Surface Modification of Polymeric Materials by Poiyaniline and Application of Polyaniline/Polymeric Composites

Author(s):  
Yu. A. Hnizdiukh ◽  
M. M. Yatsyshyn ◽  
O. V. Reshetnyak
2020 ◽  
Vol 27 (10) ◽  
pp. 1616-1633 ◽  
Author(s):  
Oana Cristina Duta ◽  
Aurel Mihail Ţîţu ◽  
Alexandru Marin ◽  
Anton Ficai ◽  
Denisa Ficai ◽  
...  

Polymeric materials, due to their excellent physicochemical properties and versatility found applicability in multiples areas, including biomaterials used in tissue regeneration, prosthetics (hip, artificial valves), medical devices, controlled drug delivery systems, etc. Medical devices and their applications are very important in modern medicine and the need to develop new materials with improved properties or to improve the existent materials is increasing every day. Numerous reasearches are activated in this domain in order to obtain materials/surfaces that does not have drawbacks such as structural failure, calcifications, infections or thrombosis. One of the most used material is poly(vinylchloride) (PVC) due to its unique properties, availability and low cost. The most common method used for obtaining tubular devices that meet the requirements of medical use is the surface modification of polymers without changing their physical and mechanical properties, in bulk. PVC is a hydrophobic polymer and therefore many research studies were conducted in order to increase the hydrophilicity of the surface by chemical modification in order to improve biocompatibility, to enhance wettability, reduce friction or to make lubricious or antimicrobial coatings. Surface modification of PVC can be achieved by several strategies, in only one step or, in some cases, in two or more steps by applying several techniques consecutively to obtain the desired modification / performances. The most common processes used for modifying the surface of PVC devices are: plasma treatment, corona discharge, chemical grafting, electric discharge, vapour deposition of metals, flame treatment, direct chemical modification (oxidation, hydrolysis, etc.) or even some physical modification of the roughness of the surface.


Author(s):  
Karthik Babu ◽  
Oisik Das ◽  
Vigneshwaran Shanmugam ◽  
Rhoda Afriye Mensah ◽  
Michael Försth ◽  
...  

Abstract3D printing or additive manufacturing (AM) is considered as a flexible manufacturing method with the potential for substantial innovations in fabricating geometrically complicated structured polymers, metals, and ceramics parts. Among them, polymeric composites show versatility for applications in various fields, such as constructions, microelectronics and biomedical. However, the poor resistance of these materials against fire must be considered due to their direct relation to human life conservation and safety. In this article, the recent advances in the fire behavior of 3D-printed polymeric composites are reviewed. The article describes the recently developed methods for improving the flame retardancy of 3D-printed polymeric composites. Consequently, the improvements in the fire behavior of 3D-printed polymeric materials through the change in formulation of the composites are discussed. The article is novel in the sense that it is one of the first studies to provide an overview regarding the flammability characteristics of 3D-printed polymeric materials, which will further incite research interests to render AM-based materials fire-resistant.


2000 ◽  
Vol 127 (1) ◽  
pp. 18-23 ◽  
Author(s):  
Z. Iskanderova ◽  
J. Kleiman ◽  
Y. Gudimenko ◽  
R.C. Tennyson ◽  
W.D. Morison

2005 ◽  
Vol 890 ◽  
Author(s):  
Ali Razavi

ABSTRACTThis study was undertaken to improve the bonding of fluorinated and non-fluorinated polymers to acrylic and silicone based adhesives. The polymeric materials were exposed to plasma which is comprised of methane and a second gas selected from air, Oxygen and Nitrogen or a mixture thereof. By application of surface analysis (XPS), the optimized functionality can be incorporated in the surface of desired polymers to enhance the bond ability of prepared films for pressure sensitive tape applications. Perfluoroalkoxy-tetrafluoroethylene copolymer PFA, fluorinated ethylene-propylene FEP, Polytetrafluoroethylene PTFE, and Polyester materials were exposed to this plasma. The treated samples were coated with adhesives and the adhesion to steel, holding power and other properties associated with tapes performance were studied.


BIBECHANA ◽  
2020 ◽  
Vol 17 ◽  
pp. 133-138 ◽  
Author(s):  
H B Baniya ◽  
R P Guragain ◽  
B Baniya ◽  
G Qin ◽  
D P Subedi

Atmospheric Pressure Plasma Jet (APPJ) has many applications in material processing such as surface modification and biomedical material processing. APPJ has been generated by a high voltage power supply (0-20 KV) at an operating frequency of (20-30) 23 kHz. This paper reports the generation and characterization of APPJ in Argon environment and its application in the surface modification of polymeric materials. The discharge has been characterized by optical and electrical methods. In order to characterize the plasma jet, its electron temperature and electron density has been determined by optical emissions spectroscopy. The surface properties of the untreated and plasma treated Polyamide (PA) samples were characterized by contact angle measurement and surface energy analysis. BIBECHANA 17 (2020) 133-138


2014 ◽  
Vol 314 ◽  
pp. 367-375 ◽  
Author(s):  
K.G. Kostov ◽  
T.M.C. Nishime ◽  
A.H.R. Castro ◽  
A. Toth ◽  
L.R.O. Hein

Author(s):  
Chengyan Ren ◽  
Chuansheng Zhang ◽  
Fei Kong ◽  
Cheng Zhang ◽  
Tao Shao ◽  
...  

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