Ceramic properties of Uşak clay in comparison with Ukrainian clay

Clay Minerals ◽  
2018 ◽  
Vol 53 (4) ◽  
pp. 549-562 ◽  
Author(s):  
Tural Aghayev ◽  
Ceren Küçükuysal
Keyword(s):  
Economic Value ◽  
Slip Casting ◽  
Ceramic Materials ◽  
Linear Shrinkage ◽  
Exchange Capacity ◽  
Raw Material ◽  
Quantitative Chemical Analysis ◽  
Technological Properties ◽  
Mineralogical Characterization ◽  
X Ray

ABSTRACTIn this contribution, a new raw material, Uşak clay (Usc), was investigated in order to assess its potential for the ceramic industry by comparing it with a world reference ceramic material, a Ukrainian clay (Ukc). Mineralogical characterization (X-ray diffraction [XRD], scanning electron microscopy [SEM] and Fourier-transform infrared [FTIR] spectroscopy), quantitative chemical analysis (X-ray fluorescence [XRF]) and the thermal properties of Ukc and Usc samples were investigated. Additionally, Atterberg limits, particle-size distribution and cation exchange capacity of both samples were determined. Various technological properties of Ukc and Usc were determined in the temperature range 800–1430°C. The bending and compressive strengths, total linear shrinkage, colour, water absorption and unit-volume mass values were measured. The findings from these analyses show that kaolinite-dominated Ukc and quartz-dominated Usc samples differ from each other not only mineralogically, but also in terms of their chemical, physical and technological properties. The firing colour of Usc was determined as 84% white, and so this can be considered as a light firing clay. In addition, due to its low plasticity, Usc may be utilized to reduce both the plasticity of the ceramic materials and the viscosity in slip-casting applied ceramics. Furthermore, the melting temperature of 1300°C suggests that Usc cannot be classified as refractory. However, this property does suggest an economic value for Usc in terms of developing technological characteristics at lower firing temperatures.

scholarly journals New Clayey Deposit and Their Potential as Raw Material for Red or Structured Ceramics: Technological Characterization

Materials ◽  
2021 ◽  
Vol 14 (24) ◽  
pp. 7672
Author(s):  
Ana Rosa S. Assunção ◽  
Gricirene Sousa Correia ◽  
Nazaré do Socorro L. S. Vasconcelos ◽  
Aluísio Alves Cabral ◽  
Rômulo Simões Angélica ◽  
...  
Keyword(s):  
Raw Materials ◽  
Linear Shrinkage ◽  
Exchange Capacity ◽  
Raw Material ◽  
Northeastern Brazil ◽  
Atterberg Limits ◽  
Plastic Behavior ◽  
X Ray ◽  
Dta And Tg ◽  
Ceramics Industry

Mineralogical and technological characterization of ceramic raw materials from a new deposit located at Caxias city, Maranhão State—Brazil, was accomplished to determine their potential as raw materials for the ceramics industry in northeastern Brazil. The ceramic raw materials were collected from three different locations on the site and characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), differential thermal analysis (DTA), and thermogravimetry (TG). The XRF analysis of the fraction < 2 μm revealed that most samples had SiO2 (35–51 wt%), Al2O3 (19–29 wt%), Fe2O3 (2–21 wt%), MgO (0.7 to 4.5 wt%) and K2O (0.9 to 5 wt%) as components. Quartz, kaolinite, illite, hematite and montmorillonite were the main mineral phases identified. DTA and TG analysis confirmed the mineral identification. The technological potential of the ceramic raw materials was investigated by: cation exchange capacity (CEC), plastic behavior (Atterberg Limits), linear shrinkage at 950 °C (LSF), flexural strength (FS), apparent porosity (AP), water absorption (WA) and bulk density (BD). The main experimental results—WA (9–17%), AP (19–31%), FS (2.0–23 MPa), and the Atterberg limits—indicated that the ceramic raw materials investigated have high potential to be used to develop mass for red or structured ceramics, such as bricks and roof tiles.

scholarly journals Sustainable Ceramic Materials Manufactured from Ceramic Formulations Containing Quartzite and Scheelite Tailings

2020 ◽  
Vol 12 (22) ◽  
pp. 9417
Author(s):  
Jucielle Veras Fernandes ◽  
Danyelle Garcia Guedes ◽  
Fabiana Pereira da Costa ◽  
Alisson Mendes Rodrigues ◽  
Gelmires de Araújo Neves ◽  
...  
Keyword(s):  
Rio Grande ◽  
Ceramic Materials ◽  
Linear Shrinkage ◽  
X Ray Diffraction ◽  
Ceramic Tiles ◽  
X Ray ◽  
Mining Companies ◽  
Ceramic Samples ◽  
Sustainable Materials ◽  
Mineralogical Phases

In this study, we develop ceramic formulations based on quartzite and scheelite tailings collected from mining companies in the northeast of Brazil (Rio Grande do Norte State). New ceramic samples (27 wt% of kaolin, 29 wt% of plastic clay, 11 wt% of quartzite tailing, and 0–8 wt% scheelite tailing) were uniaxially pressed in two steps (20 MPa and 50 Mpa for 20 s); dried at 110 °C for 24 h; and sintered at 1150 °C, 1200 °C, and 1250 °C. The main mineralogical phases (mullite, quartz, calcite, and anorthite) of the sintered samples were identified using X-ray diffraction (XRD). After evaluation of the physical-mechanical properties (water absorption, linear shrinkage, apparent porosity, and flexural strength), it was observed that the incorporation of scheelite tailing by up to 8 wt% did not significantly alter the properties of samples sintered at all temperatures. Our results indicate that the new ceramics formulations developed have strong potentials in manufacturing sustainable materials such as ceramic tiles and porcelain stoneware.

Preliminary evaluation of the physical properties of red ceramic incorporated with solid residue

MRS Advances ◽  
2018 ◽  
Vol 3 (61) ◽  
pp. 3575-3579
Author(s):  
Francine M. Nunes ◽  
Eduarda M. Rangel ◽  
Fernando M. Machado ◽  
Rubens Camaratta ◽  
Letícia P. Cardoso ◽  
...  
Keyword(s):  
Physical Properties ◽  
Linear Shrinkage ◽  
Raw Material ◽  
Preliminary Evaluation ◽  
Solid Residue ◽  
X Ray Diffraction ◽  
Linear Contraction ◽  
X Ray ◽  
Test Pieces ◽  
Renewable Raw Material

AbstractThe food processing industry highlights the daily generation of large amounts of eggshell solid residue. In this way, this residue becomes a non renewable raw material to be reused as an additive in red ceramics, in order to reduce the volume of disposal to the environment and improve the physical properties of the product. The objective of this work was to evaluate the forming moisture, linear shrinkage of drying and shrinkage of drying burning of ceramic test pieces (CS’s) with formulations with 2% and 3% of white eggshell residue (ER) incorporated in clay. The clay and ER were collected in the city of Pelotas-RS. The ER sample was analyzed by X-Ray Fluorescence (XRF) and X-Ray Diffraction (XRD). After pressing, natural and artificial drying was carried out and the CS’s were burned. These were evaluated through normative parameters C-020/95, C-021/95 and C-026/95. The values obtained for the forming moisture were between 5.82 and 8.78%, for the linear shrinkage of drying between 0.10 and 0.43% and, for the linear contraction burning between -0.29 and 0.08%. The results showed that the addition of ER to the ceramic mass helped in the reduction of the forming moisture and the linear shrinkage of the ceramic test pieces.

Structure Control of Hydroxyapatite Using a Magnetic Field

2007 ◽  
Vol 561-565 ◽  
pp. 1565-1568 ◽  
Author(s):  
Kazuhiko Iwai ◽  
Jun Akiyama ◽  
Shigeo Asai
Keyword(s):  
Magnetic Field ◽  
High Magnetic Field ◽  
Slip Casting ◽  
Casting Process ◽  
Ceramic Materials ◽  
X Ray Diffraction ◽  
X Ray ◽  
Structure Control ◽  
Crystal Alignment ◽  
The Magnetic Field

A high magnetic field is a useful tool to control the crystal alignment of ceramic materials. In this study, a horizontal 10T static magnetic field was imposed on slurry containing hydroxyapatite (HAp) crystals under the horizontal mold rotation during slip casting process so as to introduce uni-axial alignment for some amount of crystals in the sample, and then it was sintered in atmosphere without the magnetic field. From X-ray diffraction, it has been found that the HAp crystals in the sample treated with the mold rotation under the magnetic field were aligned its c-axis to a particular direction.

Fabrication and Sinter-Ability of Ce3+-Doped YAG Ceramics by Low-Temperature Combustion Method

2011 ◽  
Vol 299-300 ◽  
pp. 493-497
Author(s):  
Zhi Qiang Wang ◽  
Xin Sun ◽  
Xiao Li Zhou
Keyword(s):  
Low Temperature ◽  
Sintering Temperature ◽  
Combustion Method ◽  
Linear Shrinkage ◽  
Raw Material ◽  
Low Temperature Combustion ◽  
Photoluminescence Properties ◽  
X Ray ◽  
Sintering Additive ◽  
Temperature Combustion

The phosphors YAG doped with Ce3+was prepared by low-temperature combustion method. Utilizing the prepared YAG powders as raw material and Li2O-CaO-ZnO-Y2O3-Al2O3-SiO2glass powder as sintering additive, YAG:Ce3+ceramics were sintered at 1400-1550°C for 10h in vacuum. Thesinter-ability of the YAG ceramics was studied by measuring the linear shrinkage rate. The phase, microstructure and photoluminescence properties of the YAG: Ce3+powders and ceramics were investigated by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and photoluminescence (PL) analysis. The results show that the sinter-ability properties of YAG:Ce3+ceramics was mainly associated with sintering temperature and contents of glass sintering additive; the best result was achieved when the sample was sintered at 1500°C and doped sintering additive of 1%.

Physico-Mineralogical Characterization: Bentonitic Clays Recently Found in Olivedos, Paraíba, Brazil

2015 ◽  
Vol 820 ◽  
pp. 56-59
Author(s):  
F.K.A. Sousa ◽  
I.A. Silva ◽  
W.S. Cavalcanti ◽  
Gelmires Araújo Neves ◽  
Heber Carlos Ferreira
Keyword(s):  
Cation Exchange Capacity ◽  
Petroleum Industry ◽  
Specific Area ◽  
Exchange Capacity ◽  
X Ray Diffraction ◽  
Mineralogical Characterization ◽  
X Ray ◽  
Petroleum Wells ◽  
The Town

Used in various branches of the industry, bentonitic clays are considered a valuable mineral, used specially in the petroleum industry for manufacturing of fluids used the drilling of petroleum wells in long depth. Recently, a deposit of this valuable mineral was discovered in the town of Olivedos-PB. There are data that prove that this is a very poor and underdeveloped town. So, this work aims at the physico-mineralogical characterization of clays recently discovered and, this way, verify if they present similar characteristics which allow them to replace the clays from Boa Vista-PB, and if they can be used by the industry, thus bringing social development for that town. The characterization was made by means of the analysis of chemical composition by X-ray fluorescence (EDX), thermogravimetric and thermal differential analyses (TG and DTA), X-ray diffraction (XRD), cation-exchange capacity (CEC) and specific area (SA). The results show that the clays recently discovered in Olivedos-PB are polycationic clays, presenting MgO, CaO and K2O content, and that they are constituted by smectitic clay mineral, by quartz and kaolinite.

scholarly journals Characterization of clays from the State of Paraíba, Brazil for aesthetic and medicinal use

Cerâmica ◽  
2019 ◽  
Vol 65 (373) ◽  
pp. 78-84
Author(s):  
B. M. A. B. Buriti ◽  
J. S. Buriti ◽  
I. A. Silva ◽  
J. M. Cartaxo ◽  
G. A. Neves ◽  
...  
Keyword(s):  
Exchange Capacity ◽  
The State ◽  
Raw Material ◽  
Bacterial Strains ◽  
X Ray Diffraction ◽  
X Ray ◽  
Granulometric Analysis ◽  
Medicinal Use ◽  
Antimicrobial Evaluation ◽  
Clinical Interest

Abstract This study aimed to evaluate the potential of clays from the State of Paraíba to be used for medicinal, therapeutic and aesthetic treatments. The samples were characterized by X-ray diffraction, X-ray fluorescence chemical composition, thermogravimetry, differential thermal analysis, laser diffraction granulometric analysis, cation exchange capacity, and antimicrobial activity. Based on the study, it was concluded that the clays from the State of Paraíba had properties similar to those of commercial clay. The antimicrobial evaluation revealed that the samples showed no activity against the three bacterial strains of clinical interest: Staphylococcus epidermidis ATCC 12 228, Staphylococcus aureus ATCC 25 923, and Escherichia coli ATCC 25 922. Finally, it was concluded that the clays studied have the potential for technological applications in medicinal, therapeutic, and aesthetic treatments, and as raw material for obtaining biomaterials, due to their stability and biological safety.

Influence of Firing Temperature on the Behavior of Clay Ceramics Incorporated with Elephant Grass Ash

2014 ◽  
Vol 798-799 ◽  
pp. 526-531 ◽  
Author(s):  
Aline Marcia Ferreira Dias da Silva ◽  
Rosane Toledo ◽  
Veronica Scarpini Candido ◽  
Sergio Neves Monteiro ◽  
Carlos Maurício Fontes Vieira ◽  
...  
Keyword(s):  
Water Absorption ◽  
Firing Temperature ◽  
Rupture Strength ◽  
Linear Shrinkage ◽  
Standard Test ◽  
Elephant Grass ◽  
Technological Properties ◽  
X Ray Diffraction ◽  
X Ray ◽  
Clay Ceramics

The microstructural and technological properties of clay ceramic incorporated with 10 and 20 wt% of elephant grass ashes were investigated at different firing temperatures of 650, 850 and 1050oC. X-ray diffraction were used to obtain the minerals and phase compositions. The microstructure was analyzed by scanning electron microscopy. The technical properties related to water absorption, linear shrinkage and flexural rupture strength were obtained by standard test. The results showed significant changes in the microstructure and phasic composition with increasing firing temperature. A marked improvement in the water absorption, decreasing to 18% as well as increase in strength, above 5 MPa, was found at 1050°C. However, only a slight contribution might be attributed to the incorporation of elephant grass ash. Nevertheless, its use as a by-product and the associated saving in clay are relevant environmental and economical advantages.

Use of Sludge as Ceramic Materials

2010 ◽  
Vol 660-661 ◽  
pp. 1003-1008
Author(s):  
Leandro C. Morais ◽  
R.S.C. Vianna ◽  
V. Campos ◽  
Leonardo F. Fraceto ◽  
André H. Rosa ◽  
...  
Keyword(s):  
Ceramic Materials ◽  
Underground Water ◽  
Raw Material ◽  
Icp Oes ◽  
Toxic Compounds ◽  
X Ray ◽  
Xrf Scanning ◽  
Dta Curves ◽  
Sludge Ash ◽  
Plasma Emission Spectroscopy

Nowadays, with increase amounts of sludge derived from the treatment of domestic sewage put pressure into research on systems for the adequate use of these materials. The aim of the present work is to study the use of sludge ash, from sintering and calcinated process, as a raw material for the ceramic industry. Using the sewage sludge ashes as ceramic raw material there will be no contamination of soil and underground water. Metals and toxic compounds like Al, Fe, Ba, Cr, Cu, Mn and Zn oxides were analyzed and characterized by X-ray fluorescence (XRF), scanning electron microscopy (SEM) and plasma emission spectroscopy (ICP-OES). The leached material was chemically analyzed where the integration of oxides into the ceramic matrix of sludge ash was observed. Residual decomposition was analyzed by TG, DTG and DTA curves.

Quality Characterization of Iron Dust Exhaust Thermal as Alternative Ceramic Coating Raw Materials in a Brazilian Company

2014 ◽  
Vol 1077 ◽  
pp. 135-138
Author(s):  
Luiz Oliveira Veriano dalla Valentina ◽  
Marilena Valadares Folgueras ◽  
Wanessa Rejane Knop ◽  
Maria Cristina Pacheco do Nascimento ◽  
Glaucia Aparecida Prates
Keyword(s):  
Ceramic Coating ◽  
Raw Materials ◽  
Ceramic Materials ◽  
Raw Material ◽  
Silica Sand ◽  
Commercial Application ◽  
X Ray Diffraction ◽  
X Ray ◽  
Materials Used

As the raw materials used in the ceramic materials manufacturing are natural, it is important to use them as a alternative materials, thus decreasing the elements demand taken from nature. This paper aims the characterization of foundry solid powder exhaust from a brazilian company located in Joinville - SC as an alternative raw material for ceramic coating by X-ray diffraction (XRD), thermal analysis (DSC) and thermogravimetric (TG). The dust depletion is caused in the manufacturing mold sand process, when the bentonita (clay), silica sand and coal during the metal parts production are mixed in green sand production. The raw materials were characterized through X-ray diffraction (XRD), thermal (DSC) and thermogravimetric analisys (TG). The atomized powder thermogravimetric analysis curve shows three intervals associated with the mass loss and it is typical of clay commercial application.

Sign in / Sign up

Export Citation Format

Share Document