Shape Memory Polymer Blends

2016 ◽  
pp. 140-159
Polymers ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1900
Author(s):  
Ramin Hosseinnezhad ◽  
Iurii Vozniak ◽  
Fahmi Zaïri

The paper discusses the possibility of using in situ generated hybrid polymer-polymer nanocomposites as polymeric materials with triple shape memory, which, unlike conventional polymer blends with triple shape memory, are characterized by fully separated phase transition temperatures and strongest bonding between the polymer blends phase interfaces which are critical to the shape fixing and recovery. This was demonstrated using the three-component system polylactide/polybutylene adipateterephthalate/cellulose nanofibers (PLA/PBAT/CNFs). The role of in situ generated PBAT nanofibers and CNFs in the formation of efficient physical crosslinks at PLA-PBAT, PLA-CNF and PBAT-CNF interfaces and the effect of CNFs on the PBAT fibrillation and crystallization processes were elucidated. The in situ generated composites showed drastically higher values of strain recovery ratios, strain fixity ratios, faster recovery rate and better mechanical properties compared to the blend.


2016 ◽  
Vol 74 (7) ◽  
pp. 2535-2544 ◽  
Author(s):  
Muhammad Kashif ◽  
Sung-Jin Kim ◽  
Young-Wook Chang

2017 ◽  
Vol 5 (33) ◽  
pp. 8361-8365 ◽  
Author(s):  
Siyuan Chen ◽  
Qinglong Zhang ◽  
Jiachun Feng

3D-printable tunable SMPs consisting of three kinds of cheap commercial polymers are prepared using a simple melt blending strategy.


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