Comprehensive Handbook of Chemical Bond Energies

2007 ◽  
Author(s):  
Yu-Ran Luo
Keyword(s):  
Chemical Bond ◽  
Bond Energies

The Measurement of Adiabatic Lonization Potential of Si(CH3)3Cl and Chemical Bond Energies of Si(CH3)3Cl+

1996 ◽  
Vol 12 (06) ◽  
pp. 560-563
Author(s):  
Chen Wen-Wu ◽  
◽  
Sheng Liu-Si ◽  
Ding Chuan-Fan ◽  
Qi Fei ◽  
...  
Keyword(s):  
Chemical Bond ◽  
Bond Energies

scholarly journals Sunlight-Initiated Photochemistry: Excited Vibrational States of Atmospheric Chromophores

2008 ◽  
Vol 2008 ◽  
pp. 1-13 ◽  
Author(s):  
Veronica Vaida ◽  
Karl J. Feierabend ◽  
Nabilah Rontu ◽  
Kaito Takahashi
Keyword(s):  
Solar Radiation ◽  
Electronic State ◽  
Chemical Bond ◽  
Wavelength Range ◽  
Chemical Reactions ◽  
Energy Barrier ◽  
Bond Energies ◽  
Vibrational States ◽  
Vibrational Levels ◽  
Combination Bands

Atmospheric chemical reactions are often initiated by ultraviolet (UV) solar radiation since absorption in that wavelength range coincides to typical chemical bond energies. In this review, we present an alternative process by which chemical reactions occur with the excitation of vibrational levels in the ground electronic state by red solar photons. We focus on the O–H vibrational manifold which can be an atmospheric chromophore for driving vibrationally mediated overtone-induced chemical reactions. Experimental and theoretical O–H intensities of several carboxylic acids, alcohols, and peroxides are presented. The importance of combination bands in spectra at chemically relevant energies is examined in the context of atmospheric photochemistry. Candidate systems for overtone-initiated chemistry are provided, and their lowest energy barrier for reaction and the minimum quanta of O–H stretch required for reaction are calculated. We conclude with a discussion of the major pathways available for overtone-induced reactions in the atmosphere.

The Significance of Chemical Bond Energies

1934 ◽  
Vol 2 (10) ◽  
pp. 671-680 ◽  
Author(s):  
C. T. Zahn
Keyword(s):  
Chemical Bond ◽  
Bond Energies

Density functionals and chemical bond, diatomic molecules

1989 ◽  
Vol 86 ◽  
pp. 853-859 ◽  
Author(s):  
Federico Moscardó ◽  
José Pérez-Jordá ◽  
Emilio San-Fabián
Keyword(s):  
Chemical Bond ◽  
Diatomic Molecules ◽  
Density Functionals

The Chemical Bond Across the Periodic Table: Part 1 – First Row and Simple Metals

2020 ◽  
Author(s):  
Gabriel Freire Sanzovo Fernandes ◽  
Leonardo dos Anjos Cunha ◽  
Francisco Bolivar Correto Machado ◽  
Luiz Ferrão
Keyword(s):  
Physical Chemistry ◽  
Chemical Bond ◽  
Materials Science ◽  
Chemical Elements ◽  
Orbital Theory ◽  
Solid State Physics ◽  
Band Theory ◽  
Van Der Waals Clusters ◽  
Earth Systems ◽  
Chemical Content

<p>Chemical bond plays a central role in the description of the physicochemical properties of molecules and solids and it is essential to several fields in science and engineering, governing the material’s mechanical, electrical, catalytic and optoelectronic properties, among others. Due to this indisputable importance, a proper description of chemical bond is needed, commonly obtained through solving the Schrödinger equation of the system with either molecular orbital theory (molecules) or band theory (solids). However, connecting these seemingly different concepts is not a straightforward task for students and there is a gap in the available textbooks concerning this subject. This work presents a chemical content to be added in the physical chemistry undergraduate courses, in which the framework of molecular orbitals was used to qualitatively explain the standard state of the chemical elements and some properties of the resulting material, such as gas or crystalline solids. Here in Part 1, we were able to show the transition from Van der Waals clusters to metal in alkali and alkaline earth systems. In Part 2 and 3 of this three-part work, the present framework is applied to main group elements and transition metals. The original content discussed here can be adapted and incorporated in undergraduate and graduate physical chemistry and/or materials science textbooks and also serves as a conceptual guide to subsequent disciplines such as quantum chemistry, quantum mechanics and solid-state physics.</p>

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