Anisotropic effective‐medium modeling of the elastic properties of shales

Geophysics ◽  
1994 ◽  
Vol 59 (10) ◽  
pp. 1570-1583 ◽  
Author(s):  
Brian E. Hornby ◽  
Larry M. Schwartz ◽  
John A. Hudson

Shales are complex porous materials, normally consisting of percolating and interpenetrating fluid and solid phases. The solid phase is generally comprised of several mineral components and forms an intricate and anisotropic microstructure. The shape, orientation, and connection of the two phases control the anisotropic elastic properties of the composite solid. We develop a theoretical framework that allows us to predict the effective elastic properties of shales. Its usefulness is demonstrated with numerical modeling and by comparison with established ultrasonic laboratory experiments. The theory is based on a combination of anisotropic formulations of the self‐consistent (SCA) and differential effective‐medium (DEM) approximations. This combination guarantees that both the fluid and solid phases percolate at all porosities. Our modeling of the elastic properties of shales proceeds in four steps. First, we consider the case of an aligned biconnected clay‐fluid composite composed of ellipsoidal inclusions. Anisotropic elastic constants are estimated for a clay‐fluid composite as a function of the fluid‐filled porosity and the aspect ratio of the inclusions. Second, a new processing technique is developed to estimate the distribution of clay platelet orientations from digitized scanning electron microphotographs (SEM). Third, the derived clay platelet distribution is employed to estimate the effective elastic parameters of a solid comprising clay‐fluid composites oriented at different angles. Finally, silt minerals are included in the calculations as isolated spherical inclusions.

2007 ◽  
Vol 129 (11) ◽  
pp. 1415-1421 ◽  
Author(s):  
Joseph Borowsky ◽  
Timothy Wei

An experimental investigation of a two-phase pipe flow was undertaken to study kinematic and dynamic parameters of the fluid and solid phases. To accomplish this, a two-color digital particle image velocimetry and accelerometry (DPIV∕DPIA) methodology was used to measure velocity and acceleration fields of the fluid phase and solid phase simultaneously. The simultaneous, two-color DPIV∕DPIA measurements provided information on the changing characteristics of two-phase flow kinematic and dynamic quantities. Analysis of kinematic terms indicated that turbulence was suppressed due to the presence of the solid phase. Dynamic considerations focused on the second and third central moments of temporal acceleration for both phases. For the condition studied, the distribution across the tube of the second central moment of acceleration indicated a higher value for the solid phase than the fluid phase; both phases had increased values near the wall. The third central moment statistic of acceleration showed a variation between the two phases with the fluid phase having an oscillatory-type profile across the tube and the solid phase having a fairly flat profile. The differences in second and third central moment profiles between the two phases are attributed to the inertia of each particle type and its response to turbulence structures. Analysis of acceleration statistics provides another approach to characterize flow fields and gives some insight into the flow structures, even for steady flows.


2021 ◽  
pp. 2150469
Author(s):  
T. G. Naghiyev ◽  
R. M. Rzayev

The solid solutions of [Formula: see text] were synthesized by solid-phase reactions from powder components of CaS, BaS, and Ga2S3. The temperature-concentration dependences of the Gibbs free energy of formation of [Formula: see text] solid solutions from ternary compounds and phase diagrams of the CaGa2S4–BaGa2S4 were determined by a calculation method. It was revealed that continuous solid solutions are formed in these systems. The spinodal decomposition of [Formula: see text] solid solutions into two phases is predicted at ordinary temperatures.


2016 ◽  
Vol 125 ◽  
pp. 85-100 ◽  
Author(s):  
Praveen K. Srivastava ◽  
Chaman Chandel ◽  
Puneet Mahajan ◽  
Pankaj Pankaj

Carbon ◽  
2019 ◽  
Vol 144 ◽  
pp. 109-115 ◽  
Author(s):  
Zhiyong Wei ◽  
Fan Yang ◽  
Kedong Bi ◽  
Juekuan Yang ◽  
Yunfei Chen

2014 ◽  
Vol 69 (4) ◽  
Author(s):  
Norfahana Abd-Talib ◽  
Siti Hamidah Mohd-Setapar ◽  
Aidee Kamal Khamis

Over recent years, there has been an explosive growth of sample preparation techniques. Sample preparation is in most cases meant to be the isolation online or offline concentration of some components of interest or target analytes. Solid phase extraction (SPE) is a very popular technique nowadays in sample preparation. The principal is quite similar with liquid- liquid extraction (LLE) which involves partition of solutes between two phases. But, there are some differences between them and some benefits and limitations of difference types of SPE technique like presented in this paper.


Materials ◽  
2022 ◽  
Vol 15 (2) ◽  
pp. 638
Author(s):  
Ofer Tevet ◽  
David Svetlizky ◽  
David Harel ◽  
Zahava Barkay ◽  
Dolev Geva ◽  
...  

Additively manufactured (AM) materials and hot rolled materials are typically orthotropic, and exhibit anisotropic elastic properties. This paper elucidates the anisotropic elastic properties (Young’s modulus, shear modulus, and Poisson’s ratio) of Ti6Al4V alloy in four different conditions: three AM (by selective laser melting, SLM, electron beam melting, EBM, and directed energy deposition, DED, processes) and one wrought alloy (for comparison). A specially designed polygon sample allowed measurement of 12 sound wave velocities (SWVs), employing the dynamic pulse-echo ultrasonic technique. In conjunction with the measured density values, these SWVs enabled deriving of the tensor of elastic constants (Cij) and the three-dimensional (3D) Young’s moduli maps. Electron backscatter diffraction (EBSD) and micro-computed tomography (μCT) were employed to characterize the grain size and orientation as well as porosity and other defects which could explain the difference in the measured elastic constants of the four materials. All three types of AM materials showed only minor anisotropy. The wrought (hot rolled) alloy exhibited the highest density, virtually pore-free μCT images, and the highest ultrasonic anisotropy and polarity behavior. EBSD analysis revealed that a thin β-phase layer that formed along the elongated grain boundaries caused the ultrasonic polarity behavior. The finding that the elastic properties depend on the manufacturing process and on the angle relative to either the rolling direction or the AM build direction should be taken into account in the design of products. The data reported herein is valuable for materials selection and finite element analyses in mechanical design. The pulse-echo measurement procedure employed in this study may be further adapted and used for quality control of AM materials and parts.


2010 ◽  
Vol 43 (10) ◽  
pp. 1857-1863 ◽  
Author(s):  
V. Sansalone ◽  
S. Naili ◽  
V. Bousson ◽  
C. Bergot ◽  
F. Peyrin ◽  
...  

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