Boron Trichloride (BCl3)

2011 ◽  
pp. 277-278
Keyword(s):  
Boron Trichloride

Regioselective debenzylation of C-glycosyl compounds by boron trichloride

2005 ◽  
Vol 340 (3) ◽  
pp. 481-487 ◽  
Author(s):  
Juan Xie ◽  
Mickaël Ménand ◽  
Jean-Marc Valéry
Keyword(s):  
Boron Trichloride

The system phosphorus trichloride and boron trichloride

2010 ◽  
Vol 86 (6) ◽  
pp. 593-596 ◽  
Author(s):  
P. W. N. M. van Leeuwen ◽  
W. L. Groeneveld
Keyword(s):  
Phosphorus Trichloride ◽  
Boron Trichloride

Analysis of Pesticide Residues by Chemical Derivatization. V. Multiresidue Analysis of Eight Phenoxyalkanoic Acid Herbicides in Natural Waters

1977 ◽  
Vol 60 (5) ◽  
pp. 1070-1076 ◽  
Author(s):  
Haig Agemian ◽  
Alfred S Y Chau
Keyword(s):  
Natural Waters ◽  
Chromatographic Determination ◽  
Multiresidue Analysis ◽  
Boron Trichloride ◽  
Advantages And Disadvantages ◽  
Pentafluorobenzyl Bromide ◽  
Extraction Scheme ◽  
Liquid Chromatographic Determination ◽  
Liquid Chromatographic ◽  
Acid Herbicides

Abstract A multiresidue method is presented for the gas-liquid chromatographic determination of phenoxyalkanoic acid herbicides in natural waters. Extraction efficiencies of different organic solvents are considered in developing a solvent extraction scheme for these herbicides from water. Reactions for derivatizing these compounds by using pentafluorobenzyl bromide, boron trichloride-2-chloroethanol, and dicyclohexylcarbodiimide-2-chloroethanol were studied in order to obtain extracts with low blanks to provide the lowest detection limits. Advantages and disadvantages of the 3 methods are discussed. Retention times are twice as long for the pentafluorobenzyl (PFB) esters as for the 2-chloroethyl (2-Cl) esters under the same conditions, although electron capture sensitivity to the former was greater. The PFB esters are easier to form, but the 2-Cl reaction is more specific for these herbicides. Solutions from the boron trichloride reaction gave the cleanest blanks.

145. The reactivity of the methyl α-D-glucoside–boron trichloride reagent

1962 ◽  
Vol 0 (0) ◽  
pp. 761-767 ◽  
Author(s):  
T. G. Bonner ◽  
E. J. Bourne ◽  
S. McNally
Keyword(s):  
Boron Trichloride
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