Preparation, Characterisation and Mechanical Properties of Environmentally Friendly Waterborne Polyurethane and Polyurethane-Acrylate

2009 ◽  
Vol 17 (8) ◽  
pp. 521-527 ◽  
Author(s):  
Fengxian Qiu ◽  
Jingli Zhang ◽  
Dongmei Wu ◽  
Qinqin Zhang ◽  
Dongya Yang
2011 ◽  
Vol 287-290 ◽  
pp. 1532-1537 ◽  
Author(s):  
Xiao Juan Lai ◽  
Yi Ding Shen ◽  
Lei Wang

Waterborne polyurethane emulsions were synthesized with isophorone diisocyanate(IPDI), dihydromethyl propionic acid(DMPA) and poly-ε-caprolactone glycol(PCL), and then reacted with hydroxy-ethyl acrylate(HEA) and 3-aminopropyltriethoxylsilane(APTES) to cap the terminal -NCO groups. The polyurethane emulsions were used to copolymerize with acrylates to synthesize the modified waterborne polyurethane-acrylate hybrid emulsions. The structure, thermal stability and crystallinity of modified polyurethane were studied by FTIR, TG, XRD and the mechanical properties of modified polyurethane films was also investigated. The results show that crystallization of the modified waterborne polyurethane decreases and thermal stability is improved. When the mass fraction of acrylate is 20% and APTES content is 15%, tensile strength of the modified polyurethane films can reach 23.9MPa and elongation at break is 247%.


2020 ◽  
Vol 15 ◽  
pp. 155892502093555
Author(s):  
Mengjin Wu ◽  
Ruosi Yan ◽  
Zhihui Xia ◽  
Bao Shi ◽  
Sainan Wei ◽  
...  

In this study, we fabricated para-aramid flexible angle-ply-laminated hybrid composites based on weft-knitted reinforcements. Here, four kinds of weft-knitted reinforcements with rib, interlock, punto di roma, and two-thread fleecy were prepared using para-aramid spun yarn. They were then compounded with silicone rubber and waterborne polyurethane–acrylate using the coating method. The layers were angle-plied to produce stab-resistant, weft-knitting-reinforced, flexible laminated hybrid composites. Tensile and tearing strengths of the para-aramid-knitted reinforcements were investigated. Relevant response analyses were chosen to evaluate the influence of three independent variables, including weft-knitted structures, matrix types, and ply orientations. The results showed that the mechanical properties of the composites were dependent on weft-knitted structures and matrix types. The fabric with high strength and the degree in approximate isotropy of stress in all composites was most suited for the reinforcement of the flexible stab-resistant composite. The optimum design with the best stab-resistant property was punto di roma/waterborne polyurethane–acrylate with a ply orientation angle of [0°/0°/0°/0°]. The interlaminar adhesion of flexible stab-resistant composite based on waterborne polyurethane–acrylate can be improved by increasing the surface roughness of fabric structure or modifying its surface.


RSC Advances ◽  
2016 ◽  
Vol 6 (79) ◽  
pp. 75440-75448 ◽  
Author(s):  
Suli Chen ◽  
Tao Jin ◽  
Wenling Wu ◽  
Guanghui Zhao

Superparamagnetic nanocomposite films based on waterborne polyurethane and hollow Ni0.3Zn0.5Fe2O4 nanospheres (WPU/h-NZFO) were synthesized via an in situ polymerization technique.


RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12748-12756
Author(s):  
Yong Joon Lee ◽  
Yunju La ◽  
Ok Sung Jeon ◽  
Hak Ji Lee ◽  
Min Kyoon Shin ◽  
...  

Composite coating materials consisting of waterborne polyurethane–acrylate (WPUA) and boron nitride nanotubes (BNNTs) showed enhanced mechanical properties, thermal properties and chemical resistance.


2011 ◽  
Vol 124 (2) ◽  
pp. 958-968 ◽  
Author(s):  
Heping Xu ◽  
Fengxian Qiu ◽  
Yingying Wang ◽  
Dongya Yang ◽  
Wenling Wu ◽  
...  

Polymer ◽  
2020 ◽  
Vol 186 ◽  
pp. 122008 ◽  
Author(s):  
Manoj B. Kale ◽  
Nidhin Divakaran ◽  
Suhail Mubarak ◽  
Duraisami Dhamodharan ◽  
T. Senthil ◽  
...  

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