High-resolution surface NMR tomography of shallow aquifers based on multioffset measurements

Geophysics ◽  
2009 ◽  
Vol 74 (6) ◽  
pp. G47-G59 ◽  
Author(s):  
Marian Hertrich ◽  
Alan G. Green ◽  
Martina Braun ◽  
Ugur Yaramanci

Conventional surface nuclear magnetic resonance (NMR) surveying based on 1D inversions of data recorded using a common (coincidence) transmitter and receiver loop provides only limited or distorted water-concentration information in regions characterized by strong lateral heterogeneity. We introduce a combined field-acquisition and tomographic-inversion strategy suitable for 2D surface NMR investigations of free (i.e., unbound) water stored in hydrogeologically complex regions. Using combinations of coincident and multioffset loops, we take advantage of the range of sensitivities offered by different loop configurations to variations in subsurface free-water concentration. The new tomographic scheme can invert data acquired with diverse loop configurations. Tests of the combined acquisition and inversion strategy on complicated synthetic and observed data demonstrate the substantially higher resolution information provided by combinations of loop configurations vis-à-vis that supplied by a standard coincident loop. A combination of coincident and half-overlapping loop data sets yields tomograms rich in detail, comparable to tomograms derived from a combination of all considered loop configurations. If resources are limited, surface NMR practitioners should consider the half-overlapping loop configuration as an alternative to the standard coincident loop configuration. For a four-station data recording campaign, the half-overlapping loop configuration with 50% more measurements and equal number of loop deployments and retrievals provides significantly higher resolution tomograms than a coincident loop configuration.

1969 ◽  
Vol 52 (5) ◽  
pp. 1074-1092 ◽  
Author(s):  
L H Keith ◽  
A L Alford ◽  
A W Garrison

Abstract The high resolution nuclear magnetic resonance spectra of the DDT class of pesticides and related compounds are discussed, including a study of the resonances of the aromatic protons as they are affected by various substiluents. The CCl3 moiety on the α-carbon strongly deshields the ortho protons on the aromatic rings, and this deshielding effect is greatly enhanced by substitution of a chlorine ortho rather than para on the aromatic ring. These deshielding effects are explained by a consideration of the electronegativity of the substituents and the stereochemistry of the molecule. The chemical shifts and coupling constants are tabulated.


2021 ◽  
Vol 75 (2-3) ◽  
pp. 119-131
Author(s):  
Albert A. Smith ◽  
Nicolas Bolik-Coulon ◽  
Matthias Ernst ◽  
Beat H. Meier ◽  
Fabien Ferrage

AbstractThe dynamics of molecules in solution is usually quantified by the determination of timescale-specific amplitudes of motions. High-resolution nuclear magnetic resonance (NMR) relaxometry experiments—where the sample is transferred to low fields for longitudinal (T1) relaxation, and back to high field for detection with residue-specific resolution—seeks to increase the ability to distinguish the contributions from motion on timescales slower than a few nanoseconds. However, tumbling of a molecule in solution masks some of these motions. Therefore, we investigate to what extent relaxometry improves timescale resolution, using the “detector” analysis of dynamics. Here, we demonstrate improvements in the characterization of internal dynamics of methyl-bearing side chains by carbon-13 relaxometry in the small protein ubiquitin. We show that relaxometry data leads to better information about nanosecond motions as compared to high-field relaxation data only. Our calculations show that gains from relaxometry are greater with increasing correlation time of rotational diffusion.


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