetry using a Cobalt(II) Phthalocyanine-Modified Screen-Printed Electrochemical Sensor

2020 ◽  
Vol 16 (3) ◽  
pp. 341-348
Author(s):  
Surinya Traipop ◽  
Suchada Chuanuwatanakul ◽  
Orawon Chailapakul ◽  
Eakkasit Punrat
Keyword(s):  
Electrochemical Sensor ◽  
Square Wave Voltammetry ◽  
Silver Chloride ◽  
Reference Electrode ◽  
High Sensitivity ◽  
Plastic Substrate ◽  
Fast Analysis ◽  
Square Wave ◽  
Wave Voltammetry ◽  
Screen Printed

Background: Recently, Derris scandens, a Thai herbal medicine with anti-inflammatory activity, is widely used as beverage and supplementary food. When the traditional medicine is a choice for health therapy, the simple and reliable equipment is required to control the suitable consuming amount of the active component. Objective: To develop the electrochemical sensor for genistein determination in Derris scandens with high sensitivity and rapid operation. Methods: An in-house screen-printed electrochemical sensor consisting of a three-electrode system was developed for genistein determination. A silver/silver chloride (Ag/AgCl) reference electrode, a carbon counter electrode and a carbon working electrode were prepared on a 0.3-mm-thick plastic substrate by the screen-printing technique using conductive ink. The dimensions of each sensor were 2.5×1.0 cm. Only 50 µL of sample solution was required on this device for the determination of genistein concentration by rapid response square wave voltammetry. Results: The oxidation peak of genistein appeared with good response in acidic media at a peak potential of 0.6 V. Moreover, the signal was enhanced by modifying the conductive carbon ink with cobalt( II) phthalocyanine. Under the optimized conditions, the linear range was found to be 2.5-150 µM and the detection limit was 1.5 µM. Moreover, the small volume extraction was successfully developed without any further pre-concentration. This proposed method was applied to determine genistein in Derris scandens with satisfying results. Conclusion: The proposed method is promising as an alternative method for genistein determination with facile and fast analysis.

scholarly journals Obtaining Silicon Oxide Nanoparticles Doped with Fluorine and Gold Particles by the Pulsed Plasma-Chemical Method

2019 ◽  
Vol 2019 ◽  
pp. 1-6
Author(s):  
Galina Kholodnaya ◽  
Roman Sazonov ◽  
Denis Ponomarev ◽  
Igor Zhirkov
Keyword(s):  
Chemical Synthesis ◽  
Silicon Oxide ◽  
Fine Particles ◽  
Chemical Reactor ◽  
Beam Diameter ◽  
Pulsed Plasma ◽  
Plasma Chemical ◽  
Plasma Chemical Synthesis ◽  
Transmission Electron ◽  
Average Size

This paper presents a study on pulsed plasma-chemical synthesis of fluorine- and gold-doped silicon oxide nanopowder. The gold- and fluorine-containing precursors were gold chloride (AuCl3) and sulphur hexafluoride (SF6). Pulsed plasma-chemical synthesis is realized on the laboratory stand, including a plasma-chemical reactor and TEA-500 electron accelerator. The parameters of the electron beam are as follows: 400–450 keV electron energy, 60 ns half-amplitude pulse duration, up to 200 J pulse energy, and 5 cm beam diameter. We confirmed the composite structure of SixOy@Au by using transmission electron microscopy and energy-dispersive spectroscopy. We determined the chemical composition and morphology of synthesized SixOy@Au and SixOy@F nanocomposites. The material contained a SixOy@Au carrier with an average size of 50–150 nm and a shell of fine particles with an average size of 5–10 nm.

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