Mineralogical and crystal-chemical characterization of the talc ore deposit of Minzanzala, Gabon

Clay Minerals ◽  
2019 ◽  
Vol 54 (3) ◽  
pp. 245-254
Author(s):  
Mathilde Poirier ◽  
Jean-Eudes Boulingui ◽  
François Martin ◽  
Michel Mbina Mounguengui ◽  
Charles Nkoumbou ◽  
...  

AbstractThis research aims to characterize the mineralogical and crystal-chemical purity of two samples of natural talc (BTT6, BTT7) from the occurrence ‘Ecole1’ in the deposit of Minzanzala, southwest Gabon. X-ray diffraction and modal-composition calculations demonstrated the presence of quartz and Al–Fe-bearing phases (kaolinite and/or chlorite and/or Al–Fe oxyhydroxides) as accessory minerals in both ores. In contrast, the chemical and spectroscopic characterization of the talc component revealed remarkable chemical purity expressed by very low Fe contents. According to these results, the talc of Minzanzala might be used as a filler in a wide range of industrial applications, such as in cosmetics, paints, polymers or ceramics.

Minerals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 388
Author(s):  
Teresa Pi-Puig ◽  
Dante Yosafat Animas-Torices ◽  
Jesús Solé

The detailed mineralogical, physical and chemical characterization of nine samples of imported cosmetic talc and of two samples of talc from currently non-productive Mexican ore deposits (Oaxaca and Puebla States) is presented. The imported cosmetic talc was classified into two groups, considering whether they are packed in the country of origin or in Mexico and considering their price. X-ray diffraction, infrared short wave, thermogravimetric analysis and scanning electron microscopy were used for mineralogical characterization. For the physical characterization, colorimetry and laser granulometry were used. The chemical composition (major, trace elements) was studied by ICP-MS. It was concluded that only the highest priced and imported in packaged form talcs meet the specific purity requirements for a talc of cosmetic type. The talcs that are packed in Mexico and the talc of the studied Mexican deposits present mineralogical and chemical impurities that make their use difficult in the manufacture of high-quality cosmetic talc. The low-price talc should not be sold as cosmetic talc, and the regulations in Mexico on this subject should be reviewed and updated.


2019 ◽  
Vol 9 (2) ◽  
pp. 3915-3917
Author(s):  
S. Akhtar ◽  
Z. Farid ◽  
H. Ahmed ◽  
S. A. Khan ◽  
Z. N. Khan

Silver (Ag) nanoparticles (NPs) are synthesized and characterized by a low-cost chemical reduction method. Silver nanoparticles (Ag NPs) have pre-occupied the consideration of the scientific community due to their wide range of functions, utility and industrial applications, particularly in the fields of sensing technologies and medicine (particularly their efficiency against microbes, the ability of healing the wound and anti-inflammatory properties). Ag NPs are synthesized by a low-cost fabrication method. X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray diffraction (EDX) and photometry techniques are used in this work to identify their nature and potentiality for diverse applications in sensing technologies.


Clay Minerals ◽  
2015 ◽  
Vol 50 (5) ◽  
pp. 607-617 ◽  
Author(s):  
Angela Dumas ◽  
François Martin ◽  
The Ngo Ke ◽  
Hanh Nguyen Van ◽  
Dung Nguyen Viet ◽  
...  

AbstractThe mineralogy and crystal chemistry of a new talc ore deposit situated at Thu Ngac commune, Thanh Son district, Phu Tho province, Vietnam, was investigated using X-ray fluorescence, electron microprobe, X-ray diffraction, Fourier transform infrared spectroscopy, solid-state nuclear magnetic resonance (29Si and1H) and colorimetry.Both chemical and crystal-chemical analyses showed that the talcs from the Phu Tho province are very pure because they contain few accessory minerals (chlorite, amphibole and goethite) and few substitutions of Si by Fe and Al in their crystal structure. The talc ore may well meet the standards required for a wide range of industrial applications.


Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2160
Author(s):  
Alexander Bogdanov ◽  
Ekaterina Kaneva ◽  
Roman Shendrik

Elpidite belongs to a special group of microporous zirconosilicates, which are of great interest due to their capability to uptake various molecules and ions, e.g., some radioactive species, in their structural voids. The results of a combined electron probe microanalysis and single-crystal X-ray diffraction study of the crystals of elpidite from Burpala (Russia) and Khan-Bogdo (Mongolia) deposits are reported. Some differences in the chemical compositions are observed and substitution at several structural positions within the structure of the compounds are noted. Based on the obtained results, a detailed crystal–chemical characterization of the elpidites under study was carried out. Three different structure models of elpidite were simulated: Na2ZrSi6O15·3H2O (related to the structure of Russian elpidite), partly Ca-replaced Na1.5Ca0.25ZrSi6O15·2.75H2O (close to elpidite from Mongolia), and a hypothetical CaZrSi6O15·2H2O. The vibration spectra of the models were obtained and compared with the experimental one, taken from the literature. The strong influence of water molecule vibrations on the shape of IR spectra of studied structural models of elpidite is discussed in the paper.


2014 ◽  
Vol 805 ◽  
pp. 343-349
Author(s):  
Carine F. Machado ◽  
Weber G. Moravia

This work evaluated the influence of additions of the ceramic shell residue (CSR), from the industries of Lost Wax Casting, in the modulus of elasticity and porosity of concrete. The CSR was ground and underwent a physical, chemical, and microstructural characterization. It was also analyzed, the environmental risk of the residue. In the physical characterization of the residue were analyzed, the surface area, and particle size distribution. In chemical characterization, the material powder was subjected to testing of X-ray fluorescence (XRF). Microstructural characterization was performed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The residue was utilized like addition by substitution of cement in concrete in the percentages of 10% and 15% by weight of Portland cement. It was evaluated properties of concrete in the fresh and hardened state, such as compressive strength, modulus of elasticity, absorption of water by total immersion and by capillarity. The results showed that the residue can be used in cement matrix and improve some properties of concrete. Thus, the CSR may contribute to improved sustainability and benefit the construction industry.


2007 ◽  
Vol 71 (06) ◽  
pp. 641-650 ◽  
Author(s):  
L. Bindi ◽  
M. Evain ◽  
P. G. Spry ◽  
K. T. Tait ◽  
S. Menchetti

Abstract The pearceite-polybasite group of minerals, general formula [M6T2S7][Ag9CuS4] with M = Ag, Cu; and T = As, Sb, show a crystal structure which can be described as the succession, along the c axis, of two pseudo-layer modules: a [M6T2S7]2– A module layer and a [Ag9CuS4]2+ B module layer. Copper is present in one structural position of the B module layer and replaces Ag in the only fully occupied M position of the A module layer. When the Cu content is >4.00 a.p.f.u., the structural position of the A module layer becomes Cu-dominant and, consequently, the mineral deserves its own name. In this paper we report the crystal-chemical characterization of two Cu-rich members exhibiting the 111 unitcell type (corresponding to the Tac polytype). One sample (space group (P )m1, a 7.3218(8), c 11.8877(13) Å, V 551.90(10) Å3, Z = 1) having As >Sb and with the structural position of the A module layer dominated by Cu, has been named cupropearceite and the other sample (space group (P3̄)m1, a 7.3277(3), c 11.7752(6) Å, V 547.56(8) Å3, Z = 1) having Sb >As has been named cupropolybasite. Both the new minerals and mineral names have been approved by the IMA-CNMNC.


Author(s):  
Nguyen Hong Nam ◽  
Le Gia Thanh Truc ◽  
Khuong Duy Anh ◽  
Laurent Van De Steene

Agricultural and forest residues are potential sources of renewable energy in various countries. However, the difference in characteristics of biomass resources presents challenges for energy conversion processes which often require feedstocks that are physically and chemically consistent. This study presented a complete and comprehensive database of characteristics of a wide range of agricultural and forest residues. Moisture, bulk density, calorific value, proximate and elemental compositions, as well as cellulose, hemicellulose, and lignin compositions of a wide range of biomass residues were analyzed. The major impacts of the variability in biomass compositions to biochemical and thermochemical processes were also discussed.


2015 ◽  
Vol 820 ◽  
pp. 65-70
Author(s):  
I.D.S. Pereira ◽  
V.N.F. Lisboa ◽  
I.A. Silva ◽  
J.M.R. Figueirêdo ◽  
G.A. Neves ◽  
...  

Bentonite exhibt a range of industrial applications moving millions of dollars on the market per year. Among several applications if highlights it is use for petroleum drilling fluids. Thus, this work aims to characterize physical, mineralogical and technologically, the bentonitics clays of Sossego County, Paraíba, Brazil. Mineralogical characterization of clays was done through the following techniques: particle size analysis by laser diffraction, thermogravimetric and differential thermal analysis, chemical analysis and x-ray diffraction. The clays were turned in by treatment with sodium in Na2CO3 and then determined whether the apparent viscosity, plastic and volume of filtrate of clay-water dispersions. The results showed that the samples are of polycationic, showing levels of MgO, CaO and K2O, similar to those from Boa Vista County, Paraíba, Brazil, and consist of clay mineral kaolinite, quartz and esmec. The clays showed rheological properties that indicate potential for use in drilling fluids.


1995 ◽  
Vol 395 ◽  
Author(s):  
S. A. Ustin ◽  
L. Lauhon ◽  
K. A. Brown ◽  
D. Q. Hu ◽  
W. Ho

ABSTRACTHighly oriented aluminum nitride (0001) films have been grown on Si(001) and Si (111) substrates at temperatures between 550° C and 775° C with dual supersonic molecular beam sources. Triethylaluminum (TEA;[(C2H5)3Al]) and ammonia (NH3) were used as precursors. Hydrogen, helium, and nitrogen were used as seeding gases for the precursors, providing a wide range of possible kinetic energies for the supersonic beams due to the disparate masses of the seed gases. Growth rates of AIN were found to depend strongly on the substrate orientation and the kinetic energy of the incident precursor; a significant increase in growth rate is seen when seeding in hydrogen or helium as opposed to nitrogen. Growth rates were 2–3 times greater on Si(001) than on Si(111). Structural characterization of the films was done by reflection high energy electron diffraction (RHEED) and x-ray diffraction (XRD). X-ray rocking curve (XRC) full-width half-maxima (FWHM) were seen as small as 2.5°. Rutherford back scattering (RBS) was used to determine the thickness of the films and their chemical composition. Films were shown to be nitrogen rich, deviating from perfect stoichiometry by 10%–20%. Surface analysis was performed by Auger electron spectroscopy (AES).


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