Novel polyimides based on diamine containing thiazole units with thioether linkage and pyridine as pendent group

2017 ◽  
Vol 30 (7) ◽  
pp. 840-846 ◽  
Author(s):  
Jafar Rezania ◽  
Abbas Shockravi ◽  
Morteza Ehsani ◽  
Vahid Vatanpour
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Pyridine Ring ◽  
Polar Solvent ◽  
Nitrogen Atmosphere ◽  
Scanning Calorimetry ◽  
Glass Transition Temperatures ◽  
Good Thermal Stability ◽  
Pendent Group ◽  
High Yields

Three new organic-soluble polyimides (PIs) bearing flexible thioether linkages, thiazole, and pyridine ring units were synthesized from a novel thioether-bridged diamine monomer and commercially available aromatic dianhydrides (1–3) via chemical imidization method. The resulting polymers were obtained in high yields and possessed inherent viscosities in the range of 0.67–0.89. The PIs are characterized by Fourier-transform infrared (FTIR), nuclear magnetic resonance (NMR), differential scanning calorimetry, and thermogravimetric analysis (TGA). All of the PIs exhibited excellent solubility in polar solvent. The polymers showed good thermal stability with glass transition temperatures ( Tgs) in the range of 194–244°C, and decomposition temperatures ( T5%) exceeding 300°C were observed using TGA in nitrogen atmosphere for the current polymers.

Thermal properties of a series of tetrafunctional fluorene-based oxazines/P-a blends

2016 ◽  
Vol 29 (10) ◽  
pp. 1139-1147 ◽  
Author(s):  
Zi Sang ◽  
Tiantian Feng ◽  
Wenbin Liu ◽  
Jun Wang ◽  
Mehdi Derradji
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Thermal Properties ◽  
Mechanical Analysis ◽  
Proton Nuclear Magnetic Resonance ◽  
Primary Amines ◽  
Resonance Spectroscopy ◽  
High Glass Transition Temperature ◽  
Scanning Calorimetry ◽  
Good Thermal Stability

A new series of aniline and aniline-mixed tetrafunctional fluorene-based oxazine monomers were synthesized using 2,7-hydroxy-9,9-bis-(4-hydroxyphenyl) fluorene, paraformaldehyde, and primary amines (including aniline or aniline mixed with n-butylamine or n-octylamine composition). Fourier transform infrared spectroscopy and proton nuclear magnetic resonance spectroscopy were used to characterize the structure of the monomers. The copolymers were obtained by adding the monomers into a typical monofunctional polybenzoxazine (phenol-aniline-based benzoxazine). Differential scanning calorimetry, thermogravimetric analysis, and dynamic mechanical analysis were performed to study the thermal properties of the copolymers. The copolymers exhibited high glass transition temperature values (164–201°C). A good thermal stability was also obtained with a 5% weight loss temperature over 355°C and high char yields at 800°C (42–50%).

Synthesis and Thermal Stability of Unsaturated Polyamides

1992 ◽  
Vol 4 (2) ◽  
pp. 67-71
Author(s):  
N. R. Patel ◽  
N. Z. Patel ◽  
R. M. Patel
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Thermogravimetric Analysis ◽  
Scanning Calorimetry ◽  
Aromatic Diamines ◽  
Good Thermal Stability ◽  
Kinetics Of Decomposition ◽  
Glutaconic Acid ◽  
Kinetics Of ◽  
Thermal Stability Of

Unsaturated polyamides were prepared by condensing /3(4-ethoxyphenyl) glutaconic acid with various aromatic diamines. The polycondensates were characterized by IR spectroscopy, vapor phase osmometry, thermogravimetric analysis, differential scanning calorimetry and elemental analysis. All resins were found to decompose in the range '-210-600 °C. The kinetics of decomposition were studied. The results indicated that the resins possess reasonably good thermal stability.

Synthesis of aromatic, soluble, and thermally stable polyamides derived from new diamine containing unsymmetrical phenolphthalein and imidazole pendent group

2017 ◽  
Vol 30 (10) ◽  
pp. 1260-1266
Author(s):  
Mohammad Barghamadi
Keyword(s):  
Terephthalic Acid ◽  
Isophthalic Acid ◽  
Nitrogen Atmosphere ◽  
Pendant Group ◽  
The Novel ◽  
Polar Solvents ◽  
Glass Transition Temperatures ◽  
Pendent Group ◽  
High Yields ◽  
Diamine Monomer

A novel diamine monomer containing unsymmetrical phenolphthalein and triaryl imidazole pendant group, 3,3-bis(4-(4-amino-2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)phenyl)isobenzofuran-1(3H)-one (BADPPI), was successfully prepared in three steps. The novel diamine monomer BADPPI was directly polymerized with commercially available diacids, such as terephthalic acid, isophthalic acid, pyridine-2,6-dicarboxylic acid, and adipic acid, to obtain corresponding polyamides (PAs). The resulting novel aromatic PAs were obtained in high yields and moderate inherent viscosities in the range of 0.52–0.57 dL g−1 and exhibited excellent solubility in aprotic polar solvents, such as N,N-dimethylacetamide , N-methyl-2-pyrrolidone, N,N-dimethylformamide, dimethyl sulfoxide, tetrahydrofuran, meta cresol, and pyridine. PAs showed high glass-transition temperatures between 191°C and 277°C. Thermogravimetric analysis of the PAs indicated a 10% weight loss ( T10%) in the temperature range of 382–473°C and char yields at 600°C under nitrogen atmosphere in the range of 56–70% depending on the diacids monomer used for the PAs preparation.

Synthesis and properties of poly(arylene imino) containing fluorenone group (PIKF)

e-Polymers ◽  
2010 ◽  
Vol 10 (1) ◽  
Author(s):  
Lin Zhang ◽  
Guanjun Chang ◽  
Zhen Xu ◽  
Lubin Miao ◽  
Yi Xu ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Optical Properties ◽  
Thermal Properties ◽  
Electron Transport ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Scanning Calorimetry ◽  
Good Thermal Stability ◽  
Palladium Catalyzed

AbstractA series of novel poly(arylene imino) containing fluorenone group (PIKF) have been synthesized via palladium-catalyzed polycondensation. The thermal properties of PIKF are detected by thermal behavior (TG) and differential scanning calorimetry (DSC). UV-vis absorption spectra, photoluminescence are investigated. PIKF exhibit good thermal stability and high Tgs(>200 °C ). The optical properties of PIKF show that PIKF are interesting materials for further investigations to be presented as possible candidates for use as an electron transport layer (n-type) in multilayer LEDs.

Thermal Stability of N-Heterocycle-Stabilized Iodanes – A Systematic Investigation

2019 ◽  
Author(s):  
Andreas Boelke ◽  
Yulia A. Vlasenko ◽  
Mekhman S. Yusubov ◽  
Boris Nachtsheim ◽  
Pavel Postnikov
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Thermogravimetric Analysis ◽  
Systematic Investigation ◽  
Scanning Calorimetry ◽  
Thermal Stability Of

<p>The thermal stability of pseudocyclic and cyclic <i>N</i>-heterocycle-stabilized (hydroxy)aryl- and mesityl(aryl)-l<sup>3</sup>-iodanes (NHIs) through thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) is investigated. NHIs bearing <i>N</i>-heterocycles with a high N/C-ratio such as triazoles show among the lowest descomposition temperatures and the highest decomposition energies. A comparison of NHIs with known (pseudo)cyclic benziodoxolones is made and we further correlated their thermal stability with reactivity in a model oxygenation. </p>

scholarly journals EVALUATION THERMOANALYTICAL OF WHEAT FLOUR FORTIFIED WITH FOLIC ACID AND FERROUS SULPHATE

2009 ◽  
Vol 06 (12) ◽  
pp. 47-50
Author(s):  
Eliane Gonçalves ARAÚJO ◽  
Nedja Suely FERNANDES
Keyword(s):  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Folic Acid ◽  
Wheat Flour ◽  
Ferrous Sulphate ◽  
Scanning Calorimetry ◽  
Iron Sulphate ◽  
Derivative Thermogravimetry

In this work wheat flour aditived with folic acid and iron sulphate was evaluated by Thermogravimetry (TG), Derivative Thermogravimetry (DTG) and differential scanning calorimetry (DSC) for evaluation of the thermal stability. The results obtained showed that the samples of wheat flour have similar behaviour.

scholarly journals Thermal behaviour study of solid state compounds of manganese (II), zinc (II) and lead (II) with cinnamic acid

1998 ◽  
Vol 23 (0) ◽  
pp. 09-16
Author(s):  
Marco Aurélio da Silva CARVALHO FILHO ◽  
Massao IONASHIRO
Keyword(s):  
Thermal Stability ◽  
Aqueous Solution ◽  
Differential Scanning Calorimetry ◽  
Cinnamic Acid ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
X Ray ◽  
Manganese Zinc ◽  
Behaviour Study ◽  
Derivative Thermogravimetry

Compounds of cinnamic acid with manganese, zinc and lead have been prepared in aqueous solution. Thermogravimetry, derivative thermogravimetry (TG, DTG), differential scanning calorimetry (DSC), X-ray diffraction and complexometry have been used in the characterization as well as in the study of the thermal stability and interpretation concerning the thermal decomposition.

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