Estimating seismic velocities at ultrasonic frequencies in partially saturated rocks

Geophysics ◽  
1994 ◽  
Vol 59 (2) ◽  
pp. 252-258 ◽  
Author(s):  
Gary Mavko ◽  
Richard Nolen‐Hoeksema

Seismic velocities in rocks at ultrasonic frequencies depend not only on the degree of saturation but also on the distribution of the fluid phase at various scales within the pore space. Two scales of saturation heterogeneity are important: (1) saturation differences between thin compliant pores and larger stiffer pores, and (2) differences between saturated patches and undersaturated patches at a scale much larger than any pore. We propose a formalism for predicting the range of velocities in partially saturated rocks that avoids assuming idealized pore shapes by using measured dry rock velocity versus pressure and dry rock porosity versus pressure. The pressure dependence contains all of the necessary information about the distribution of pore compliances for estimating effects of saturation at the finest scales where small amounts of fluid in the thinnest, most compliant parts of the pore space stiffen the rock in both compression and shear (increasing both P‐ and S‐wave velocities) in approximately the same way that confining pressure stiffens the rock by closing the compliant pores. Large‐scale saturation patches tend to increase only the high‐frequency bulk modulus by amounts roughly proportional to the saturation. The pore‐scale effects will be most important at laboratory and logging frequencies when pore‐scale pore pressure gradients are unrelaxed. The patchy‐saturation effects can persist even at seismic field frequencies if the patch sizes are sufficiently large and the diffusivities are sufficiently low for the larger‐scale pressure gradients to be unrelaxed.

2021 ◽  
Author(s):  
Marco Dentz ◽  
Alexandre Puyguiraud ◽  
Philippe Gouze

<p>Transport of dissolved substances through porous media is determined by the complexity of the pore space and diffusive mass transfer within and between pores. The interplay of diffusive pore-scale mixing and spatial flow variability are key for the understanding of transport and reaction phenomena in porous media. We study the interplay of pore-scale mixing and network-scale advection through heterogeneous porous media, and its role for the evolution and asymptotic behavior of hydrodynamic dispersion. In a Lagrangian framework, we identify three fundamental mechanisms of pore-scale mixing that determine large scale particle motion: (i) The smoothing of intra-pore velocity contrasts, (ii) the increase of the tortuosity of particle paths, and (iii) the setting of a maximum time for particle transitions. Based on these mechanisms, we derive an upscaled approach that predicts anomalous and normal hydrodynamic dispersion based on the characteristic pore length, Eulerian velocity distribution and Péclet number. The theoretical developments are supported and validated by direct numerical flow and transport simulations in a three-dimensional digitized Berea sandstone sample obtained using X-Ray microtomography. Solute breakthrough curves, are characterized by an intermediate power-law behavior and exponential cut-off, which reflect pore-scale velocity variability and intra-pore solute mixing. Similarly, dispersion evolves from molecular diffusion at early times to asymptotic hydrodynamics dispersion via an intermediate superdiffusive regime. The theory captures the full evolution form anomalous to normal transport behavior at different Péclet numbers as well as the Péclet-dependence of asymptotic dispersion. It sheds light on hydrodynamic dispersion behaviors as a consequence of the interaction between pore-scale mixing and Eulerian flow variability. </p>


Geophysics ◽  
1986 ◽  
Vol 51 (1) ◽  
pp. 183-189 ◽  
Author(s):  
Kenneth W. Winkler

It is generally accepted that acoustic velocities in fluid‐saturated rocks vary with frequency. Evidence comes from experimental measurements and from theoretical causality arguments. We have developed a simple analysis technique that gives estimates of total velocity dispersion between zero frequency and any measurement frequency. The technique requires compressional (P) and shear (S) wave velocity measurements on dry and fully saturated rock. Assuming that the dry velocities are independent of frequency, the Biot‐Gassmann equations are used to calculate the zero‐frequency velocities in the fully saturated rock. Any difference between the measured velocities and the calculated zero‐frequency velocities is interpreted as evidence of dispersion. Application of this analysis technique to a variety c ultrasonic data sets gives consistent results. In many rocks, dispersion between zero frequency and ultrasonic frequencies is on the order of 10 percent at low effective stress, and it decreases to only a few percent at higher stresses. Dispersion varies with degree of saturation and with fluid viscosity in the same way as do low‐frequency attenuation measurements. The results are readily interpreted in terms of the same local‐flow absorption/dispersion mechanism that has been used to explain recent laboratory attenuation measurements. This apparent dispersion places upper bounds on seismic‐to‐sonic velocity differences. It also points out possible discrepancies between seismic velocities and ultrasonic laboratory measurements.


Geophysics ◽  
2006 ◽  
Vol 71 (3) ◽  
pp. N21-N32 ◽  
Author(s):  
Matthias Zillmer

The occurrence of gas hydrate or free gas in a porous medium changes the medium’s elastic properties. Explicit formulas for gas-hydrate or free-gas saturation of pore space on the basis of the Frenkel-Gassmann equations describe the elastic moduli and seismic velocities of a porous medium for low frequencies. A key assumption of the model is that either gas hydrate or free gas is present in the pore space in addition to water. Under this assumption, the method uses measured P- and S-wave velocities and bulk density along with estimates of the moduli and densities of the solid and fluid phases present to determine whether gas or hydrate is present. The method then determines the saturation level of either the gas or the hydrate. I apply the method to published velocity and density data from seismic studies at the antarctic Shetland margin and at the Storegga slide, offshore Norway, and to borehole log and core data from Ocean Drilling Program (ODP) Leg 164 at Blake Ridge, offshore South Carolina. A sensitivity analysis reveals that the standard deviations of the gas-hydrate and free-gas saturations reach 30%–70% of the saturations if the standard deviations of the P- and S-wave velocities and of the bulk density are [Formula: see text] and [Formula: see text], respectively. I conclude that a reliable quantification of gas hydrate and free gas can be achieved by seismic methods only if the seismic velocities and bulk density of the medium are determined with high accuracy from the measured data.


2021 ◽  
Author(s):  
Anna J. P. Gülcher ◽  
Maxim D. Ballmer ◽  
Paul J. Tackley

<p>The nature of compositional heterogeneity in Earth’s lower mantle is a long-standing puzzle that can inform about the thermochemical evolution and dynamics of our planet. On relatively small scales (<1km), streaks of recycled oceanic crust (ROC) and lithosphere are distributed and stirred throughout the mantle, creating a “marble cake” mantle. On larger scales (10s-100s of km), compositional heterogeneity may be preserved by delayed mixing of this marble cake with either intrinsically-dense or -strong materials of e.g. primordial origin. Intrinsically-dense materials may accumulate as piles at the core-mantle boundary, while intrinsically viscous (e.g., enhanced in the strong mineral MgSiO<sub>3 </sub>bridgmanite) may survive as blobs in the mid-mantle for large timescales (i.e., as plums in the mantle “plum pudding”). So far, only few, if any, studies have quantified mantle dynamics in the presence of different types of heterogeneity with distinct physical properties.<br><br>Here, we use 2D numerical models of global-scale mantle convection to investigate the coupled evolution and mixing of (intrinsically-dense) recycled and (intrinsically-strong) primordial material. We explore the effects of ancient compositional layering of the mantle, as motivated by magma-ocean solidification studies, and the physical parameters of the primordial material. Over a wide parameter range, primordial and recycled heterogeneity is predicted to coexist with each other. Primordial material usually survives as mid-to-large scale blobs in the mid-mantle, and this preservation is largely independent on the initial primordial-material volume. In turn, recycled oceanic crust (ROC) persists as piles at the base of the mantle and as small streaks everywhere else. The robust coexistence between recycled and primordial materials in the models indicate that the modern mantle may be in a hybrid state between the “marble cake” and “plum pudding” styles.<br><br>Finally, we put our model predictions in context with geochemical studies on early Earth dynamics as well as seismic discoveries of present-day lower-mantle heterogeneity. For the latter, we calculate synthetic seismic velocities from output model fields, and compare these synthetics to tomography models, taking into account the limited resolution of seismic tomography. Because of the competing effects of compositional and thermal anomalies on S-wave velocities, it is difficult to identify mid-mantle bridgmanitic domains in seismic tomography images. This result suggests that, if present, bridgmanitic domains in the mid-mantle may be “hidden” from seismic tomographic studies, and other approaches are needed to establish the presence/absence of these domains in the present-day deep Earth.</p>


Geophysics ◽  
1994 ◽  
Vol 59 (7) ◽  
pp. 1100-1109 ◽  
Author(s):  
Grant A. Gist

It is an old problem in rock physics that the saturation dependence of high‐frequency laboratory velocities does not match the Biot‐Gassmann theory commonly used to predict the effects of gas on seismic velocities. A new interpretation of laboratory velocity data shows that the saturation dependence is controlled by two previously published high‐frequency acoustic mechanisms: (1) a gas pocket model that describes pressure equilibration between liquid and gas‐saturated regions of the pore space, and (2) local fluid flow, induced by pressure equilibration in pores with different aspect ratios. When these two mechanisms are added to Biot theory, the result describes published velocity versus gas saturation data for a wide range of rock types. These two mechanisms are negligible at the lower frequencies of seismic data, so the saturation dependence of laboratory velocities cannot be used to predict the saturation dependence at seismic frequencies. The one laboratory measurement that is relevant for predicting the seismic velocity is the ultrasonic velocity of the dry rock. The dry‐rock velocities should be used in the Biot‐Gassmann theory to predict the full saturation dependence of the seismic velocities.


Metabolomics ◽  
2021 ◽  
Vol 17 (2) ◽  
Author(s):  
Tiina Jääskeläinen ◽  
◽  
Olli Kärkkäinen ◽  
Jenna Jokkala ◽  
Anton Klåvus ◽  
...  

Abstract Introduction Maternal metabolism changes substantially during pregnancy. However, few studies have used metabolomics technologies to characterize changes across gestation. Objectives and methods We applied liquid chromatography–mass spectrometry (LC–MS) based non-targeted metabolomics to determine whether the metabolic profile of serum differs throughout the pregnancy between pre-eclamptic and healthy women in the FINNPEC (Finnish Genetics of Preeclampsia Consortium) Study. Serum samples were available from early and late pregnancy. Results Progression of pregnancy had large-scale effects to the serum metabolite profile. Altogether 50 identified metabolites increased and 49 metabolites decreased when samples of early pregnancy were compared to samples of late pregnancy. The metabolic signatures of pregnancy were largely shared in pre-eclamptic and healthy women, only urea, monoacylglyceride 18:1 and glycerophosphocholine were identified to be increased in the pre-eclamptic women when compared to healthy controls. Conclusions Our study highlights the need of large-scale longitudinal metabolomic studies in non-complicated pregnancies before more detailed understanding of metabolism in adverse outcomes could be provided. Our findings are one of the first steps for a broader metabolic understanding of the physiological changes caused by pregnancy per se.


Author(s):  
K. R. Daly ◽  
T. Roose

In this paper, we use homogenization to derive a set of macro-scale poro-elastic equations for soils composed of rigid solid particles, air-filled pore space and a poro-elastic mixed phase. We consider the derivation in the limit of large deformation and show that by solving representative problems on the micro-scale we can parametrize the macro-scale equations. To validate the homogenization procedure, we compare the predictions of the homogenized equations with those of the full equations for a range of different geometries and material properties. We show that the results differ by ≲ 2 % for all cases considered. The success of the homogenization scheme means that it can be used to determine the macro-scale poro-elastic properties of soils from the underlying structure. Hence, it will prove a valuable tool in both characterization and optimization.


2021 ◽  
Vol 9 (6) ◽  
pp. 1110
Author(s):  
Ángel Córcoles García ◽  
Peter Hauptmann ◽  
Peter Neubauer

Insufficient mixing in large-scale bioreactors provokes gradient zones of substrate, dissolved oxygen (DO), pH, and other parameters. E. coli responds to a high glucose, low oxygen feeding zone with the accumulation of mixed acid fermentation products, especially formate, but also with the synthesis of non-canonical amino acids, such as norvaline, norleucine and β-methylnorleucine. These amino acids can be mis-incorporated into recombinant products, which causes a problem for pharmaceutical production whose solution is not trivial. While these effects can also be observed in scale down bioreactor systems, these are challenging to operate. Especially the high-throughput screening of clone libraries is not easy, as fed-batch cultivations would need to be controlled via repeated glucose pulses with simultaneous oxygen limitation, as has been demonstrated in well controlled robotic systems. Here we show that not only glucose pulses in combination with oxygen limitation can provoke the synthesis of these non-canonical branched-chain amino acids (ncBCAA), but also that pyruvate pulses produce the same effect. Therefore, we combined the enzyme-based glucose delivery method Enbase® in a PALL24 mini-bioreactor system and combined repeated pyruvate pulses with simultaneous reduction of the aeration rate. These cultivation conditions produced an increase in the non-canonical branched chain amino acids norvaline and norleucine in both the intracellular soluble protein and inclusion body fractions with mini-proinsulin as an example product, and this effect was verified in a 15 L stirred tank bioreactor (STR). To our opinion this cultivation strategy is easy to apply for the screening of strain libraries under standard laboratory conditions if no complex robotic and well controlled parallel cultivation devices are available.


Geophysics ◽  
1994 ◽  
Vol 59 (1) ◽  
pp. 87-92 ◽  
Author(s):  
Gary Mavko ◽  
Diane Jizba

Seismic velocity dispersionin fluid-saturated rocks appears to be dominated by tow mecahnisms: the large scale mechanism modeled by Biot, and the local flow or squirt mecahnism. The tow mechanisms can be distuinguished by the ratio of P-to S-wave dispersions, or more conbeniently, by the ratio of dynamic bulk to shear compliance dispersions derived from the wave velocities. Our formulation suggests that when local flow denominates, the dispersion of the shear compliance will be approximately 4/15 the dispersion of the compressibility. When the Biot mechanism dominates, the constant of proportionality is much smaller. Our examination of ultrasonic velocities from 40 sandstones and granites shows that most, but not all, of the samples were dominated by local flow dispersion, particularly at effective pressures below 40 MPa.


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