Coronitic reactions: Constraints to element diffusion during UHP metamorphism

2015 ◽  
pp. 261-306
Author(s):  
Marco Rubbo ◽  
Marco Bruno
2014 ◽  
Vol 56 (4) ◽  
pp. 318-324
Author(s):  
Mehmet Uzkut ◽  
Bekir Sadık Ünlü ◽  
Mesut Yavuz ◽  
Mustafa Akdag
Keyword(s):  

2012 ◽  
Vol 48 (11) ◽  
pp. 1306 ◽  
Author(s):  
Xu ZHANG ◽  
Yumin WANG ◽  
Jiafeng LEI ◽  
Rui YANG

Author(s):  
E. Blereau ◽  
C. Clark ◽  
P. D. Kinny ◽  
E. Sansom ◽  
R. J. M. Taylor ◽  
...  

2008 ◽  
Vol 62 (2) ◽  
pp. 262-265 ◽  
Author(s):  
Weizhong Jiang ◽  
Ying Wang ◽  
Lixia Gu

2017 ◽  
Vol 476 (2) ◽  
pp. 1222-1225 ◽  
Author(s):  
A. Yu. Selyatitskii ◽  
K. V. Kulikova

Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1796 ◽  
Author(s):  
Hai Kuang ◽  
Dunqiang Tan ◽  
Wen He ◽  
Zhiqiang Yi ◽  
Zhihang Zou ◽  
...  

The coating is one of the biggest problems in the recycling of coated multicomponent hardmetal scraps. The isothermal oxidation behavior of WC-Co multicomponent cemented carbide inserts with a TiCN/Al2O3/TiN hard coating in the recycling process was investigated. The oxidation rate slowed down as the protective coating blocked element diffusion. A rapid oxidation rate was obtained when they were milled into powders and isothermally oxidized at 900 °C. A rapid path for element diffusion was provided by the defects, which were promoted by stress, expansion, and gas volatilization. Both the TiN and TiCN layers were oxidized to a porous TiO2 scale, while the Al2O3 phase remained and the dense Al2O3 layer acted as a barrier for its good oxidation resistance. Pieces of the Al2O3 layer were obviously seen in the final oxides. This provides critical information to reduce the negative effect of coatings and improve the performance of recycled WC powders and hard alloys.


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