Sulfide partial melting and galena–tetrahedrite intergrowth texture: An experimental study

2020 ◽  
pp. 1-10
Author(s):  
Boddepalli Govindarao ◽  
Kamal Lochan Pruseth ◽  
Biswajit Mishra

Abstract Galena–tetrahedrite intergrowth textures have been observed in some quenched run products of melting experiments conducted at 500 and 600°C in the systems ZnS–PbS–FeS–Cu2S–Sb2S3 and ZnS–PbS–FeS–Cu2S–Sb2S3–As2S3, using the evacuated silica-tube method. At 600°C the intergrowth formed an interface between sulfide melt and galena, whereas at 500°C it existed as inclusions partially embedded or completely embedded within tetrahedrite. At 600°C tetrahedrite was absent in PbS-bearing experiments, instead galena and melt were a part of the equilibrium phase assemblage. From the disposition of the galena–tetrahedrite intergrowths at 500°C it is evident that droplets of galena–tetrahedrite melt coexisted with tetrahedrite or tetrahedrite + galena and gave rise to these intergrowths upon quenching. The intergrowths coexisting with galena probably represent compositions on the galena-rich liquidus in the galena–tetrahedrite binary and those coexisting with tetrahedrite represent points on the tetrahedrite-rich liquidus. A eutectic at galena:tetrahedrite = ~30:70, very close to 500°C is apparent. It is clearly indicated that galena–tetrahedrite intergrowths can be formed by sulfide partial melting, and could be used as a potential indicator of partial melting in metamorphosed sulfide ore deposits.

2004 ◽  
Vol 51 (5) ◽  
pp. 499
Author(s):  
Soo Mee Lim ◽  
Hye Young Choi ◽  
Yoo Kyung Kim ◽  
Do Yeon Kim ◽  
Min Sun Lee

1986 ◽  
Vol 108 (3) ◽  
pp. 649-653 ◽  
Author(s):  
E. M. Sparrow ◽  
G. A. Gurtcheff ◽  
T. A. Myrum

Melting experiments were performed encompassing both pure and impure substances. The pure substances included n-octadecane paraffin and n-eicosane paraffin, while the impure substances were mixtures synthesized from the pure paraffins. The experiments were carried out in a closed vertical tube whose wall was subjected to a step-change increase in temperature to initiate the melting. For each impure substance, supplementary measurements were made of two characteristic temperatures: the temperature T** at which melting of the solid phase first begins and the lowest temperature T* at which the melting can go to completion. For a pure substance, T** = T*. The time-dependent melting results for all the investigated substances, both pure and impure, were well correlated as a function of FoSte**(Gr**)1/8 alone, where the ** signifies the presence of T** in the temperature difference which appears in Ste and Gr. This correlation enables melting rates for impure substances to be determined from melting rates for pure substances. The T** values needed for the implementation of the correlation can be obtained from simple experiments, obviating the need for the complete equilibrium phase diagram.


1993 ◽  
Vol 8 (9) ◽  
pp. 2187-2190 ◽  
Author(s):  
Y.C. Guo ◽  
H.K. Liu ◽  
S.X. Dou

Silver doping into (Bi, Pb)2Sr2Ca2Cu3O10 superconducting composite tapes was found to accelerate the formation process of high-Tc (2223) phase owing to lowering the partial melting point of the samples. The differential thermal analysis (DTA) results showed that the partial melting temperature of the sample was lowered by about 10 °C from 850 °C to 840 °C by silver doping. However, with sufficient sintering both the silver-doped and undoped samples can reach a very high level of high-Tc phase fraction, suggesting that the silver doping only speeds up the rate of high-Tc phase formation, but does not change the final phase assemblage of the materials. The reaction kinetics was analyzed by using the Avrami equation, and the results indicated that the conversion process of low-Tc (2212) phase to high-Tc (2223) phase was a diffusion-controlled, two-dimensional reaction. The correlation of the phase evolution with electrical property inside the superconducting tape during the process of heat treatment was also discussed.


Geology ◽  
2018 ◽  
Vol 46 (4) ◽  
pp. 343-346 ◽  
Author(s):  
Alicia M. Cruz-Uribe ◽  
Horst R. Marschall ◽  
Glenn A. Gaetani ◽  
Véronique Le Roux

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